Heterophase Network Polymers: Synthesis, Characterization, and Properties

by Rozenberg; Boris A

• ISBN13: 9780415284172
• ISBN10: 0415284171
• Edition: 1st
• Format: Hardcover
• Copyright: 2002-06-27
• Publisher: CRC Press

Summary

This volume explains the theory and experimental investigations in the preparation of heterophase polymer network materials through cure reaction-induced microphase separation (CRIMPS). It describes the synthesis of a new family of block- and graft-copolymers with controlled solubility in epoxies and characterizes CRIMPS processes using novel applications of known methods such as nuclear magnetic resonance, electron spin resonance and photochemistry. The text develops a new method for characterizing the molecular mass distribution (MMD) of linear and network polymers using thermomechanical analysis data, as well as new methods for determining internal stresses and flaw formation during thermoset curing. The CRIMPS theory will be helpful for researchers and engineers designing and improving toughened plastics and other smart heterophase network materials for different applications. The new method for MMD characterization of polymers in bulk will be very useful to quickly analyze a polymer's MMD and to design new polymers. This book will provide a useful reference for graduates, researchers and working professionals in polymer chemistry and physics and materials science.

Table of Contents

Preface	ix
List of Contributors	xi
I SYNTHESIS AND CHARACTERIZATION OF MODIFIERS	1	(42)
Synthesis of Well-Defined Bifunctional Oligobutadienes as Initiated by Dilithium Alkanes Soluble in Hydrocarbons	3	(12)
Aleksandr A. Grishchuk
Larisa T. Kasumova
Yakov I. Estrin
Synthesis of Block Copolymers with Controlled Solubility in Epoxy Resins	15	(12)
Elmira R. Badamshina
Yakov I. Estrin
Valentina A. Grigor'Eva
Aleksandr A. Grishchuk
Galina A. Gorbushina
Larisa T. Kasumova
Viktoriya V. Komratova
Anatolii I. Kuzaev
Vera P. Lodygina
Universal Calibration in Gel Permeation Chromatography of Oligomers	27	(6)
Anatolii I. Kuzaev
Phase Equilibrium in Binary Polymer Systems Based on Diglycidyl Ether of Bisphenol A	33	(10)
Yurii M. Mikhailov
Lyudmila V. Ganina
Vladimir S. Smirnov
II THEORY OF MICROPHASE SEPARATION IN CURING SYSTEMS	43	(74)
Cure Reaction-Induced Microphase Separation in Multicomponent Blends: Theory of Nonequilibrium Nucleation and Growth	45	(18)
Grigori M. Sigalov
Boris A. Rozenberg
Analytical Description of Microphase Formation in Curing Polymer Blends	63	(16)
Leonid I. Manevich
Boris A. Rozenberg
Shagen A. Shaginyan
Two-Dimensional Model of Phase Separation during Polymerization of a Binary Polymer Blend	79	(12)
Avigeya N. Ivanova
Leonid I. Manevich
Theory and Simulation for Dynamics of Polymerization-Induced Phase Separation in Reactive Polymer Blends	91	(16)
Thein Kyu
Hao-Wen Chiu
Jae-Hyung Lee
Phase Diagrams of Multicomponent Reacting Polymer Systems Undergoing Phase Decomposition	107	(10)
Elina L. Manevitch
Grigori M. Sigalov
Boris A. Rozenberg
III KINETICS AND MECHANISM OF CURE REACTIONS AND REACTION-INDUCED MICROPHASE SEPARATION	117	(34)
Cure Rate and Crimps Mechanism	119	(10)
Lyudmila M. Bogdanova
Emma A. Dzhavadyan
Grigori M. Sigalov
Boris A. Rozenberg
The Role of Intermolecular Interactions in Polyurethane Formation	129	(10)
Elena V. Stovbun
Vera P. Lodygina
Elmira R. Badamshina
Valentina A. Grigor'Eva
Irina V. Doronina
Sergei M. Baturin
Formation of Spatial Dissipative Structures During Synthesis of Polyurethanes	139	(12)
Lev P. Smirnov
Evgenii V. Deyun
IV STRUCTURE-PROPERTIES RELATIONSHIP	151	(94)
Thermoset/Thermoplastic Blends with a Crosslinked Thermoplastic Network Matrix	153	(14)
Ying Yang
Tsuneo Chiba
Takashi Inoue
Epoxy-Based PDLCs: Formation, Morphological, and Electroptical Properties	167	(14)
Lyudmila L. Gur'Eva
Georgii B. Nosov
Vladimir K. Gerasimov
Anatolii E. Chalykh
anatolii S. Sonin
Boris A. Rozenberg
Crosslinking Studies in Rigid and Semi-Rigid Polymers	181	(18)
Shawn Jenkins
Karl I. Jacob
Satish Kumar
Modeling Shrinkage Defects in Fiber Composites	199	(10)
Vladimir N. Korotkov
Boris A. Rozenberg
Analysis of Shrinkage Cracking in Three-Dimensionally Constrained Heterophase Network Polymers	209	(14)
Valentina A. Lesnichaya
Vladimir N. Korotkov
Modeling Polymer Film Formation by Spin Coating	223	(12)
Aleksei K. Alekseev
Sergei M. Baturin
Georgii A. Pavlov
Anatolii A. Shiryaev
Thermal Decomposition of Thin Polyepoxide Films	235	(10)
Lev. P. Smirnov
V NEW APPROACHES TO POLYMER NETWORKS CHARACTERIZATION	245	(66)
Characterization of Molecular Weight Distribution for Linear and Network Polymers in the Bulk	247	(14)
Vadim I. Irzhak
Microphase Separation in Epoxies as Studied by Photoactive Probe Technique	261	(10)
Vladimir F. Razumov
Sergei B. Brichkin
Aleksandr V. Veretennikov
Lyudmila L. Gur'Eva
Lyudmila M. Bogdanova
Boris A. Rozenberg
Investigation of Crimps by NMR	271	(8)
Viktor P. Tarasov
Anatoloii K. Khitrin
Lyudmila M. Bogdanova
Boris A. Rozenberg
Crimps in an Epoxy-Amine System as Studied by ESR	279	(10)
Boris E. Krisyuk
Boris A. Rozenberg
Gelation and Reaction-Induced Microphase Separation during Cure of Model Epoxy-Amine Systems as Studied by Dielectroscopy	289	(12)
Gennadii F. Novikov
Tatyana L. Elizarova
Emma A. Dzhavadyan
Lyudmila M. Bogdanova
Boris A. Rozenberg
Pulsed NQR for Measuring Internal Stresses in Polymers and Composites	301	(10)
Viktor P. Tarasov
Leonid N. Erofeev
Emma A. Dzhavadyan
Yurii N. Smirnov
Boris A. Rozenberg
Subject Index	311