Inorganic and Organometallic Polymers Macromolecules Containing Silicon, Phosphorus, and Other Inorganic Elements

by Zeldin, Martel; Wynne, Kenneth J.; Allcock, Harry R.

• ISBN13: 9780841214422
• ISBN10: 0841214425
• Format: Hardcover
• Copyright: 1987-12-01
• Publisher: American Chemical Society

Summary

Discusses the electrical, photochemical, mechanical, and biomedical properties of these polymers, as well as their unusual behavior at both low and high temperatures. Tells how these polymers can provide solutions to a wide range of engineering problems because of their unusual properties. Offers a better perspective of accomplishments and new efforts in this field. Serves newcomers and specialists alike in the areas of inorganic and polymer chemistry, materials science, and ceramic chemistry.

Table of Contents

Introduction

Polysilane High Polymers

Polycarbosilanes

Soluble Polysilane Derivatives

Poly(di-n-hexysilane) in Room-Temperature Solution

New Synthetic Routes to Polysilanes

Polymerization of Group 14 Hydrides

Polysilane Preparations

Copolydiorganosilanes with Varying Compositions

Synthetic Routes to Polysilazanes

Silicon-Containing Ceramics

A Precursor to Si-C-N-0 Ceramics

S-N-Containing Rings and Polymers

Organosiloxane Copolymers

Catalysts for Transacylation Reactions

Polymers Bearing Phenyldisilanyl Units

Routes to Molecular Metals

Alkyl Silicates and Organosiloxanes

Polyphosphazene Chemistry

Phosphazene Synthesis

Polyphosphazenes: Performance Polymers

Poly (alkyl/arylphosphazenes)Hybrid Inorganic-Organic Polymers

Polybis(pyrrolyl)phosphazene

NOVEL Phosph(III)azane Oligomers/Polymers

Sol-Gel-Derived Inorganic Polymers

Organically Modified Silicates

Sol-Gel Preparation of Fibers

A New TEOS-PTMO Hybrid System

Precursors to Nonoxide Macromolecules

Boron-Nitrogen Polymer Precursors

Boron Nitride and Its Precursors

Polymeric Films of Metallotetraphenylporphyrins

Poly(trisbipyridine) Metal Complexes

Copper Chloride Complexes

Organometallic Monomers

Soluble Metal Chelate Polymers

Oligomeric Organotin Compounds

Tri-n-butyltin Polymers

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