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9780471208259

Inorganic Syntheses, Volume 33

by
  • ISBN13:

    9780471208259

  • ISBN10:

    0471208256

  • Edition: 1st
  • Format: Hardcover
  • Copyright: 2002-05-02
  • Publisher: Wiley-Interscience
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Supplemental Materials

What is included with this book?

Summary

The Inorganic Syntheses series provides inorganic chemists with detailed and foolproof procedures for the preparation of important and timely compounds. Volume 33 includes provocative contributions on syntheses of selected supramolecules, useful reagents/ligands, solid state materials/clusters, and other compounds of general interest.

Author Biography

DIMITRI COUCOUVANIS, PhD, is Professor of Chemistry at the University of Michigan.

Table of Contents

Syntheses of Selected Supramolecules
Toward Magnetic Building Blocks: Synthesis of a Planar Co(III)-cation Radical-cobalt(III) Complex of the Binucleating Ligand 1,2,4,5-Tetrakis(2-hydroxy-2 methylpropanamido)benzene
1(9)
1,2,4,5-Tetrakis(2-acetate-2-methylpropanamido)benzene (t-AcMPA-B)
2(2)
1,2,4,5-Tetrakis(2-hydroxy-2-methylpropanamido)benzene, [H8(t-HMPA-B)]
4(1)
Bistetraphenylphosphonium-di-cobalt(III)-k4:k4-[1,2,4,5-tetrakis(2-oxy-2-methylpropanamido)benzene] {[PPh4]2[Co(k4:k4-t-HMPA-B)]}
5(2)
Tetraphenylphosphonium-di-cobalt(III)-k4:k4-[1,2,4,5-tetrakis(2-oxy-2- methylpropanamido)benzene) {[PPh4][Cok4:k4-t-HMPA-B)]}
7(3)
A Luminescent Decanuclear Ruthenium(II) Polypyridine Complex: A Convergent Approach to a Dendritic Structure Employing the ``Complexes as Metals/Complexes as Ligands'' Synthetic Strategy
10(8)
Bishexafluorophosphate-bisbipyridyl-2,3-bis(2-pyridylpyrazine)ruthenium(II) {[Ru(bPy)2(2,3-dpp))(PF6)2}
13(2)
Tetrakis-hexafluorophosphate-bis-bisbipyridyl-2,3-bis(2- (2-pyridylpyrazine)ruthenium(II)-dichlororuthenium(II)({Cl2Ru[(μ-2,3-dpp)Ru(bPy)2]2}(PF6)4)
15(1)
Icosakishexafluorophosphate-tris-bis-bisbipyridyl-2,3-bis(2- pyridylpyrazine)ruthenium(II)-2,3-bis(2-pyridylpyrazine) Ruthenium(II)[({Ru[(μ-2,3-dpp)Ru(μ-2,3-dpp)Ru(bPy)2]2}3)(PF3)20]
16(2)
Dodecatungstoaluminic Acid and Its Monolacunary and Mixed-Addendum Derivatives
18(8)
Dodecatungstoaluminic Acid H5[AlW12O40]
20(2)
α-Pentasodium Dodecatungstoaluminate α-Na5(AlW12O40)
22(1)
α-Nonapotassium Undecatungstoaluminate α-K9[AlW11O39]
23(1)
α-Heptapotassium Vanadoundecatungstoaluminate α-K7[AlVIV,W11O40]
24(1)
α-Hexapotassium Vanadoundecatungstoaluminate α-K6[AlVVW11O40]
25(1)
Supramolecular Complexes of Bis(2,2'-bipyridine)osmium(II) and Ruthenium(II)
26(13)
2,3-Bis(2-Pyridyl)quinoxaline (dpq)
28(1)
2,3-Bis(2-pyridyl)benzoquinoxaline (dpb)
29(1)
cis-Bis(2,2'-bipyridine)2,3-bis(2-pyridyl)pyrazineosmium(II) hexafluorophosphate Hydrate {[Os(bPy)2(dpp)](PF6)2 . HO}
30(1)
cis-Bis(2,2'-bipyridine)2,3-bis(2-pyridyl)quinoxalineosmium(II) Hexafluorophosphate {[Os(bpy)2(dpq)](PF6)2}
31(1)
cis-Bis(2,2'-bipyridine)2,3-bis(2-pyridyl) benzoquinoxalineosmium(II) Hexafluorophosphate ([Os(bPy)2(dpb)}(PF6)2}
32(1)
cis-Tetrakis(2,2'-bipyridine)-μ-[2,3-bis(2-pyridyl)pyrazine] diosmium(II) Hexafluorophosphate Dihydrate {[(bPy)2Os(dpp)Os(bPy)2](PF6)4 . 2HO}
32(1)
cis-Tetrakis(2,2'-bipyridine)-μ-[2,3-bis(2-pyridyl)quinoxaline] diosmium(II) Hexafluorophosphate Dihydrate ([(bPy)2Os(dpq)Os(bPy)2](PF6)4 . 2HO}
33(1)
cis-Tetrakis(2,2'-bipyridine)-μ-[2,3-bis(2-pyridyl) benzoquinoxaline]diosmium(II) Hexafluorophosphate Trihydrate {[(bpy)2Os(dpb)Os(bpy)2](PF6}4 . 3H2O}
34(1)
cis-Tetrakis(2,2'-bipyridine)-μ-[2,3-bis(2-pyridyl)pyrazine]ruthenium(II)-osmium(II) Hexafluorophosphate Dihydrate {[(bPy)2Os(dpp)Ru(bpy)2](PF6)4 . 2HO}
34(1)
cis-Tetrakis(2,2'-bipyridine)-μ,-[2,3-bis(2-pyridyl)quinoxaline] ruthenium(II)-osmium(II) Hexafluorophosphate Trihydrate {[(bPy)2Os(dpq)Ru(bPy)2](PF6)4 . 3HO}
35(1)
cis-Tetrakis(2,2'-bipyridine)- μ,-[2,3-bis(2-pyridyl) benzoquinoxaline]ruthenium(II)-osmium(II) Hexafluorophosphate Dihydrate {[bpy)2Os(dpb)Ru(bpy)2](PF6)4 . 2HO}
36(3)
Binuclear Oxomolybdenum-Metalloporphyrin Complexes
39(13)
5-(3,4-Dimethoxyphenyl)-10,15,20-tri-p-tolylporphyrin (3,4-OMe-TTP)
40(2)
5-(2,3-Dimethoxyphenyl)-10,15,20-tri-p-tolylporphyrin (2,3-OMe-TTP)
42(1)
5-(3,4-Dihydroxyphenyl)-10,15,20-tri-p-tolylporphyrin (3,4-OH-TTP)
42(1)
5-(2,3-Dihydroxyphenyl)-10,15,20-tri-p-tolylporphyrin (3-OH-TTP)
43(1)
[Hydrotris(3,5-Dimethyl-l-pyrazolyl)borato] oxomolybdenum(V)dichloride (LMoOCl2)
43(1)
[Hydrotris(3,5-Dimethyl-I-pyrazolyl)borato] oxomolybdenum(V)ethyleneglycolate [LMoO(Eth-Gly)]
44(1)
5-{3,4-Catecholato[hydrotris(3,5-dimethyl-I-pyrazolyl) borato]oxomolybdenum(V)}-10,15,20-tri-p-tolylporphyrin (3,4-Mo-TTP)
45(1)
5-{2,3-Catecholato[hydrotris(3,5-dimethyl-1-pyrazolyl)borato] oxomolybdenum(V)}- -10,15,20-tri-p-tolylporphyrin (2,3-Mo-TTP)
45(1)
5-{3,4-Catecholato[hydrotris(3,5-dimethyl-1-pyrazolyl)borato]oxomolybdenum(V)}-10,15,20-tri-p-tolylporphinatozinc(II) [Zn(3,4-Mo-TTP)]
46(1)
5-{2,3-Catecholato[hydrotris(3,5-dimethyl-1-pyrazolyl)borato]oxomolybdenum(V)}-10,15,20-tri-p-tolylporphinatozinc(II) [Zn(2,3-Mo-TTP)]
47(1)
5-{3,4-Catecholato[hydrotris(3,5-dimethyl-1-pyrazolyl)borato]oxomolybdenum(V)}-10,15,20-tri-p-tolylporphinatoiron(III)chloride [FeCl(3,4-Mo-TTP)]
47(1)
5-{2,3-Catecholato[hydrotris(3,5-dimethyl-1-pyrazolyl)borato]oxomolybdenum(V)}-10,15,20-tri-p-tolylporphinatoiron(III)chloride [FeCl(2,3-Mo-TTP)]
48(1)
5-{3,4-Catecholato[hydrotris(3,5-dimethyl-1-pyrazolyl)borato]oxomolybdenum(V)}-10,15,20-tri-p-tolylporphinatoiron(III)bis(N-methylimidazole)adduct {Fe(N-MeIm)2[(3,4-Mo-TTP)]Cl}
49(1)
5-{2,3-Catecholato[hydrotris(3,5-dimethyl-1-pyrazolyl)borato]oxomolybdenum(V)}-10,15,20-tri-p-tolylporphinatoiron(III)bis(N-methylimidazole) adduct {Fe(N-MeIm)4[(2,3-Mo-TTP)]Cl}
49(1)
5-{3,4-Catecholato[hydrotris(3,5-dimethyl-1-pyrazolyl)borato]oxomolybdenum(V)}-10,15,20-tri-p-tolylporphinatocopper(II) [Cu(3,4-Mo-TTP)]
50(1)
5-{2,3-Catecholato[hydrotris(3,5-dimethyl-1-pyrazolyl)borato]oxomolybdenum(V)}-10,15,20-tri-p-tolylporphinatocopper(II) [Cu(2,3-Mo-TTP)]
50(2)
Iron Sandwich Polyoxoanion Compounds
52(3)
Hexakistetrabutylammonium Octadecatungstotetrairon-diphosphate {(TBA)6 [Fe(H2O)2(PW9O34)2]}
52(2)
Dodecasodium Triacontatungstotetrairontetraphosphate Hydrate {Na12(Fe(H2O) 2(P2W15O56)2] . 58H2O}
54(1)
Dipyrryl and Porphyrinic Precursors to Supramolecular Conjugated (Porphinato)metal Arrays: Syntheses of Dipyrrylmethane and (5,15-diphenylporphinato)zinc(II)
55(6)
2,2'-Dipyrrylmethane (C9H10N2)
59(1)
5,15-Diphenylporphyrin
60(1)
(5,15-Diphenylporphinato)zinc(II)
60(1)
Synthesis of Dodecaoxohexadecacarboxylatotetraaquo-dodecamanganese Mn12O12(O2CR)16(H2O)4] (R = Me,Et,Ph,Cr) Complexes
61(6)
[Mn12O12(O2CMe)16(H2O)4] . 4H2O . 2HO2CMe
63(1)
[Mn12O12(O2CEt)16(H2O)3](H3O)
64(1)
[Mn12O12(O2CPh)16(H2O)4]
65(1)
[Mn12O12(O2CCH=CHCH3)16(H2O)3]
65(2)
Use of Picolinehydroximate Complexes in Preparation of Uranyl and Lanthanide 15-Metallacrown-5: UO2(NO3)2[15-MCCu(II)N(pic)-15] and (Eu(NO3)2[15-MCCu(II)N(pic)-15]}NO3
67(3)
UO2(NO3)2[15-MCcu(II)N(pic)-15]
68(1)
{Eu(NO3)2[15-MCcu(II)N(picHA)-15]}NO3
69(1)
Use of Salicyl- and Naphthoylhydroximate Complexes in Preparation of Manganese and Copper 12-Metallacrown-4 Complexes: Mn(II)(Acetate)2[Mn(III)(salicylhydroximate)]4 and (Tetramethylammonium)2[Cu(II)5(naphthoylhydroximate)4]
70(5)
Preparation of Free-Base Hydroxylamine:KOH Solution
71(1)
3-Hydroxy-2-naphthohydroxamic Acid (H3NHA)
72(1)
(Tetraethylammonium)2[Cu(II)5(naphthoylhydroximate)4] dimethylformamide {(Et4N)2[Cu(II)12-MCCu(II)N(nha)-4]DMF}
72(1)
Mn(II)(Acetate)2[Mn(III)(salicylhydroximate)]4{Mn(OAc)2[12-MCMn(III)N(shi)-4]}
73(2)
Useful Reagents and Ligands
Homoleptic Transition Metal Acetonitrile Cations with Tetrafluoroborate or Trifluoromethanesulfonate Anions
75(8)
Bistetrafluoroborate-Hexakisacetonitrile Metal(II){M(CH3CN)6(BF4)2} (M = Fe,Co,Ni)
76(1)
Bistetrafluoroborate-Tetrakisacetonitrile Manganese(II){[Mn(CH3CN)4](BF4)2}
77(1)
Bistetrafluoroborate-Tetrakisacetonitrile Copper(II){[Cu(CH3CN)4](BF4)2)
77(1)
[M(CH3CN)x][BF4]2 from [M(H2O)x][BF4]2 (M= Mn,Fe,Co,Ni,Cu)
78(1)
Bistetrafluoroborate-Tetrakisacetonitrile Chromium(II) [Cr(CH3CN)4](BF4)2 from Chromous Acetate [Cr2(O2CCH3)4]
79(1)
Preparation of Acetonitrile Cations with Trifluoromethanesulfonate (Triflate) Anions
79(1)
Anhydrous Metal Triflate Complexes
80(1)
Metal Acetonitrile Complex Cations with Triflate Anions
80(3)
Synthesis of [MII(NCMe)6]2+ (M = V,Cr,Mn,Fe,Co,Ni) Salts of Tetra[3,5-bis(trifluoromethyl)phenyl]borate
83(8)
Potassium Tetra-3,5-bis(trifluoromethyl)phenylborate, (K{B[C6H3(CF3)2]4})
85(1)
Silver Tetra-3,5-bis(trifluoromethyl)phenylborate (Ag{B[C6H3(CF3)2]4})
86(1)
Hexakis(acetonitrile)manganese(II)bis-tetra-3,5-bis(trifluoromethyl)phenylborate ([MnII(NCMe)6]{B[C6H3(CF3)2]4}2)
86(1)
Hexakis(acetonitrile)iron(II)bis-tetra-3,5-bis(trifluoromethyl) phenylborate ([FeII(NCMe)6]{B[C6H3(CF3)2]4}2)
87(1)
Hexakis(acetonitrile)cobalt(II)bis-tetra-3,5-bis(trifluoromethyl) phenylborate ([CoII(NCMe)6][B[C6H3(CF3)2]4})
87(1)
Hexakis(acetonitrile)nickel(II)bis-tetra-3,5-bis(trifluoromethyl)phenylborate ([NiII(NCMe)6]{B[C6H3(CF3)2]4})
88(1)
Hexakis(acetonitrile)chromium(II)bis-tetra-3,5- bis(trifluoromethyl)phenylborate ([CrII(NCMe)6]{B[C6H3(CF3)2]4}2)
88(1)
Hexakis(acetonitrile)vanadium(II)bis-tetra-3,5-bis(trifluoromethyl)phenylborate ([VII(NCMe)6]{B[C6H3(CF3)2]4}2)
89(2)
Transition Metal p-Toluenesulfonates
91(12)
Tetraaquotitanium(III)tris-p-toluenesulfonate
93(1)
Titanium(Ill)tris-p-toluenesulfonate
94(1)
Hexaaquovanadium(III)tris-p-toluenesulfonate
95(1)
Vanadium(III)tris-p-toluenesulfonate
95(1)
Pentaquooxovanadium(IV)bis-p-toluenesulfonate Hemihydrate
96(1)
Tetraaquochromium(II)bis-p-toluenesulfonate
97(1)
Hexaquochromium(IlI)tris-p-toluenesulfonate
97(1)
Tetraquomanganese(II)bis-p-toluenesulfonate Hydrate
98(1)
Hexaquoiron(II)bis-p-toluenesulfonate
98(1)
Iron(III)tris-p-toluenesulfonate
99(1)
Hexaquocobalt(II)bis-p-toluenesulfonate
100(1)
Hexaquonickel(II)bis-p-toluenesulfonate
100(1)
Cesium-p-toluenesulfonate
101(1)
Preparation of Anhydrous Tosylate Salts
101(2)
Salts of Binuclear Iron(II) and Iron(III) Dianions [(Fe2Cl6)2- and (Fe2OCl6)2-]
103(4)
Di(tetraphenylphosphonium)hexachlorodiferrate(II) [(Fe2Cl6)(PPh4)2]
104(1)
Di(tetraphenylphosphonium)(μ-oxo)bis(trichloroferrate(III) [(PPh4)2(Fe2OCl6)]
105(1)
Di(tetraethylammonium)(μ-oxo)bis(trichloroferrate(III) (Et4N)2(Fe2OCl6)
105(2)
Tetraethylammonium-Tetrathioperrhenate Et4N(ReS4)
107(3)
Stock Ammonium Sulfide Solution (20%)
108(1)
Tetraethylammonium-tetrasulfidorhenate [Et4N(ReS4)]
108(2)
Large-Scale Synthesis of Methyltrioxorhenium (CH3ReO3)
110(2)
Silver Tetraoxorhenate [Ag(ReO4)]
111(1)
Methyltrioxorhenium (CH3ReO3)
111(1)
4,5-Diaminocatechol: A Useful Building Block in Synthesis of Multimetallic Complexes
112(7)
1,2-Dimethoxy-4,5-dinitrobenzene (4,5-Dinitroveratrole)
114(1)
1,2-Dimethoxy-4,5-diaminobenzene (4,5-Diaminoveratrole)
115(1)
1,2-Dihydroxy-4,5-diaminobenzenehydrobromide
115(1)
[N,N'-Bis(3,3'-H-5,5'-H'-salicylidene)-4,5-dihydroxyphenylenediamine] [H2-(H4salphen)-(OH)2]
116(1)
(N,N'-Bis(3,3'-t-butyl-5,5'-t-butylsalicylidene) 4,5- dihydroxyphenylenediamine]etherate ([H2-('Butyl4salphen)(OH)2]ether}
116(1)
(N,N'-Bis(3-ethoxy-5-H-salicylidene)-4,5-dihydroxyphenylenediamine(pyridinium bromide) {[H2(EtO2H2salphen)(OH)2] . pyHBr}
117(1)
[N,N'-Bis(3,3'-H-5,5'-H'-salicylidene)-4,5-dihydroxyphenylenediamino)nickel(II) {[NiII-(H4salphen)(OH)2]}
118(1)
Bis-tetrabutylammonium-bis[N,N'-bis(3,3'-H-5,5'- H'-salicylidene)catecholatodiamino]nickel(II)-oxovanadium(IV) (Bu4)2(VO[NiII(H4salphen)(O)2]2}
118(1)
Convenient Synthesis of 1,5,9-Trithiacyclododecane (S3C9H18)
119(3)
1.5,9-Trithiacyclododecane
120(2)
Solid-State Materials and Clusters
Synthesis of Quaternary Selenophosphates using Molten Salt Fluxes: Rb8Hg4(Se2)2(PSe4)4, K4In2(PSe5)2(P2Se6), Rb4Ti2(P2Se7)(P2Se9)2, Rb4U4(Se)2(Se2)4(PSe4)4
122(8)
Diphosphoruspentaselenide (P2Se5)
123(1)
Octarubidium-tetramercury-bisdiselenido-tetrakistetraselenophosphate Rb8Hg4(Se2)2(PSe4)4]
124(1)
Tetrapotassium-diindium-bisphosphoruspentaselenide-diphosphorushexaselenide [K4In2(PSe5)2(P2Se6)]
125(2)
Tetrarubidium-dititanium-diphosphorusheptaselenide-bisdiphosphorusnonaselenide [Rb4Ti2(P2Se7)(P2Se9)2]
127(1)
Tetrarubidium-tetrauranium-bisselenidotetrakisdiselenido-tetrakistetraselenophosphate [Rb4U4(Se)2(Se2)4(PSe4)4]
128(2)
Hydrothermal Synthesis of Sulfosalts: Ag3AsS3, Ag3SbS3, Ag7SbS6, Cu12Sb4S13, CuInS2, FeIn2S4
130(9)
Trisilver Arsenic Trisulfide (Proustite; Ag3AsS3)
132(4)
Trisilver Antimony Trisulfide (Pyrargyrite; Ag3SbS3)
136(1)
Heptasilver Antimony Hexasulfide (Argrodite; Ag7SbS6)
136(1)
Dodecacopper Tetraantimony Decatrisulfide (Tetrahedrite; Cu12Sb4S13)
137(1)
Copper Indium Disulfide (Roquesite; CuInS2)
137(1)
Iron Diindium Tetrasulfide (Indite; FeIn2S4)
138(1)
Open-Framework Solids of the Vanadium Oxide-Phosphate System
139(5)
1,3-Diammoniumpropane-bisaquo-bishydroxo-bisphosphato-trisvanadyl(IV) {[H3N(CH2)3NH3] [(VO)3(OH)2(H2O)2(PO4)2]}
140(3)
[HN(CH2CH2)2NH]K1.35[V5O9(PO4)2]xH2O
143(1)
[H2N(CH2CH2)2NH2][(VO)3(HPO3)4(H2O)2]
143(1)
Sulfur-Bridged Incomplete Cubane-Type Molybdenum and Tungsten Aqua Ions
144(6)
Sulfur-Bridged Incomplete Cubane-Type Molybdenum Aqua Ion, [Mo3S4(H2O)9]4+(Mo3), in Solution and [MO3S4(H2O)9](CH3C6H4SO3)4+ . 9H2O (Mo3pts)
145(1)
Nonaaquotrimolybdenum-tetrasulfide, [Mo3S4(H2O)9]4+ (Mo3), in Solution
145(2)
Nonaaquotrimolybdenum-tetrasulfide-tetrakis-p-toluenesulfonate-nonahydrate, [MO3S4(H2O)9](CH3C6H4SO3)4 . 9H2O (Mo3pts)
147(1)
Sulfur-Bridged Incomplete Cubane-Type Tungsten Aqua Ion, [W3S4(H2O)9]4+ (W3), in Solution and [W3S4(H2O)9](CH3C6H4SO3)4 . 9H2O (Wpts)
147(1)
Nonaaquotritungsten-tetrasulfide, [W3S4(H2O)9]4+(W), in Solution
147(1)
Nonaaquotritungsten-tetrasulfide-tetrakis-p-toluenesulfonate-nonahydrate, [W3S4(H2O)9] (CH3CH6SO3)4 . 9H2O (W3pts)
148(2)
Sulfur-Bridged Cubane Type Mixed-Metal Clusters with Mo3MS4 (M = Fe,Co,Ni,Cu,In,Sn) and W3NiS4 Cores
150(12)
Molybdenum-iron Cluster Aqua Ion, [Mo3FeS4(H2O)10]4+ (Mo3Fe), in Solution and [Mo3FeS4(H2O)10](CH3C6H4SO3)4 . 7H2O(Mo3Fepts)
152(1)
Decaaquotrimolybdenum-iron-tetrasulfide, [Mo3FeS4(H2O)10]4+(Mo3Fe), in Solution
152(2)
Decaaquotrimolybdenum-iron-tetrasulfide-tetrakis-p-toluenesulfonate-heptahydrate, [Mo3FeS4(H2O)10](CH3C6H4SO3)4 . 7H2O (Mo3Fepts)
154(1)
Molybdenum-cobalt Cluster Aqua Ion, [(H2O)9Mo3S4CoCoS4Mo3(H2O)9]8+ (Mo3Co-D), in Solution and [(H2O)9Mo3S4CoCoS4Mo3(H2O)9(CH3C6H4SO3)8 . 18H2O (Mo3Co-Dpts)
155(1)
Bisnonaaquotrimolybdenum-cobalt-tetrasulfide, [(H2O)9Mo3S4CoCoS4Mo4(H2O)9]+ (Mo3Co-D), in Solution
155(1)
Bisnonaaquotrimolybdenum-cobalt-tetrasulfide-octakis-p-toluenesulfonate-octadecahydrate, [(H2O)9Mo3S4CoCoS4Mo3(H2O)9] (CH3C6H4SO3)8 . 18H2O (Mo3Co-Dpt)
155(1)
Molybdenum-nickel Cluster Aqua Ion, [Mo3NiS4(H4O)10]4+(Mo3Ni) in Solution and [Mo3NiS4(H2O)10] (CH3C6H4SO3)4 . 7H2O (Mo3Nipts)
156(1)
Decaaquotrimolybdenum-nickel-tetrasulfide, [Mo3NiS4(H2O)10]4+ (Mo3Ni), in Solution
156(1)
Decaaquotrimolybdenum-nickel-tetrasulfide-tetrakis-p-toluenesulfonate-heptahydrate, [Mo3NiS4(H2O)10] (CH3C6H4SO3)4 . 7H2O (Mo3Nipts)
156(1)
Molybdenum-copper Cluster Aqua Ion Decaaquo Trimolybdenum-copper-tetrasulfide, [Mo3CuS4(H2O)10]4+ (Mo3Cu), and Bisnonaaquotrimolybdenum-copper-tetrasulfide, [(H2O)9Mo3S4CuCuS4Mo3(H2O)9]8+(Mo3Cu-D), in Solution and Bisnonaaquotrimolybdenum-copper-tetrasulfide-octakis-p-toluenesulfonate-icosahydrate, [(H2O)9Mo3S4CuCuS4Mo3(H2O)9] (CH3C6H4SO3)8 . 20H2O (Mo3Cu-Dpts)
157(1)
Bisnonaaquotrimolybdenum-copper-tetrasulfide-octakis-p-toluenesulfonate- icosahydrate, [(H2O)9Mo3S4CuCuS4Mo3(H2O)9](CH3CH6SO3)8 . 20H2O (Mo3Cu-Dpts)
157(1)
Molybdenum-indium Cluster Aqua Ion Dodecaaquo Trimolybdenum-indium-tetrasulfide, [Mo3InS4(H2O)12]5+ (Mo3In), in Solution and Di-p-toluenesulfonato-decaaquo- trimolybdenum-indium-tetrasulfide-tris-p-toluenesulfonate-tridecahydrate, [Mo3InS4(CH3C6H4SO3)2(H2O)10] (CH3C6H4SO3)3 . 13H2O (Mo3Inpts)
158(1)
Di-p-toluenesulfonato-decaaquo-trimolybdenum-tetrasulfide-tris-p-toluenesulfonate-tridecahydrate, [Mo3InS4(CH3C6SO3)2(H2O)10](CH3C6H4SO3)3 . 13H2O (Mo3Inpts)
159(1)
Molybdenum-tin Cluster Aqua Ion Bis(nonaaquo Trimolybdenum-tetrasulfide)-tin, [(H2O)9Mo3S4SnS4Mo3(H2O)9]8+ (Mo3Sn-SW), and Dodecaaquotrimolybdenum- tin-tetrasulfide, [Mo3SnS4(H2O)12]6+ (Mo3Sn-OX),in Solution and is(nonaaquotrimolybdenum-tetrasulfide)-tin-octakis-p-toluenesulfonate-hexacosahydrate,[(H2O)9Mo3S4SnS4Mo3(H2O)9](CH3C6H4SO3)8 . 26H2O (Mo3Sn-SWpts)
159(1)
Bis(nonaaquotrimolybdenum-tetrasulfide)-tin-octakis-p-toluenesulfonate-icosahexahydrate, (H2O)9Mo3S4SnS4Mo3(H2O)9](CH3C6H4SO3)8 . 26H2O (Mo3Sn-SWpts)
159(1)
Dodecaaquotrimolybdenum-tin-tetrasulfide, [Mo3SnS4(H2O)12]6+ (Mo3Sn-OX), in Solution
160(1)
Tungsten-nickel Cluster Aqua Ion Decaaquo Tritungsten-nickel-tetrasulfide, [W3NiS4(H2O)10]4+ (W3Ni), in Solution and Bisnonaaquotritungsten-nickel-tetrasulfide-octakis-p-toluenesulfonate-icosahydrate, [(H2O)9W3S4NiNiS4W3 (H2O)9](CH3C6H4SO3)8 . 20H2O (W3Ni-Dpts)
161(1)
Bisnonaaquotritungsten-nickel-tetrasulfide-octakis-p-toluenesulfonate-icosahydrate [(H2O)9W3S4NiNiS4 W3(H2O)9](CH3C6H4SO3)8 . 20H4O (W3Ni-Dpts)
161(1)
Molybdenum and Tungsten Clusters as Aqua Ions [M3Q4(H2O)9]4+(M = Mo,W;Q = S,Se) and Related Chalcogen-Rich Trinuclear Clusters
162(9)
Heptachalcogenotetrabromotrimetallo Compounds, {M3Q7Br4)x, (M = Mo,W;Q = S,Se)
164(1)
Nonaaquatetrasulfidotrimolybdenum(IV) [Mo3S4(H2O)9]4+ (First Method)
165(1)
[Mo3S4(H2O)9]4+ (Second Method)
166(1)
Preparation of (NH4)2[Mo3S13] . 2HO from {Mo3S7Br4}x
166(1)
Bistetraethylammonium-heptasulfidohexabromotrimolybdate, (Et4N)2[Mo3S7Br4]x
166(1)
Nonaaquatrimolybdenum-tetrasulfide, [Mo3S4(H2O)9]4+
167(1)
W3S4(H2O)9]4+ (First Procedure)
167(1)
[W3S4(H2O)9]4+ (Second Procedure)
167(1)
(NH4)2[W3S16(NH3)3] . H2O from {W2S7Br4}x
168(1)
[W3S4(H2O) ]+
168(1)
[MoSe(H2O)9]4+
168(1)
Preparation of [W3Se4(H2O)9]4+ from {W3Se7Br4}x
169(2)
Compounds Of General Interest
The Diphenylmethylenethiophosphinate (MTP) Ligand in Gold(I), Platinum(II), Lead(II), Thallium(I), and Mercury(II) Complexes, sym-Au2(MTP)2, (PPN)[Au(MTP)2], Au2Pt(MTP)4, Au2Pb(MTP)4, AuTI(MTP)4, Hg(MTP)2, Hg(MTP)2(AuCl)2, and HgIIAuI(MTP)2AuIIIC14
171(10)
(Diphenylmethylenethiophosphinato)di-gold(I), [AuCH2P(S)Ph2]2
172(2)
Bis(triphenylphosphoranylidene)ammonium (diphenylmethylenethiophosphinato)gold(I),(PPN){Au[CH2P(S)Ph2]2}
174(1)
Tetrakis(diphenylmethylenethiophosphinato)digold(I) platinum(II) Au2Pt[CH2P(S)Ph2]4
175(1)
Tetrakis(diphenylmethylenethiophosphinato)digold(I)lead(II) Au2Pb[CH2P(S)Ph2]4
176(1)
Bis(diphenylmethylenethiophosphinato)gold(I)thallium(I), 2AuTl[CH2P(S)Ph2]2
177(1)
Bis(diphenylmethylenethiophosphinato)mercury(II), Hg[CH2P(S)Ph2]2
177(1)
Bis(diphenylmethylenethiophosphinato)mercury(II) dichloro-di-gold(I), Hg[CH2P(S)Ph2]2(AuCl)2
178(1)
Bis(diphenylmethylenethiophosphinato)mercury(II)gold(I)-tetrachlorogold(III), HgIIAuI[CH2P(S)Ph2]2AuIIICl4
179(2)
Mesityl-gold(I) Complexes
181(4)
Mesityltriphenylarsine-gold(I) {[Au(mes)(AsPh3)]}
181(1)
(Benzyl)triphenylphosphonium-chloromesitylaurate(I) {BrPPh3[Au(mes)Cl]}
182(1)
Pentamesityl-gold(I) {[Au(mes)]5}
183(2)
An Improved Synthesis of cis-Dithiocyanato-bis(4,4'-dicarboxy-2,2`-bpy)Rut(II) Sensitizer
185(4)
cis-Dichloro-bis(4,4'-dicarboxy-2,2'-bpy)Ru(II) [RuL2(Cl)2]
185(1)
cis-Dithiocyanato-bis(4,4'-dicarboxy-2.2'-bpy)Ru(II) [RuL2(NCS)2]
186(3)
Dimethylsulfoxide Complexes of Platinum(II): K[PtCl3(Me2SO)], cis-[PtCl2L(Me2SO)1](L = Me2SOMeC), [PtCl(μ-Cl)(Me2SO)]2, and [Pt(Me2SO)4](CF3SO3)2
189(7)
Potassium Trichloro(dimethylsulfoxide)platinate(II) (K[PtCl3{(CH3)2SO}])
191(1)
cis-Dichlorobis(dimethylsulfoxide)platinum(II) (cis-[PtCl2{(CH3)2SO}2])
192(1)
cis-Dichloro(acetonitrile)(dimethylsulfoxide)platinum(II) (cis-[PtCl2(CH3CN){(CH3)2SO}])
192(1)
Di-μ-chloro-dichloro-bis(dimethylsulfoxide)diplatinum(II) ([PtCl(μ-cl){(CH3)2SO}]2)
193(1)
Tetrakis(dimethylsulfoxide)platinum(II) bis(trifluoromethanesulfonate) [Pt{(CH3)2SO}2[(CH3)2SO2][SO3CF3]2
194(2)
Tetrasulfur-tetranitride (S4N4)
196(3)
Bis[bis(trimethylsilyl)amino]sulfide {[(Me3Si)2N]2S}
197(1)
Tetrasulfur Tetranitride (S4N4)
198(1)
Hydrotris(methimazolyl)borate
199(4)
Hydrotris(methimazolyl)borate
200(3)
Arsenic(III)bromide
203(1)
Arsenic-tribromide (AsBr3)
203(1)
Dichlorodioxo-bis(triphenylphosphine oxide)uranium(VI) [UO2Cl2(OPPh3)2]
204(2)
Chlorohydro-tris(pyrazol-1-yl)borato-bis(triphenylphosphine) ruthenium(II) {RuCl[k4-HB(pz)3](PPh3)2} (pz = pyrazol-l-yl)
206(2)
Octacarbonyl-di-μ-hydridodirhenium [Re2(μ-H)2(CO)8]
208(2)
Zero-Valent Binuclear Nickel Complexes
210(3)
Di(carbonyl)-(μ-carbonyl)bis[μ-bis(diphenylphosphino) methane]dinickel(0) [Ni2(μ-CO)(CO)2(μ-dpmm)2]
210(1)
Di(isocyanomethane)-(μ-isocyanomethane)bis [μ-bis(diphenylphosphino)methane)di-nickel(0) (Ni2(μ-CNCH3)(CNCH3)2(μ-dpPm)2]
211(2)
Preparation of a Synthetic Ribonuclease: The Europium(III) Complex of 1-(4-nitrobenzyl)-4,7,10-Tris(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane
213(5)
1-(4-Nitrobenzyl)-4,7,10-tetraazacyclododecane (NBC)
214(1)
1-(4-Nitrobenzyl)-4,7,10-tris(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane (NBAC)
215(2)
1-(4-Nitrobenzyl)-4,7,10-tris(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane europium(III)] [[Eu(NBAC)](CF3SO3)3]
217(1)
Carbonyl Halide Tungsten(II) Complexes of Tris(3,5-dimethylpyrazolyl)hydroborate
218(9)
Potassium-tris(3,S-dimethylpyrazolyl)hydroborate (KTp*)
219(1)
3,5-Dimethylpyrazole
219(1)
Potassium Tris(3,5-dimethylpyrazolyl) hydroborate. KTp*
220(1)
Tetraethylammonium Tricarbonyl[tris-(3,5-dimethylpyrazolyl)hydroborato]-tungstate(0) {NEt4(Tp*W(CO)3]}
221(1)
Tricarbonylhalo[tris(3,5-dimethylpyrazolyl)hydroborato] tungsten(11) [Tp*WX(CO)3] (X=Cl, Br)
222(1)
Tp*WCl(CO)3
223(1)
Tp*WBr(CO)3
223(1)
Tricarbonyliodo[tris(3,5-dimethylpyrazolyl)hydroborato] tungsten(II) [Tp*WI(CO)3]
224(1)
Dicarbonylhalo[tris(3,5-dimethylpyrazolyl)hydroborato] tungsten(II) [Tp*WX(CO)2] (X = Cl, Br, I)
225(1)
Carbonyl(acetonitrile-k2N,C)tris(3,5-dimethylpyrazolyl) hydroborato]tungsten(II) [Tp*WI(MeCN-k2N,C)(CO)]
226(1)
A Luminescent Complex of Re(I): fac-[Re(CO)3(bpy)(py)](CF3SO3) (bpy = 2.2'-bipyridine; py = Pyridine)
227(3)
fac-Tricarbonyl(trispyridine)rhenium(I)trifluoromethanesulfonate {fac-[Re(CO)3(py)3](CF3SO3)}
228(1)
fac-Tricarbonyl(2,2'bipyridine)(pyridine)rhenium(I) trifluoromethanesulfonate {fac-[Re(CO)3(bpy)(py)](CF3SO3)}
228(2)
RSi(OH)3 and RSi(NH2)3 [R = 2,6-iPr2C6H3N(SiMe3)]: Synthesis of Stable Organosilanes with Three Functional Groups
230(4)
[2,6-iPr2C6H3N(SiMe3)]Si(OH)3
231(1)
[2.6-iPr2C6H3N(SiMe3)]Si(NH2)3
232(2)
Fluorination with Me3SnF: Synthesis of Cyclopentadienyl-Substituted Group 4 Metal Fluoride Complexes
234(5)
Pentamethylcyclopentadienyl(titanium trifluoride) [η5-C5Me5)TiF3]
234(1)
Pentamethylcyclopentadienyl(zirconium trifluoride) {[(η5-C5Me5)ZrF3]4)
235(1)
Pentamethylcyclopentadienyl(hafnium trifluoride) {[(η5-C5Me5)HfF3]4}
236(1)
Pentamethylcyclopentadienyl(titanium oxofluoride){[(η5-C5Me5)TiFO]4}
236(1)
Pentamethylcyclopentadienyl(titanium imidophenyl fluoride) {[(η5-C5H4Me)TiF(NPh)]2}
237(1)
Bispentamethylcyclopentadienyl(titanium fluoride) (η5-C5Me5)2TiF
238(1)
Seven-Coordinate [MI2(CO)3(NCMe)2], [MI2(CO)3(NCMe)(PPh3)], and Alkyne [MI2(CO)(NCMe)(2-RC2R)2] Complexes of Molybdenum(II) and Tungsten(II)
239(5)
Diiodo(tricarbonyl)bis(acetonitrile)molybdenum(II)/tungsten(II)
240(1)
Diiodo(carbonyl)(acetonitrile)bis(diphenylacetylene) [tungsten(II)]
241(1)
Diiodotricarbonyl(acetonitrile)triphenylphosphine [tungsten(II)]
242(2)
Chlorothiocarbonyl-bis(triphenylphosphine)iridium(I) [IrCl(CS)(PPh)3]2
244(3)
Contributor Index 247(2)
Subject Index 249(6)
Formula Index 255

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