Ion Exchange and Solvent Extraction: A Series of Advances, Volume 16

by SenGupta; Arup K.

• ISBN13: 9780824754891
• ISBN10: 0824754891
• Edition: 1st
• Format: Hardcover
• Copyright: 2004-03-01
• Publisher: CRC Press

Summary

Reflecting the sustained and diverse experimental momentum in the field of ion exchange, Volume 16 summarizes revolutionary advances on par with the consistently high-level research related by this series. This text discusses the kinetics, theoretical models, experimental results/supporting data, and applications for isothermal supersaturation, metal separation via pH-induced parametric pumping, and for ultrapure water (UPW). Topics also include the engineering of activated carbons and carbonaceous materials for removal of metal ions; hydrophobic ionizable organic compounds (HIOCs); the sorption/desorption mechanisms of organic micropollutants in water; and ion exchange process variables on perchlorate treatment.

Table of Contents

Preface	iii
Contributors to Volume 16	xiii
Contents of Other Volumes	xiii
1. Adsorption and Ion-Exchange Properties of Engineered Activated Carbons and Carbonaceous Materials	1	(84)
Michael Streat, Danish J. Malik, and Basudeb Saha
I. Introduction	1	(3)
II. Preparation and Properties of Activated Carbon	4	(16)
III. Characterization of the Surface Chemical Groups in Engineered Carbons	20	(12)
IV. Activated Carbon Fibers and Woven Cloths	32	(3)
V. Sorption of Trace Metals onto Activated Carbon	35	(21)
VI. Summary of Metal Sorption	56	(1)
VII. Sorption of Herbicides on Activated Carbon and Hypercross-Linked Polymers	57	(20)
VIII. Summary of Herbicide Sorption on Activated Carbons and Hypercross-Linked Polymers	77	(1)
IX. Future Trends and Concluding Remarks	78	(3)
References	81	(4)
2. Entropy-Driven Selective Ion Exchange for Hydrophobic Ionizable Organic Compounds (HIOCs)	85	(34)
Ping Li and Arup K. SenGupta
I. Introduction	85	(2)
II. Nature of Solute-Sorbent and Solute-Solvent Interactions	87	(4)
III. Experimental Section	91	(4)
IV. Results and Discussion	95	(21)
V. Conclusions	116	(1)
References	117	(2)
3. Ion-Exchange Isothermal Supersaturation: Concept, Problems, and Applications	119	(92)
Dmitri N. Muraviev and Ruslan Khamkov
I. Introduction	119	(1)
II. Main Features of the IXISS Technique	120	(2)
III. Areas of Potential Application of the IXISS Effect-Wasteless Ion-Exchange Processes	122	(3)
IV. IXISS of Zwitterlyte Solutions	125	(13)
V. Aminecarboxylate Interaction of Zwitterlyte Molecules	138	(22)
VI. Application of IXISS of Amino Acids	160	(5)
VII. IXISS of Inorganic Substances	165	(14)
VIII. IXISS-Based Green Ion Exchange Technologies	179	(24)
IX. Concluding Remarks	203	(2)
References	205	(6)
4. Metal Separation by pH-Driven Parametric Pumping	211	(56)
Wolfgang H. Höll, Randall Kiefer, Cornelia Stöhr, and Christian Bartosch
I. Introduction	211	(1)
II. Basic Principles of pH-Induced Parametric Pumping	212	(4)
III. Development of pH-Induced Parametric Pumping	216	(6)
IV. Experimental Work	222	(3)
V. Application of Strongly Acidic Cation Exchangers	225	(19)
VI. Separation with Weakly Basic Anion Exchangers	244	(17)
VII. Summary and Outlook	261	(2)
List of Symbols	263	(1)
References	263	(4)
5. Selectivity Considerations in Modeling the Treatment of Perchlorate Using Ion-Exchange Processes	267	(72)
Anthony R. Tripp and Dennis A. Clifford
I. Introduction	267	(7)
II. Results and Discussion	274	(28)
III. Computer Modeling	302	(29)
IV. Process Recommendations	331	(2)
V. Summary and Conclusions	333	(3)
References	336	(3)
6. Ion-Exchange Kinetics for Ultrapure Water	339	(36)
Dennis F. Hussey and Gary L. Foutch
I. Introduction	339	(5)
II. Mass Transfer Coefficient-A Method to Evaluate Resin Effectiveness	344	(11)
III. Modeling Approach to UPW Kinetics	355	(14)
IV. Concluding Comments	369	(1)
Nomenclature	370	(2)
References	372	(3)
Index	375