Ionic Liquids in Organic Synthesis

by Malhotra, Sanjay V.

• ISBN13: 9780841274075
• ISBN10: 084127407X
• Edition: 1st
• Format: Hardcover
• Copyright: 2007-01-18
• Publisher: American Chemical Society

Summary

Ionic Liquids in Organic Synthesis brings together leading scientists who have made major contributions to the field of ionic liquids. This book assembles several new methodologies that are interdisciplinary by nature, discussing the unique properties of ionic liquids and the ways in which they induce significant solvent effects on a wide range of pf processes. Twenty-two chapters are included. Ionic Liquids in Organic Synthesis covers areas of rapid progress and industrial importance. Ionic liquids are emerging as novel replacements for volatile organic compounds traditionally used as industrial solvents this book will elaborate on this subject while also examining practical synthetic applications of ionic liquids. This field has been an important topic of research for scientists in both industry and academia over the past 30 years and continues to grow.

Table of Contents

Preface

The Interaction Affecting Organic Reactivity and Selectivity in Ionic Liquids

Electrophilic Chemistry in Ionic Liquids

Electropolymerization of Benzene in an Ionic Liquid

Onium-Poly (Hydrogen Fluorides):Convenient Ionic Liquids for Fluorination and Acid Catalysis

Diels-Adler and Friedel-Crafts Reactions in Pyridinium-Based Ionic Liquids

Organic Synthesis in Ionic Liquids Utilizing Organometallic Reagents

Transition Metal Complexes in Imidazolium Ionic Liquids as Recoverable and Reusable Homogeneous Catalysts

Approches to Imino Diels-Adler Reactions in Imidazolium Ionic Liquids

Sythesis of Homoallyl Ethers via Allylation of Acetals and Aldehydes in Ionic Liquids

Room Temperature Ionic Liquids as Homogeneous Supports for Synthesis

Ionic Liquids as a Support of Organic and Inorganic Catalysts

Ionic Liquids Applications in Green Chemistry: Copper and Zinc Catalysis

Ionic Liquid: A Green Solvent for Organic Transformations

Ionic Liquid: A Green Solvent for Organic Transformations

Ionic Liquids: Neoteric Solvents of Organic and Biocatalytic Transformations

Toward Green Processes for Fine Chemcials Synthesis: Biocatalysis in Ionic Liquid-Supercritical Carbon Dioxide Biphasic System

Ruthenium Catalyzed Asymmetric Hydrogenation of ?- and ?- Ketoesters in Room Temperature Ionic Liquids Using Chiral P-Phos Ligand

Organocatalyzed Asymmetric Michael Reaction in Ionic Liquids-Carbon Dioxide

Enantiomerically Pure Thiazolinium and Imidazolium Low Melting Point Salts Prepared for ?-AminoacidsDelpine Bregeon

New Cations for Ionic Liquids, Including Chiral Adjuncts with Phosphate and Sulfonylimide Anions

Tailoring Adsoprtion-Desorption Properties of Hydroamination Catalysts with Ionic Liquids

Synthesis and Application of New Ionic Liquids with Tris(perfluoroalkyl)trifluorophosphate Anions

Author Index

Subject Index

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