Microporous and Macroporous Materials

by Lobo, Raul F.; Beck, Jeffrey S.; Suib, Steven L.; Corbin, David R.; Davis, Mark E.

• ISBN13: 9781558993341
• ISBN10: 1558993347
• Format: Hardcover
• Copyright: 1996-09-01
• Publisher: Materials Research Society

Summary

Explosive growth has been seen in research on both microporous and mesoporous molecular sieves. Accordingly this book focuses on major advances in synthesis, characterization and applications of porous materials. It opens with a section on synthetic approaches to zeolites, pillared materials, sol-gel materials and mesoporous materials. New types of microporous materials are described, including the preparation of microporous metal-organic solids which have both organic and inorganic building units in the structure. The area of mesoporous molecular sieves is also featured. Creative synthetic methods in this area have allowed design tailoring of composition, pore size, structure and texture. New mesoporous compositions are described, including hexagonal, transition metal-oxide structures. Such compositions may have catalytic uses. To complement the synthetic areas, advanced characterization techniques are also discussed. These include new methods for studying porosity, as well as advanced spectroscopic techniques. Applications of microporous and mesoporous materials include the areas of adsorption, batteries, catalysis, ceramic precursors, nonlinear optical materials, electronic conductivity, sensors, and similar areas.

Table of Contents

Preface	xiii	(1)
Materials Research Society Symposium Proceedings	xiv
PART 1: ZEOLITIES, CLAYS AND MICROPOROUS MATERIALS	3	(74)
Synthesis, Characterization, and Reactivity of Feitknechtite	3	(6)
J. Luo
S.R. Segal
J.Y. Wang
Z.R. Tian
S.L. Suib
Local Microstructural Organization in Carbogenic Molecular Sieves	9	(6)
Michael S. Kane
Henry C. Foley
Structural, Textural and Catalytic Properties of Al-, Ti-Pillared Clays	15	(6)
C.E. Ramos-Galvan
J.M. Dominguez
G. Sandoval-Robles
A. Castillo-Mares
N. Nava E.
The Synthesis, Structure and Catalytic Properties of Some Aluminophosphate and Gallophosphate Materials Prepared Using Chiral Metal Complex Templates	21	(6)
A.P. Wilkinson
M.J. Gray
S.M. Stalder
*Synthesis and Crystal Structure of ULM-16, a New Open Framework Fluorinated Gallium Phosphate with 16-Ring Channels	27	(12)
Thierry Loiseau
Gerard Ferey
Designer Carbons Templated by Pillared Clays: Lithium Secondary Battery Anodes	39	(6)
G. Sandi
K.A. Carrado
R.E. Winans
J.R. Brenner
G.W. Zajac
Vanadium Molecular Sieve, VAPO-5: Preparation and Electrochemical Characterization	45	(6)
F. Bedioui
E. Briot
J. Devynck
K.J. Balkus, Jr.
Synthesis and Characterization of Ln/Al Pillared Clays	51	(6)
A. Lopez-Ortega
J.M. Dominguez
A. Rojas-Hernandez
A. Benitez-Patricio
M. Salmon
ULM-12 and ULM-19: The Hydrated and Anhydrous Forms of the First Synthetic Oxyfluorinated Iron Phosphate with an Open Structure	57	(6)
Myriam Cavellec
Didier Riou
Jean Marc Greneche
Gerard Ferey
Electrical Behaviour of Natural Manganese Dioxide (NMD)	63	(6)
H.F. Gorgulho
R.Z.D. Fernandes
J.M. Pernaut
Porous Materials from Fly Ash	69	(8)
Jorge G. Moller
Wei-Heng Shih
PART II: MESOPOROUS MATERIALS	77	(60)
The Synthesis and Characterisation of Ordered Mesoporous Materials Incorporating Organo-Siloxanes	77	(6)
Stephen D. Sims
Sandra L. Burkett
Stephen Mann
Direct Synthesis of Acidic Aluminosilicate Mesoporous Molecular Sieves	83	(6)
Robert Mokaya
William Jones
Immobilization of Cobalt Complexes on Mesoporous MCM-41 Support Materials	89	(6)
J.M. Diaz
F. Bedioui
E. Briot
J. Devynck
K.J. Balkus
Periodic Mesoporous Silica Gels	95	(6)
M.T. Anderson
J.E. Martin
J.G. Odinek
P. Newcomer
J.P. Wilcoxon
*Mesostructured Zirconium Oxide	101	(10)
P. Liu
J.S. Reddy
A. Adnot
A. Sayari
Influence of the Synthesis Parameters on Textural and Structural Properties of MCM-41 Mesoporous Materials	111	(6)
E. Terres
S.S. Ramirez
J.M. Dominguez
A. Montoya
J. Navarrete
M. Gomez-Cisneros
Emission Control Catalyst Derived from Mesoporous Molecular Sieves	117	(6)
Partha P. Paul
Michael A. Miller
Martin J. Heimrich
Stuart T. Schwab
Structural Evolution in Carbon Aerogels as a Function of Precursor Material and Pyrolysis Temperature	123	(6)
J. Gross
C.T. Alviso
R.W. Pekala
Mesoporous TiO2 Electrodes for Photovoltaic Applications	129	(8)
C.J. Barbe
M. Greatzel
PART III: METHODS OF STUDYING POROSITY	137	(74)
The Band at "960"	137	(10)
S. Schwarz
D.R. Corbin
A.J. Vega
Computer Simulation of Xe Adsorption in Zeolite Y	147	(6)
Vishwas Gupta
H. Ted Davis
Alon V. McCormick
Coadsorption of Nitriles and CO on Cu-ZSM-5: An In Situ FTIR Spetroscopic Study	153	(6)
J. Szanyi
M.T. Paffett
Potentialities of an Innovative Technique Like 129Xe NMR and of SAXS for the Characterization of Microporous Sol-Gel Derived SiO2	159	(6)
L.C. de Menorval
A. Julbe
H. Jobic
J.A. Dalmon
C. Guizard
Spectroscopy of Iron Germanium Sulfide Open-Framework Materials and Precursors	165	(6)
Scott J. Kirkby
Geoffrey A. Ozin
Porous Silicon Structural Evolution from In-Situ Luminescence and Raman Measurements	171	(6)
D.R. Tallant
M.J. Kelly
T.R. Guillinger
R.L. Simpson
*NMR Studies of Hydrofluorocarbon-Cation Interactions and Cation Migrations on Adsorption of Hydrofluorocarbon-134 on Zeolites NaY and CsY	177	(8)
Clare P. Grey
Faiza I. Poshni
Yong Ba
David R. Corbin
Preparation of Microporous Films with Sub Nanometer Pores and Their Characterization Using Stress and FTIR Measurements	185	(6)
J. Samuel
A.J. Hurd
F. van Swol
L.J. Douglas Frink
C.J. Brinker
S.C. Contakes
Do Alkali Metal Anions (M-)Exist in Zeolite A?	191	(6)
P.D. Barker
P.A. Anderson
R. Dupree
S. Kitchin
P.P. Edwards
L.J. Woodall
Continuum and Stochastic Modeling on the Role of Gel Microstructure in Zeolite Crystallization	197	(6)
Michael Tsapatsis
Dionisios G. Vlachos
Neutro Vibrational Spectroscopy of the H5O2+ Ion and Its Deuterated Analog in Phosphotungistic Acid Hexahydrate	203	(8)
N.C. Maliszewskyj
T.J. Udovic
J.M. Nicol
PART IV: THIN FILMS AND ADSORPTION	211	(68)
Growth and Engineering of Microporous Zeolite Films and Coatings	211	(6)
Y. Yan
S. Ray Chaudhuri
A. Sarkar
Synthesis of Periodic Mesoporous Silica Thin Films	217	(8)
M.T. Anderson
J.E. Martin
J.G. Odinek
P. Newcomer
*Preparation of Supported Zeolite Films and Layers: Processing of Zeolite Suspensions and In Situ Growth	225	(12)
Mark C. Lovallo
Laura Boundreau
Michael Tsapatsis
Zeolite Membranes from Kaolin	237	(8)
B.G. Karle
C.J. Brinker
M.L.F. Phillips
Preparation of Continuous Mesoporous Films on Porous and Dense Substrates	245	(6)
J. Liu
J.R. Bontha
A.Y. Kim
S. Baskaran
Special Hysteresis Effects in N2-Sorption and Mercury-Porosimetry Measurements	251	(8)
Herbert Giesche
Microstructural Analysis and Modelling of Thin Porous Silicon Layers with Variable Angle Spectroscopic Ellipsometry	259	(6)
L.A.A. Pettersson
S. Zangooie
R. Bjorklund
H. Arwin
Nanostructural Study of Luminescent Porous Polycrystalline Thin Silicon	265	(6)
M.C. Poon
P.G. Han
J.K.O. Sin
H. Wong
A New Class of Microporous Materials: Porous Metal Phosphonate Thin Films	271	(8)
Lori A. Vermeulen
J. Pattanayak
Travis Fisher
Monica Hansford
Scott J. Burgmeyer
PART V: SOL-GEL SYNTHESIS OF METAL OXIDES AND NITRIDES	279	(52)
Synthesis and Structural Studies of Microporous Yttriastabilized Zirconia Ceramics	279	(6)
R. srinivasan
D.E. Sparks
D.R. Milburn
B.H. Davis
Proteins Encapsulated in Porous Sol-Gels: Biomolecules as Pore Structure Templates	285	(6)
B.C. Dave
B. Dunn
J.S. Valentine
J.I. Zink
Aerogel Synthesis Using Extractive Drying	291	(6)
D.M. Smith
W.C. Ackerman
R. Roth
A. Zimmerman
F. Schwertfeger
A Rapid Supercritical Extraction Process for the Production of Silica Aerogels	297	(6)
J.F. Poco
P.R. Coronado
R.W. Pekala
L.W. Hrubesh
Porous Silica Doping by Ion Bombardment	303	(6)
G.F. Cerofolini
L. Meda
A. Anselmino
G. Ranghino
Si3N4 Whisker Upper Layer Formation on A Sic-Al2O3 Porous Body	309	(6)
P. Toro
A. Perez
B. Baeza
G. Piderit
P. Rojast
Characterization of Porous AIN and Separators for Batteries	315	(8)
Brett N. Thorsland
Herbert Giesche
Thomas J. Mroz
Michael Martin
Sol-Gel Polymerization of Tetraalkoxygermanium and Organotrailkoxygermanium Monomers	323	(8)
Brigitta M. Baugher
Douglas A. Loy
PART VI: APPLICATIONS OF POROUS METAL OXIDES	331	(56)
Sol-Gel Process from Heterometallic Alkoxides to Incorporate Alkaline- and Rare Earths in Alumina for Automotive Applications	331	(6)
C.K. Narula
Synthesis, Characterization and Catalytic Properties of Al2O3-TiO2 Mixed Oxides Prepared by Sol-Gel	337	(6)
A. Montoya
J. Melendez-Hernandez
J.M. Dominguez
G. Sandoval-Robles
Gas Permeation and Microstructure of Silica Membranes Prepared Using an Organic Template Approach by Sol-Gel Processing	343	(6)
G.Z. Cao
C.J. Brinker
Sol-Gel Processed Alumina Based Materials in Microcalorimeter Sensor Device Fabrication for Automotive Applications	349	(6)
S.R. Nakouzi
J.R. McBride
K.E. Nietering
C.K. Narula
Nanochannel Glass Replica Membranes for Parallel Patterning Applications	355	(6)
D.H. Pearson
R.J. Tonucci
C.R. Eddy, Jr.
Optical Properties of Si Nanoclusters with Passivated Surface	361	(6)
L.N.Dinh
L.L. Chase
M. Balooch
W.J. Siekhaus
F. Wooten
High-Pass Optical Filters Based on Gold-Coated Nanochannel Glass Materials	367	(6)
A. Rosenberg
R.J. Tonucci
Optical Interference Filters Made of Porous Silicon	373	(6)
M. Thonissen
M.G. Berger
M. Kruger
S. Billat
R. Arens-Fischer
O. Gluck
H. Luth
S. Hilbrich
W. Theiss
P. Grosse
Effect of Preparation Parameters on the Microporous Structure of Ni/SiO2 Catalysts	379	(8)
F.F. Castillon
N. Bodganchikova
S. Fuentes
M. Avalos
PART VII: POROUS SEMICONDUCTORS	387	(88)
Fabrication of InAs Wires in Nanochannel Glass	387	(6)
A.D. Berry
R.J. Tonucci
P.P. Nguyen
Activated Carbon Filaments with Mainly Mespores	393	(6)
Weiming Lu
D.D.L. Chung
Graphitized Needle Cokes and Natural Graphites for Lithium Intercalation	399	(6)
T.D. Tran
L.M. Spellman
R.W. Pekala
W.M. Goldberger
K. Kinoshita
Effect of Processing Variables on the Microstructure and Mechanical Properties of Microporous Carbon Materials	403	(6)
M. Singh
R.F. Dacek
The Influence of Precursor Structure on the Development of Porosity in Polymer-Derived SiC	409	(6)
J.F. Nebo
C.S. Scotto
C.A. Bennett
C.J. Brinker
Bicontinuous Cubic Phase as a Matrix for the Synthesis of Semiconductor Nanocrystallites	415	(6)
Jianping Yang
Syed Qadri
Banahalli Ratna
Magnetic Properties of Uniform Nanowire Arrays	421	(6)
P.P. Nguyen
R.J. Tonucci
Gas Sensing Behavior of Porous ZnO Varistors Densified via Rate Controlled Sintering	427	(6)
Gaurav Agarwal
Robert F. Speyer
From Graphite to Porous Carbon Containing Nanoparticles through Chemical Reactions	433	(6)
C.C. Hung
J. Corbin
*Formation and Properties of Porous GaAs	439	(10)
P. Schmuki
D.J. Lockwood
J.W. Fraser
M.J. Graham
H.S. Isaacs
Photonic Band Structure of Nanochannel Glass Materials	449	(6)
A. Rosenberg
R.J. Tonucci
H.-B. Lin
Colloidal Processing of Temperature Shock Resistant SiC with Tailored Porosity	455	(6)
Mesut Aslan
Rudiger Nass
Helmut Schmidt
A Comparison of the Electrochemical Behavior of Carbon Aerogels and Activated Carbon Fiber Cloths	461	(6)
T.D. Tran
C.T. Alviso
S.S. Hulsey
J.K. Nielsen
R.W. Pekala
Electronic Doping in Porous Nano-Crystalline ZnO Films	467	(8)
R. Konenkamp
A. Wahi
PART VIII: POROUS POLYMERS	475	(64)
Nanofoam Porosity Measured by Infrared Spectroscopy and Refractive Index	475	(6)
M.I. Sanchez
J.L. Hedrick
T.P. Russell
Tailoring the Pore Size of Hypercrosslinked Polymer Foams	481	(6)
W.P. Steckle, Jr.
M.A. Mitchell
P.G. Apen
Nanoporous Polyimide Films from Polyimide-Aliphatic Polyester or Polyimide-Aliphatic Polycarbonate Copolymers	487	(10)
K.R. Carter
J.L. Hedrick
R. Richter
P.T. Furuta
D. Mecerreyes
R. Jerome
Permeability and Structure of Resorcinol-Formaldehyde Gels	497	(6)
G.W. Scherer
C. Alviso
R. Pekala
J. Gross
Heterogeneous Microcomposite Materials Based on Porous Matrices and Liquid Crystals	505	(6)
F.M. Aliev
G.P. Sinha
Microporous Crosslinked Elastomers	511	(10)
J.L. Hedrick
S. Srinivasan
R.D. Miller
D.Y. Shih
Y.-H. Liao
J.G. Hilborn
C.J.G. Plummer
A. Della Martina
Resorcinol-Formaldehyde and Carbon Aerogel Microsheres	521	(6)
C.T. Alviso
R.W. Pekala
J. Gross
X. Lu
R. Caps
J. Fricke
Macroporous Thermosets via Chemically Induced Phase Separation	527	(6)
J. Kiefer
R. Porouchani
D. Mendels
J.B. Ferrer
C. Fond
J.L. Hedrick
H.H.Kausch
J.G. Hilborn
Morphological Characterization of Furfuraldehyde Resins Adsorbents	533	(6)
R. Sanchez
S.N. Monteiro
J.R. D'Almeida
Improving Thermal Performance of High Internal Phase Emulsion Polymerized Foams with Maleimide Based Monomers	539	(6)
Mark A. Hoisington
Joseph R. Duke
David A. Langlois
Author Index	545	(4)
Subject Index	549