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9780901716521

Modifications of Passive Films

by ;
  • ISBN13:

    9780901716521

  • ISBN10:

    0901716529

  • Format: Nonspecific Binding
  • Copyright: 1994-01-01
  • Publisher: CRC Press

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Summary

The modification of passive films is a promising method of improving the corrosion resistance of metallic materials. As well as reviewing a wide spectrum of film modifications and their effects on passivity and to corrosion resistance, papers presented at this international symposium deal with chemical composition, chemical states and electronic properties of passive films.

Table of Contents

Series Introduction
Preface
Influence of Ternary Elements on the Chloride Composition of Passive Films on Iron-Chromium Alloysp. 1
Composition of Passive Films on Stainless Steels Formed in Neutral Sulphate Solutionsp. 6
Characterisation of Surface Films on FeCrPC Alloys by XPS and X-ray Excited Auger Peaksp. 12
Modifications of Passive Films formed on Ni-Cr-Fe Alloys with Chromium Content in the Alloy and Effects of Adsorbed or Segregated Sulphurp. 17
Influence of Fe and Mo Alloying Elements on the Composition of Passive Films Formed on Ni-Cr Alloys in an Acidic Chloride Solutionp. 26
Depth Composition of Passive Films Grown on Fe-Cr Alloys in Borate Solutions: Influence of the Chromium Bulk Concentrationp. 35
Chemical Composition of Naturally Formed Oxide on MgAl Alloysp. 41
Examination of Passive Layers on Fe/Cr, Fe/Ni and Cu/Ni Alloys with Ion Scattering Spectroscopy (ISS)p. 46
In Situ Xanes Studies of the Passive Film on Fe and Fe-26Crp. 57
Scanning Tunnelling Microscopy Study of the Atomic Structure of the Passive Film Formed on Nickel Single Crystal Surfacesp. 62
Atomic-Resolution STM of Passive Films on Fe-Cr Alloysp. 66
AFM Studies of EFC Round Robin Alloy 516 Relating to the Role of Mo in Passivationp. 70
Photoelectrochemical Study of Passive Filmsp. 76
Modifications of the Structural and Electronic Properties of Thermochemically Formed Passive Films on Fe-Cr Alloys during Long Term Ageing: Influence of Silicon Additionp. 85
Polarisation and pH Effects on the Semiconducting Behaviour of Passive Films Formed in Chloride Containing Aqueous Solutionsp. 91
Modification of the Passivating Film on Copper in the Presence of Benzotriazole: Photoelectrochemical Characterisationp. 96
Kinetics of Film Formation on Fe-Cr Alloysp. 102
Influence of Anions on the Electrochemical Behaviour of Passive Ironp. 108
Modifications of Passive Films on 304 Stainless Steel Investigated by Capacitance Measurementsp. 114
Passive Characteristics of Amorphous Ni-P Alloysp. 119
Passivity of Chromium in Concentrated and Anhydrous Solutions of Sulphuric Acidp. 123
Influence of Electrochemical Formation Conditions on the Stability of Passive Layers Formed on Fe17%Cr Stainless Steel in Sulphuric Acidp. 128
Identifiability and Distinguishability of Passivation Mechanisms by Electrochemical Impedance Spectroscopy and Electrogravimetric Transmittancep. 134
Electrochemical Dissolution of [actual symbol not reproducible] Amorphous Alloy and h. e. r. Investigation on the Anodically Activated Alloyp. 139
Growth/dissolution Processes of Anodic Films Formed on Titanium under [alpha]-irradiation, Studied by Coupling Electrochemistry and Inductively Coupled Plasma Atomic Emission Spectrometryp. 144
Characterisation of Passive Layers of Bronze Patinas (Cu-Sn Alloys) in Relation with the Tin Content of the Alloyp. 150
Hydrogen Permeation Through Passive Films on Ironp. 155
Hydrogen and Iron Transport Through Passive Oxide Films on Electropolished Ironp. 161
Electrode Reaction Inhibition by Surface Modification and Localised Corrosion Resistance of Stainless Steels in Aqueous Solutionp. 168
Modification of Passive Zinc by Alloying Elementsp. 173
Modification of Passive Films on 304L by Cyclic Polarisation Influence on Film Stability in Acidic Environmentsp. 176
Surface Modification of Stainless Steel by an Alternating Voltage Processp. 183
Modification of Passive Films Composition due to Water Ageingp. 188
Chromate-free Surface Treatment: MolyPhos - A New Surface Conversion Coating for Zinc. Optimising the Treatment by Corrosion Testingp. 195
Passive Film Evolution on Stainless Steels with the Medium Composition: Electrochemical Studies in the Presence of Chloride and Molybdate Ionsp. 198
Passive films on Glassy FeCrPC Alloy - The Role of Phosphorus in Stabilityp. 202
Modification of Ta/Ta[subscript 2]O[subscript 5] Films by Platinum Depositsp. 206
The Effect of Pretreatments on the Corrosion Behaviour of Aluminiump. 214
The Effect of Hydrostatic Pressure on the Modification of Passive Films Formed on 316L Stainless Steel in Sea Waterp. 220
Effect of Laser Surface Remelting on Passivity and its Breakdown on Al-Si Alloysp. 225
Laser Pulsed Irradiation of Passive Filmsp. 230
Irradiation Effects in Anodic Oxide Films on Titaniump. 234
Modification of Oxide Films by Ion-Implantation and its Influence on the Corrosion Behaviourp. 240
Simulation of [gamma]-Ray Effects on Passive Films by Laser Irradiationp. 246
Passivation of Metals by Plasma-Polymerised Filmsp. 253
Fundamental Aspects in the Design of Passive Alloysp. 262
In Situ AFM Investigation of Pittingp. 274
Passivity of Non-metallic Inclusions in Stainless Steels and their Effect on Resistance Against Pittingp. 280
Inclusions in Stainless Steels - Their Role in Pitting Initiationp. 290
Influence of Ion Implanted Molybdenum or Molybdate Solution on Pitting Corrosion of 304 Stainless Steel in Chloride Solutions. Statistical Study by Digital Image Analysis of Pit Initiation and Propagationp. 296
The Effect of pH and Potentiostatic Polarisation on the Pitting Resistance of Stainless Steels: Relation to Non-metallic Inclusions or Passive Film Modificationsp. 300
Localised Corrosion of Laser Surface Alloyed 7175-T7351 Aluminium Alloy With Chromiump. 308
The Problem of Convective Diffusion in Laser Pit Initiationp. 313
Pitting Corrosion of Heat-tinted Stainless Steelp. 316
Pitting Corrosion Susceptibility of Oxide Layers in the Amorphous Alloy [actual symbol not reproducible]p. 322
Influence of the Energetic [beta]-Flux on the Corrosion Behaviour of Zr Alloysp. 326
Influence of Ion Implantation on Corrosion and Stress Corrosion Cracking of 304L Stainless Steelp. 330
Development of a Neural Network Model for Predicting Damage Functions for Pitting Corrosion in Condensing Heat Exchangersp. 336
Table of Contents provided by Blackwell. All Rights Reserved.

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