Multifunctional Conducting Molecular Materials

by Saito, Gunzi; Wudl, Fred; Haddon, Robert C.; Tanigaki, Katsumi; Enoki, Toshiaki

• ISBN13: 9780854044962
• ISBN10: 0854044965
• Format: Hardcover
• Copyright: 2006-11-30
• Publisher: Royal Society of Chemistry

Summary

The use of conducting molecular materials is a rapidly developing, multidisciplinary field of research, offering a wide variety of possibilities for the future. It is of particular relevance to nano fabrication and technology because it offers high density, small size integrated and multifunctional properties that can be fabricated under mild conditions. Multifunctional Conducting Molecular Materials covers a wide range of topics including: molecular conductors and superconductors; design and synthesis of functional molecular materials; organic/inorganic hybrids and photoinduced phenomena; fullerenes, nanotubes and other related nano materials. The book concludes with a look at integration and functionalities of molecular materials such as organic field effect transistors (OFET). This high level book is ideal for researchers in both industry and academia who are interested in this new and exciting field.

Table of Contents

Mesomeric fused betainic radicals as organic conductors	p. 3
TTF based materials : from exotic organic superconductors to transistors	p. 15
Two isomeric methylenediseleno-diselenadithiafulvalenes (MDSE-TS and MDSE-ST) : synthesis and properties of new selenium-containing fulvalene-type electron donors	p. 23
Correlation and frustration effects in molecular conductors Et[subscript x]Me[subscript 4-x]Z[Pd(dmit)[subscript 2]][subscript 2] (dmit = C[subscript 3]S[subscript 5][superscript 2-], Z = N, P, As, Sb, x = 0, 1, 2)	p. 31
Electric field effect of quantum oscillations in few-layer graphene in high magnetic fields	p. 39
New single-component molecular conductors with diselenadithiafulvalene frameworks	p. 45
Charge transfer complexes of cytosine and TCNQ derivatives	p. 49
Electron donors from natural products : donating and ligating ability and charge-transfer complex formation of imidazo[1,2-a]pyrazin-3(7H)-ones	p. 55
One-dimensional alternating antiferromagnetic chain accompanying charge ordering in DODHT organic superconductors	p. 59
Dimethyl-substituted analogue of BDH-TTP, DMDH-TTP, and its metallic salts	p. 63
Monooxygen-containing analogues of DHDA-TTP, DHOTA-TTP and OTDA-TTP and their charge-transfer salts	p. 67
TTF derivatives linking a dimethyldioxolane ring and their charge-transfer salts	p. 71
Structures and electrical properties of new PDT-TTP conductors	p. 75
Crystal structures and physical properties of (Mo[subscript 6]X[subscript 14])[superscript 2-] salts (X = Br, I)	p. 79
Pronounced enhancement of charge ordering transition temperatures in TMTTF salts with deuteration	p. 83
Raman spectroscopy of k-(BEDT-TTF)[subscript 2]Cu[N(CN)[subscript 2]]I	p. 87
Charge disproportionation with metallic conductivity in new ET salt, (ET)[subscript 3](AuBr[subscript 2])[subscript 2](AuBr[subscript 4])[subscript 2](solv)[subscript x], having a peculiar crystal structure	p. 91
Nano-size molecular conductors directly formed on silicon substrates	p. 97
Theoretical studies of interdimer parameters in [beta]'-Me[subscript 4]P[Pd(dmit)[subscript 2]][subscript 2] crystals and its spin frustration	p. 101
Recent progress of (EDO-TTF)[subscript 2]PF[subscript 6] and related complexes	p. 107
Crystal structures and physical properties of (EDO-TTF)[subscript 5](BF[subscript 4])[subscript 3] and (EDO-TTF)[subscript 4](Sb[subscript 2]F[subscript 11])[subscript 0.85](H[subscript 2]O)[subscript 4]	p. 115
Ionicity of intramolecular charge transfer compounds in solution	p. 119
Structures and thermal behavior of intramolecular charge transfer compounds C[subscript n]-H3CNQ derived from the reaction between l-alkyl-3,3-dimethyl-2-methyleneindoline and 7,7,8,8-tetracyanoquinodimethane (TCNQ)	p. 123
Synthesis and properties of DT-TTF derivatives possessing dicyanomethylene group as the acceptor unit	p. 127
NMP TCNQ based molecular wires	p. 131
Ethylenedithio-TTF-imidazole : construction of pluri-dimensional network by hydrogen-bonding and SäS interactions	p. 135
New strategies for designing TTP-based donor molecules	p. 139
Synthesis, physical properties and crystal structures of a new asymmetrical MDOB-EDT-TTF and its charge-transfer complexes	p. 143
The first metallic salt containing ferrocene, [beta]"-(BEDT-TTF)[subscript ä](Fe(CpCONHCH[subscript 2]SO[subscript 3])[subscript 2])-2H[subscript 2]O, and novel ferrocene containing anions, CpFeCpCONH-(m-, p-)C[subscript 6]H[subscript 4]SO[subscript 3][superscript -]	p. 147
Unconventional magnetotransport in 1D TTF-based [pi]-d interaction systems	p. 153
Magnetic conductors based on new ethylenedioxy-substituted donors with a bent molecular structure	p. 161
Crystal structure and physical properties of the new organic conductors (EDT-TSF)[subscript 2]GaCl[subscript 4] and (EDT-TSF)[subscript 2]FeCl[subscript 4]	p. 165
Synthesis and property of tetrathiafulvalene-pendent iron complexes	p. 169
Gigantic and ultrafast photoresponse in molecular charge ordering system	p. 173
Photochemical transformation of molecular crystals into devices	p. 181
Theory of optical responses of photoexcited halogen-bridged metal complexes in different insulating phases	p. 185
Electric transport and modulated density of states in rotational order and disorder in Na[subscript 2]CsC[subscript 60]	p. 191
Ultraviolet photoelectron spectroscopy of endohedral fullerenes	p. 198
Manipulation and assembly of carbon nanotubes by dielectrophoresis	p. 206
Superconducting phase made from C[subscript 60] doped with lanthanum	p. 212
Electric transport properties of doped C[subscript 60] nanowhiskers	p. 216
Variable range hopping conduction and magnetic anomalies in ordered mesoporous carbon materials CMK-n	p. 220
Magnetic properties of hydrogenated and fluorinated surface layer of diamond nanoparticle	p. 224
Modelling and designing of nano-carbon magnets by a new density-matrix functional theory	p. 232
Eight unimolecular rectifiers	p. 239
Molecular assemblies : bridging the gap to form molecular junctions	p. 248
Study of hole injection in hole-only single-carrier devices	p. 253
Schottky-gated polymer FET fabricated by multiple laser printing method	p. 270
Mechanism of ambipolar field-effect transistors on one-dimensional organic Mott insulators	p. 276
Self-assembled monolayers modification on electrodes of organic thin-film transistors	p. 282
Organic field-effect transistors based on phenyl substituted tetrathiafulvalene derivatives	p. 286
Organic semiconductors based on nickel complexes for thin-film transistors	p. 290
Poly(p-phenylenevinylene) nanofiber yarns fabricated by electrospinning	p. 294
Paper actuators with conducting polymers	p. 298
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