Organic/Inorganic Hybrid Materials 2004

by Chujo, Y.; Laine, R. M.; Sanchez, C.; Schubert, U.

• ISBN13: 9781558997950
• ISBN10: 1558997954
• Format: Hardcover
• Copyright: 2005-07-29
• Publisher: Cambridge Univ Pr

Summary

Interest in hybrid materials has accelerated recently, in particular because tailoring materials properties through organization of organic/inorganic composites at nanometer length scales is now an important focus for numerous diverse research domains. Hybrid materials research is further motivated by efforts to build structures and hierarchies nanometer-by-nanometer in one, two or three dimensions. Still a third motivation derives from the roadmap that guides miniaturization in the electronics and photonics industries. Finally, efforts towards hybrid materials are also driven by the scientific challenges involved in the creation of new forms of matter (nonlinear properties) and the potential to discover and develop completely new scientific principles. As with previous volumes in this popular series, the objective here is to create a communal forum for researchers involved in all areas of organic/inorganic hybrid materials to share perspectives, to learn about leading-edge science and engineering occurring around the world, and to develop new ideas/points of view and collaborations. The volume is divided into focus areas that address synthesis and characterization methods, functional hybrid materials, hybrid materials influenced by biology, structured mesoporous materials and materials with multiscale organization. Topics include: methods of patterning hybrid materials; hybrid materials for photonic applications; mesoporous films and monoliths; biofunctional materials; layered hybrid materials; applications-oriented hybrid materials; hybrid materials for electronics, optoelectronics and semiconductor applications; methods of characterizing hybrid materials; and novel synthetic methods.

Table of Contents

From raspberry-like to dumbbell-like hybrid colloids through surface-assisted nucleation and growth of polystyrene nodules onto macromonomer-modified silica nanoparticles	p. 3
Two-dimensional crystalline lattice templating : a new method for the preparation of polymer-covered metal and alloyed metal nanorods by a redox process	p. 13
Single-step microstructure patterning in titania-doped sol-gel glassy thin films with electron beams	p. 19
A novel method for rapid formation of high-ordered self- assembled monolayer	p. 25
Novel organosilanes for the preparation of high refractive index silicone coatings	p. 33
Reliability analysis of an inorganic-organic hybrid sol-gel material system for waveguiding applications	p. 39
Photo-induced optical and chemical properties of polysilane/inorganic nano-hybrids	p. 45
Affinity control of aminopropylsiloxane-based organic/inorganic hybrids for optical sensors	p. 57
Photoluminescence-structure relationships in ormosils for integrated optical devices	p. 63
Femtosecond fluorescence studies of auramine O in hybrid sol-gel derived films	p. 69
Di-urethane cross-linked poly(oxyethylene)/siloxane nanohybrids doped with Eu(CF[subscript 3]SO[subscript 3])[subscript 3]	p. 75
Er[superscript 3+]-doped polyether/siloxane hybrid materials for optoelectronics	p. 81
B and P glass formers as stabilizers of luminescent Ce(III) in silica-based glasses	p. 87
Crystallization of POSS in a PEG-based multiblock polyurethane : toward a hybrid hydrogel	p. 93
Evolution of porosity and morphology in alkylene-bridged polysilsesquioxane xerogels as a function of gel aging time	p. 99
Synthesis of nanomaterials in highly swollen liquid crystals	p. 107
Hierarchical macro-mesoporous silica monolith	p. 121
Inorganic-organic hybrid hierarchically structured methyl-modified silica monoliths	p. 127
From hybrid films to mesoorganized multi-metal-oxide nanocrystalline films (M[subscript 3]NF), preparation and characterization	p. 135
Monolithic O/I-hybrids with hierarchically ordered meso- and macropores	p. 147
Macrocellular silica monoliths hierarchically textured : mesostructured Si-HIPE materials	p. 159
Collapse of porosity during drying of alkylene-bridged polysilsesquioxane gels : influence of the bridging group length	p. 165
Air-liquid foams, concentrated direct emulsion and soft chemistry toward hierarchically organized porous silica monoliths	p. 171
Iron oxide - doped mesostructured silica films	p. 177
Influence of TiO[subscript 2] on the pore structure and texture of SiO[subscript 2]-PDMS hybrid materials	p. 183
Rational design of macrocellular TiO[subscript 2] and V[subscript 2]O[subscript 5] monoliths obtained through soft chemistry and air-liquid foams	p. 189
Inorganic-organic hybrid materials from layered double hydroxide structure and their subsequent carbonaceous repliqua	p. 195
Three dimensional structure and liquid transport behavior of siloxane gels with co-continuous macropores	p. 203
Bioactive organic-inorganic hybrid aerogels	p. 211
Sol-gel silica particles for controlled release applications	p. 217
LDH-DNA nanohybrids : a complete biophysical characterization	p. 223
Mineralization of water-in-oil emulsion droplets	p. 229
Morphology and polymorph selectivity control in calcium carbonate mineralization	p. 235
Fabrication of organic/inorganic nanocomposites using pulsed laser ablation of zinc in aqueous solutions	p. 243
Preparation of intercalative organic/MoO[subscript 3] nanohybrid thin films and their VOC gas sensing properties	p. 249
The structure of a molybdenum disulfide intercalation compound	p. 255
Interlamellar incorporation of charged polymer nanobeads into sodium montmorillonite	p. 261
Layered tungsten oxide-based hybrid materials incorporating transition metal ions	p. 267
Intercalation of n-alkylamines in the vapor phase into vanadium pentoxide xerogel dispersed into silica matrix	p. 273
Control of the morphology of the layered-silicate epoxy nanocomposite	p. 279
Responsive polymer/clay aerogel composites	p. 285
Constrainment effects of interleaved organic molecules into layered double hydroxides	p. 291
Octadecylphosphonic acid self-assembled monolayers as lubricant coatings stable in alkaline media	p. 299
Self-assembled monolayers of 12-mercaptododecylphosphonic acid on titania particles; application to the extraction of heavy metals	p. 305
Abrasion resistant coatings with ultraviolet absorption, via sol-gel dipping method	p. 311
Magnetotransport properties of compression molded CrO[subscript 2]-polyimide composite	p. 321
New high-dielectric-constant polymer-ceramic composites	p. 327
Self-extinguishing polymer nanocomposites	p. 333
Effects of surface modification of Mg(OH)[subscript 2] with polysiloxane oil and silica additive on the flame retardancy and mechanical properties of LDPE-Mg(OH)[subscript 2] composites	p. 339
Hierarchical porous silicas for chromatographic applications obtained by pseudomorphic synthesis	p. 345
Study of relationship between morphology and mechanical properties of SiO[subscript 2]-polyacrylate hybrid nanocomposite	p. 357
Modification and characterization of Si-based nanobuilding blocks precursors for hybrid materials	p. 363
Simulations of organic-tethered silsesquioxane nanocube assemblies	p. 369
Evaluation of polypyrrole coating on Fe[subscript 3]O[subscript 4] and its effect on nanocomposite properties	p. 377
Pentacene transistors with polymer gate dielectrics on metallized optical fibers	p. 385
Solution processable nanocomposites based on silsesquioxane cores for use in organic light emitting diodes (OLEDs)	p. 399
Hybrid materials for optical limiting	p. 405
The synthesis and characterization of energy-conducting polymers with pendant inorganic chromophores	p. 411
ORMOCERs (organic-inorganic hybrid polymers) for telecom applications : structure/property correlations	p. 419
Hybrid materials approach in the design of electrodes and electrolytes for energy storage and conversion	p. 431
Electrochemical characterization of phosphosilicate-modified nafion membranes	p. 439
Fabrication of nanocomposite thin film of hydroxyapatite and polyvinylalcohol and its ionic conductive properties	p. 445
Ligand control of semiconductor nanocrystals for efficient carrier injection	p. 451
Structure of nanocomposite films of CdS nanoparticles in a polymer matrix	p. 457
Characterization of dendrimer-gold nanocomposite materials	p. 463
Silica and hybrid silica gels revisited : new insight by solid state nuclear magnetic resonance	p. 471
The use of multinuclear solid state NMR for the characterization of siloxane-oxide hybrid nanocomposites	p. 483
In situ SAXS/XRD on mesoscopically ordered surfactant-silica mesophases; what can we learn?	p. 495
Synthesis and characterization of imide-oligosiloxanes hybrid nanocomposite (imide HYBRIMER) by reaction of nano amine modified oligosiloxane and dianhydride	p. 509
Formation and reaction of metal-containing nanoparticles in organic/inorganic hybrid aerogels	p. 515
Preparation of particulate core-shell metal oxide-polymer nanocomposites by a sol-gel approach	p. 521
Modification of metal alkoxide precursors by organofunctional bidentate ligands : chemical problems and opportunities for materials syntheses	p. 533
Surface-modified zirconium oxide clusters and their use as components for inorganic-organic hybrid materials	p. 539
Two synthetic routes to the formation of tungsten oxide hybrid compounds	p. 545
Molybdenum dioxide and vanadium-doped molybdenum dioxide microcrystals in a polymer container	p. 551
Molybdenum and tungsten oxide nanowires prepared by electrospinning	p. 557
Vanadium oxide nanotubes : new synthesis route and mechanism of formation	p. 563
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