Organophosphorus Chemistry

by Allen, D. W.; Tebby, J. C.; Loakes, David; Keglevich, Gyorgy (CON); Odinets, Irina (CON)

• ISBN13: 9781849731386
• ISBN10: 1849731381
• Format: Hardcover
• Copyright: 2011-05-04
• Publisher: Royal Society of Chemistry

Summary

Organophosphorus Chemistry provides a comprehensive and critical review of the recent literature.

Table of Contents

Preface	p. v
Phosphines and related P-C-bonded compounds	p. 1
Introduction	p. 1
Phosphines	p. 1
P¿-Bonded phosphorus compounds	p. 26
Phosphirenes, phospholes and phosphinines	p. 31
References	p. 35
Phosphine chalcogenides	p. 52
References	p. 70
Phosphonium salts and P-ylides	p. 74
Introduction	p. 74
Phosphonium salts	p. 74
P-Ylides (phosphoranes)	p. 90
References	p. 100
Nucleotides and nucleic acids: mononucleotides	p. 106
Introduction	p. 106
Methodology	p. 106
Mononucleotides	p. 108
Dinucleotides	p. 123
Polyphosphorylated nucleosides	p. 128
References	p. 134
Nucleotides and nucleic acids; oligo- and polynucleotides	p. 139
Introduction	p. 139
Aptamers and (deoxy)ribozymes	p. 163
Oligonucleotide conjugates	p. 169
Nucleic acid structures	p. 181
References	p. 186
Quinquevalent phosphorus acids	p. 217
Introduction	p. 217
Phosphoric acids and their derivatives	p. 218
Phosphonic acids and their derivatives	p. 251
Phosphinic acids and their derivatives	p. 282
References	p. 289
Pentacoordinated and hexacoordinated compounds	p. 297
Introduction	p. 297
Synthesis and structure determination of novel hypervalent spirophosphoranes	p. 298
Stereochemistry of pentacoordinated chiral spirophosphoranes	p. 304
Hypervalent phosphorus compounds in chemical processess	p. 307
Application of hypervalent phosphorus compounds in NMR studies	p. 313
References	p. 315
Phosphazenes	p. 316
Introduction	p. 316
Biomaterials	p. 316
Material applications	p. 321
Novel phosphazene materials	p. 327
Phosphazene co-polymers	p. 342
Instrumental and theoretical aspects of polymer formation and structure	p. 347
Acknowledgments	p. 351
References	p. 351
Physical methods	p. 356
Introduction	p. 356
Theoretical and computational chemistry methods	p. 356
Nuclear magnetic resonance spectroscopy	p. 362
Electron paramagnetic (spin) resonance spectroscopy	p. 370
Vibrational and rotational spectroscopy	p. 371
Electronic spectroscopy	p. 374
X-ray diffraction (XRD) structural studies	p. 377
Electrochemical methods	p. 380
Thermal methods and thermochemistry	p. 381
Mass spectrometry techniques	p. 381
References	p. 382
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