Palladacycles Synthesis, Characterization and Applications

by Dupont, Jairton; Pfeffer, Michel

• ISBN13: 9783527317813
• ISBN10: 3527317813
• Edition: 1st
• Format: Hardcover
• Copyright: 2008-10-13
• Publisher: Wiley-VCH

Summary

From synthesis to applications in catalysis, material science and biology this much-needed book is the first to comprehensively present everything you need to know about palladacycles. Renowned international authors guarantee high-quality content, making this a must-have for everyone working in the field.

Author Biography

Jairton Dupont is Professor at the Institute of Chemistry in Porto Alegre. His research interests are organometallic chemistry, catalysis and ionic liquids. He is author of more than 120 publications, 7 patents and several book chapters. Jairton Dupont has received the Friedrich Wilhelm Bessel Forschungspreis of the Humboldt Foundation, the Simao Mathias Medal and the FAPERGS Award in Chemistry.

Michel Pfeffer is Directeur de Recherche at the University Louis Pasteur in Strasbourg and he is working on organic synthesis mediated and catalysed by transition metals (CH activation, C-C bond forming processes and more). He authored more than 160 publications and has received the Bronze Medal of the CNRS.

Table of Contents

Introduction

Synthesis via C-H Bond Activation

Synthesis via Oxidative Addition and Transmetallation

Synthesis via other synthetic solutions

Stoichiometric reactions at the Pd-C bond and the palladium centre: Reactivity of the Pd-C unit with small molecules, e.g. alkynes, alkenes, allenes, CO, CNR, etc?

Stoichiometric reactions at the Pd-C bond and the palladium centre: Applications to organic synthesis

Stoichiometric reactions at the Pd-C bond and the palladium centre:. Cyclopalladated compounds as resolving agents for racemic mixtures of ligands

Application of cyclopalladated compounds as Catalysts for Heck and Sonogashira reactions

Application of cyclopalladated compounds as Catalysts Suzuki and C-N coupling

Application of cyclopalladated compounds as catalysts for other reactions (aldol condensations, allylic alkylations, oxidations, etc?)

Cyclopalladated Liquid Crystals

Photo physical properties of cyclopalladated compounds

Cyclopalladated compounds in biomedical applications

Thermomorphic cyclopalladated compounds

Dendrimeric cyclopalladated compounds

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