Pesticide Protocols

by Vidal, Jose L. Martinez; Frenich, Antonia Garrido

• ISBN13: 9781588294104
• ISBN10: 1588294102
• Format: Hardcover
• Copyright: 2005-09-01
• Publisher: Humana Pr Inc

Summary

A comprehensive collection of robust methods for the detection of pesticide compounds or their metabolites useful in food, environmental, and biological monitoring, and in studies of exposure via food, water, air, and the skin or lungs. The readily reproducible methods range from gas and liquid chromatography coupled to mass spectrometry detection and other classic detectors, to capillary electrophoresis and immunochemical or radioimmunoassay methods. The authors have focused on extraction and cleanup procedures, in order to develop and optimize more fullyautomated and miniaturized methods, including solid-phase extraction, solid-phase microextraction, microwave-assisted extraction, and on-line tandem liquid chromatography (LC/LC) trace enrichment, among others. The protocols offer step-by-step laboratory instructions, an introduction outlining the principles behind the technique, lists of the necessary equipment and reagents, and tips on troubleshooting and avoiding known pitfalls.

Table of Contents

Preface	v
Contributors	xi
Part I. Analytical Methodologies to Determine Pesticides and Metabolites in Human Fat Tissues and Body Fluids
Analysis of Endocrine Disruptor Pesticides in Adipose Tissue Using Gas Chromatography--Tandem Mass Spectrometry: Assessment of the Uncertainty of the Method	3	(14)
Jose L. Martinez Vidal
Antonia Garrido Frenich
Francisco J. Egea Gonzalez
Francisco J. Arrebola Liebanas
Determination of Pyrethroids in Blood Plasma and Pyrethroid/Pyrethrin Metabolites in Urine by Gas Chromatography--Mass Spectrometry and High-Resolution GC--MS	17	(18)
Gabriele Leng
Wolfgang Gries
A Multianalyte Method for the Quantification of Current-Use Pesticides in Human Serum or Plasma Using Isotope Dilution Gas Chromatography--High-Resolution Mass Spectrometry	35	(14)
Dana B. Barr
Roberto Bravo
John R. Barr
Larry L. Needham
Application of Solid-Phase Disk Extraction Combined With Gas Chromatographic Techniques for Determination of Organochlorine Pesticides in Human Body Fluids	49	(12)
Adrian Covaci
A Comprehensive Approach for Biological Monitoring of Pesticides in Urine Using HPLC-MS/MS and GC--MS/MS	61	(18)
Dana B. Barr
Anders O. Olsson
Roberto Bravo
Larry L. Needham
Urinary Ethylenethiourea as a Biomarker of Exposure to Ethylenebisdithiocarbamates	79	(12)
Silvia Fustinoni
Laura Campo
Sarah Birindelli
Claudio Colosio
Analysis of 2,4-Dichlorophenoxyacetic Acid and 2-Methyl-4-Chloro-Phenoxyacetic Acid in Human Urine	91	(14)
Cristina Aprea
Gianfranco Sciarra
Nanda Bozzi
Liana Lunghini
Determination of Herbicides in Human Urine by Liquid Chromatography--Mass Spectrometry With Electrospray Ionization	105	(6)
Isabel C. S. F. Jardim
Joseane M. Pozzebon
Sonia C. N. Queiroz
Analysis of Pentachlorophenol and Other Chlorinated Phenols in Biological Samples by Gas Chromatography or Liquid Chromatography--Mass Spectrometry	111	(8)
Ji Y. Zhang
Analysis of 2,4-Dichlorophenoxyacetic Acid in Body Fluids of Exposed Subjects Using Radioimmunoassay	119	(14)
Dietmar Knopp
A High-Throughput Screening Immunochemical Protocol for Biological Exposure Assessment of Chlorophenols in Urine Samples	133	(16)
Mikaela Nichkova
M.-Pilar Marco
Part II. Assessment of Inhalatory and Potential Dermal Exposure
Assessment of Postapplication Exposure to Pesticides in Agriculture	149	(16)
Joop J. van Hemmen
Katinka E. van der Jagt
Derk H. Brouwer
Field Study Methods for the Determination of Bystander Exposure to Pesticides	165	(14)
C. Richard Glass
Determination of Household Insecticides in Indoor Air by Gas Chromatography--Mass Spectrometry	179	(12)
Edith Berger-Preiss
Lutz Elflein
Assessment of Dermal and Inhalatory Exposure of Agricultural Workers to Malathion Using Gas Chromatography-Tandem Mass Spectrometry	191	(16)
Francisco J. Egea Gonzalez
Francisco J. Arrebola Liebanas
A. Marin
Pesticides in Human Fat and Serum Samples vs. Total Effective Xenoestrogen Burden	207	(12)
Patricia Araque
Ana M. Soto
M. Fatima Olea-Serrano
Carlos Sonnenschein
Nicolas Olea
Part III. Pesticide Analysis in Food
Quality Criteria in Pesticide Analysis	219	(12)
Antonia Garrido Frenich
Jose L. Martinez Vidal
Francisco J. Egea Gonzalez
Francisco J. Arrebola Liebanas
Immunoassay Methods for Measuring Atrazine and 3,5,6-Trichloro-2-Pyridinol in Foods	231	(8)
Jeanette M. Van Emon
Jane C. Chuang
Quick, Easy, Cheap, Effective, Rugged, and Safe Approach for Determining Pesticide Residues	239	(24)
Steven J. Lehotay
Determination of Organophosphorus Pesticide Residues in Vegetable Oils by Single-Step Multicartridge Extraction and Cleanup and by Gas Chromatography With Flame Photometric Detector	263	(10)
Alfonso Di Muccio
Anna M. Cicero
Antonella Ausili
Stefano Di Muccio
Multiclass Pesticide Analysis in Vegetables Using Low-Pressure Gas Chromatography Linked to Tandem Mass Spectrometry	273	(12)
Francisco J. Arrebola Liebanas
Francisco J. Egea Gonzalez
Manuel J. Gonzalez Rodriguez
Use of Matrix Solid-Phase Dispersion for Determining Pesticides in Fish and Foods	285	(12)
Steven A. Barker
Analysis of Fungicides in Fruits and Vegetables by Capillary Electrophoresis--Mass Spectrometry	297	(14)
Yolanda Pico
Application of Supercritical Fluid Extraction for the Analysis of Organophosphorus Pesticide Residues in Grain and Dried Foodstuffs	311	(8)
Kevin N. T. Norman
Sean H. W. Panton
Application of Microwave-Assisted Extraction for the Analysis of Dithiocarbamates in Food Matrices	319	(12)
Euphemia Papadopoulou-Mourkidou
Emmanuil Nikolaos Papadakis
Zisis Vryzas
Enantioselective Determination of α-Hexachlorocyclohexane in Food Samples by GC--MS	331	(12)
Chia-Swee Hong
Shaogang Chu
Part IV. Pesticide Analysis in Water
Automated Headspace Solid-Phase Microextraction and Gas Chromatography--Mass Spectrometry for Screening and Determination of Multiclass Pesticides in Water	343	(22)
Taizou Tsutsumi
Mitsushi Sakamoto
Hiroyuki Kataoka
Janusz Pawliszyn
Analysis of Herbicides in Water by On-Line In-Tube Solid-Phase Microextraction Coupled With Liquid Chromatography--Mass Spectrometry	365	(18)
Hiroyuki Kataoka
Kurie Mitani
Masahiko Takino
Coupled-Column Liquid Chromatography for the Determination of Pesticide Residues	383	(22)
Elbert Hogendoorn
Ellen Dijkman
On-Line Admicelle-Based Solid-Phase Extraction-Liquid Chromatography-Ionization Trap Mass Spectrometry for the Analysis of Quaternary Ammonium Herbicides in Drinking Water	405	(16)
Dolores Perez-Bendito
Soledad Rubio
Francisco Merino
Molecular Imprinted Solid-Phase Extraction for Cleanup of Chlorinated Phenoxyacids From Aqueous Samples	421	(14)
Claudio Baggiani
Cristina Giovannoli
Automated Trace Analysis of Pesticides in Water	435	(18)
Euphemia Papadopoulou-Mourkidou
John Patsias
Anna Koukourikou
Gas Chromatography--High-Resolution Mass Spectrometry-Based Method for the Simultaneous Determination of Organotin Compounds in Water	453	(14)
Michael G. Ikonomou
Marc P. Fernandez
Determination of Triazine Herbicides and Degradation Products in Water by Solid-Phase Extraction and Chromatographic Techniques Coupled With Mass Spectrometry	467	(14)
Hassan Sabik
Roger Jeannot
An Optical Immunosensor for Pesticide Determination in Natural Waters	481	(10)
Sara Rodriguez-Mozaz
Maria J. Lopez de Alda
Damia Barcelo
Index	491