Proceedings of the 8th Asian Conference on Solid State Ionics

by Chowdari, B. V. R.; Prabaharan, S. R. S.; Yahaya, M.; Talib, I. A.

• ISBN13: 9789812382481
• ISBN10: 9812382488
• Format: Hardcover
• Copyright: 2003-02-01
• Publisher: World Scientific Pub Co Inc

Summary

This volume presents a comprehensive collection of state-of-the-art advances in the field of solid state ionic materials and the design, fabrication and performance of devices that use them, such as lithium batteries, gas sensors, fuel cells, supercapacitors and electrochromic displays. These electrochemical devices are becoming pervasive in our technologically driven lifestyles.The book includes research activities being carried out in the new millennium, through special keynote addresses, as well as invited and contributed papers, related to experimental and theoretical modeling in solid state ionics. The excellent coverage of topics arranged in such a fashion helps students and beginners to understand the field with enthusiasm. It also encompasses various experimental techniques often employed in solid state ionics research, such as XRD, XPS, hole-burning spectroscopy, EDAX, EXAFS, SEM, thermal analysis techniques, ac-impedance spectroscopy and other electrochemical techniques such as cyclic voltammetry, galvanostatic and potentiostatic electrochemical techniques. Theoretical and applied aspects of mixed conduction for applications mainly in solid oxide fuel cells occupy a portion of the text. Finally, this volume demonstrates the amount of research activities being carried out in this application-oriented field.Solid State Ionics will be of interest to all in the solid state ionics community, including chemists, physicists, materials scientists and electrochemists, both in industry and in research.

Table of Contents

Preface	vii
Part I: Batteries and Battery Materials	1	(192)
Lithium Ion Transfer Through the Interface Between Positive Electrode and Electrolyte in Rechargeable Lithium Batteries [Keynote]	3	(8)
Ogumi Z
Abe T
Iriyama Y
Lithium Nickel Oxide Derivatives: From an Intercalation Reaction to an Electrode Material for EV Lithium-Ion Batteries [Invited]	11	(2)
Delmas C
New Lithium Solid Electrolytes, Thio-LISICON: Materials Design Concept and Application to Solid State Battery [Invited]	13	(10)
Kanno R
Murayama M
Sakamoto K
Designing Chemically and Structurally Stable Cathode Hosts for Lithium Ion Cells [Invited]	23	(12)
Manthiram A
Layered Li-Mn-M-oxides as Cathodes for Li-Ion Batteries: Recent Trends [Invited]	35	(12)
Shaju K M
Rao G V S
Chowdari B V R
Nanostructured Energy Storage Materials [Invited]	47	(2)
Nazar L F
Souza D C
Crosnier O
Huang H
Synthesis and Electrochemical Property of Lithium Storage Intermetallic Compounds [Invited]	49	(12)
Esaka T
Mineral Fast Ion Conductors and Mineral Solid Electrolyte Batteries [Invited]	61	(12)
Wang W
Study of the Charge Transfer Process of LaNi5 Type Electrodes in Ni-MH Batteries [Invited]	73	(12)
Que L X
Thuy N P
Electronically Conductive Phospho-Olivines as Lithium Storage Electrodes	85	(2)
Chung S-Y
Blocking J T
Andersson A S
Chiang Y-M
CaSnO3 as High Capacity Anode Material for Li-Ion Batteries	87	(10)
Sharma N
Rao G V S
Shaju K M
Chowdari B V R
The Improvement of Cycleability of LiMn2O4 Materials by Coating with Ni, Co or Cu	97	(10)
Yang S T
Jia J H
Ding L
Zhang M C
Studies on the Performance of Li(Ni,Co)O2 Solid Solutions as Cathodes for Lithium Batteries	107	(10)
Kalyani P
Kalaiselvi N
Renganathan N G
Raghavan M
A Novel Soft Chemistry Approach to Synthesize LiNiVO4	117	(10)
Kalaiselvi N
Periasamy P
Kalyani P
Sastry V S
Renganathan N G
Raghavan M
Synthesis and Redox Behavior of Oxygen Deficient Brannerite LiVWO6-δ for Lithium Batteries	127	(10)
Prabaharan S R S
Begam K M
Fauzi A
Ramesh S
Michael M S
A New Electrode with Polyanion - (MoO4)3 as Cathode for Lithium Ion Batteries	137	(10)
Begam K M
Michael M S
Taufiq-Yap Y H
Prabaharan S R S
Structure and Electrochemistry of 4-V Positive Electrodes Prepared By Succinic Acid-Assisted Wet Chemistry	147	(8)
Selladurai S
Amdouni N
Mangani I R
Julien C
Performance Comparison of Commercial Mobile Phone Battery	155	(8)
Azrulnizam M
Surani B
Sulaiman M A
Comparison of LiCo0.97Mg0.03O2 PLD Film with Bulk for the Application of Lithium Micro-Batteries	163	(8)
Vasanthi R
Mangani I R
Selladurai S
Manoravi P
Solid State Battery Discharge Characteristic Studies on Some New Ag+ Ion Conducting Glasses	171	(6)
Agrawal R C
Verma M L
Kumar R
Sinha C K
Study of Solid State Protonic Battery with Composite Solid Electrolyte	177	(8)
Singh K
Ambekar P
Bhoga S S
Tiwari R U
Performance of Zn-Polyaniline Rechargeable Battery	185	(8)
Paramasivam M
Jayachandran M
Murali K R
Trivedi D C
Raghavan M
Part II: Polymer Electrodes and Electrolytes	193	(214)
Thermally Stable Polymer Electrolyte Plasticized with PEG-Borate Ester for Lithium Secondary Battery [keynote]	195	(8)
Wakihara M
Kato Y
Yokoyama S
Ikuta H
Uchimoto Y
Polymer Electrolytes: Problems, Prospects and Promises [Invited]	203	(12)
Nagasubramanian G
Doughty D H
Composite Polymer Electrolytes Based on Hyperbranched Polymer and Application to Lithium Polymer Batteries [Invited]	215	(22)
Itoh T
Ichikawa Y
Miyamura Y
Uno T
Kubo M
Takeda Y
Qi Li
Yamamoto O
Ambient Temperature Hybrid Polymer Electrolyte Based on PVK+PVDF-HFP(Co-Polymer) for Lithium Batteries [Invited]	237	(14)
Michael M S
Tou T Y
Prabaharan S R S
Nano-Composite Solid Polymer Electrolytes [Invited]	251	(12)
Dissanayake M A K L
Ionic Conduction Mechanism of Polymer Gel Electrolytes [Invited]	263	(10)
Saito Y
Kataoka H
Polymer Electrolytes: Opportunities and Challenges [Invited]	273	(10)
Kulkarni A R
The Role of Polymer Electrolytes in Drug Delivery [Invited]	283	(12)
Latham R J
Linford R G
Schlindwein W S
Single Ion Conductor Based on Modified Silica [Invited]	295	(6)
Choi N-S
Lee Y M
Park J W
Park J-K
Plastic Crystal Fast Ion Conductors [Invited]	301	(2)
MacFarlane D R
Huang J
Isa F
Forsyth M
Seeber A
Efthimiades J
Solid State and Electrochemical Studies of Poly (dimethylsilane) and Poly (dimethylstannum) Film Electrodes	303	(10)
Kulandainathan M A
Elangovan M
Kulangiappar K
Raju T
Muthukumaran A
Sanjeeviraja C
Polypyrrole Electrodes as Cathodes in a Rechargeable Cell	313	(8)
Vidanapathirana K P
Careem M A
Skaarup S
West K
Investigation on PMMA-Based Gel Electrolyte for Electrochromic Devices	321	(8)
Kamisah M M
Exploratory NMR Imaging Experiments to Determine the Possibility of a Percolating Mechanism in Plasticized Polymer Electrolytes	329	(8)
Joykumar S T H
Raghav G M
Bhat S V
Ionic Conductivity Enhancement in PEO9:Cu(CF3SO3)2 Composite Solid Polymer Electrolyte Due to Al2O3 Filler	337	(8)
Jayathilaka P A R D
Bokalawela R S P
Bandaranayake P W S K
Bandara L R A K
Dissanayake M A K L
Characterization and Conductivity Study of Poly (2 dimethylamino ethylmethacrylate) and its Hydrochloride Salt in Solid State	345	(8)
Chetia J R
Dutta A
Dass N N
Nano TiO2 Composite PVDF Polymer Electrolyte	353	(8)
Chiang C-Y
Chu P P
PVDF/Phenolic Blend Polymer Electrolyte	361	(8)
Shen Y J
Chu P P
Electrical and Structural Properties of New Li+ Ion Conducting Sol-Gel Derived Ormolytes: (SiO2-PEG)- LiCF3SO3	369	(8)
Gupta R K
Jung H Y
Wi C J
Whang C M
Plasticized Proton Conducting Polymer Electrolytes Based on Polyethylene Oxide and Ammonium Salts NH4X: X=F-, BF4-	377	(8)
Sekhon S S
Kumar M
The Influence of Dispersed State on the Structure and Capability of the Polymer Electrolytes Based on PVDF/PMMA	385	(8)
Yang S T
Chen H J
Jia J H
Mesoporous Composite PEO Solid Polymer Electrolyte	393	(8)
Reddy M J
Chu P P
The Doping Effect on Conductivity and Glass Transition Temperature of Solid Polymeric Electrolyte Based on Polyvinylchloride (PVC)	401	(6)
Rahman M Y A
Salleh M M
Talib I A
Yahaya M
Part III: Electrochromics, Sensors and Fuel Cells	407	(76)
Materials Concepts for Solid State Ionic Devices [Keynote]	409	(2)
Weppner W
Electrochromics --- History, Technology, and the Future [Invited]	411	(12)
Lampert C M
Electrochromic Properties of Iridium Oxide Films Prepared by Pulsed Anodic Electrodeposition	423	(8)
Jung Y
Tak Y
Lee J
Electrochromic Sensing of Chloride using N-Tetraphenyl Porphine Manganese (III) Chloride Langmuir-Blodgett Films	431	(8)
Salleh M M
Akrajas
Yahaya M
Electrochromic TiO2 Thin Film Prepared by Dip-Coating Technique	439	(6)
Suriani S
Kamisah M M
Electrochromic Characterization of Electrodeposited WO3 Thin Films	445	(8)
Vijayalakshmi R
Jayachandran M
Sanjeeviraja C
Ag2O:SiO2:V2O5 Glass System: A Novel Reference Electrode for SO2 Gas Sensor	453	(8)
Singh K
Lad A
Bhoga S S
New Family of Electrochemical Cells for NOx Decomposition with Multi Layer Electro-Catalytic Electrode	461	(8)
Bredikhin S
Aronin A
Abrosimova G
Matsuda K
Awano M
Ferroelectric Dispersed Composite Solid Electrolyte for CO2 Gas Sensor	469	(8)
Singh K
Ambekar P
Bhoga S S
Electrical and Microstructural Characterization of Ni/YSZ Cermet Anode for Anode-Supported Type SOFC	477	(6)
Lee D-S
Heo J-W
Lee J-H
Kim J
Lee H-W
Kim S-W
Kim G-H
Song H S
Part IV: Anion (O2-,F-) and Cation (Li+ Na+) conductors	483	(154)
Solid State Ionics: Interfaces vs. Bulk [Keynote]	485	(2)
Maier J
Electrical Characterisation of Oxide Ion Conducting Perovskites and Apatites [Invited]	487	(14)
West A R
Abram E J
Sinclair D C
Study of Sol-Gel Synthesized Ce0.8Sm0.2O1.9 Solid Electrolyte [Invited]	501	(10)
Wen T-L
Zhan Z
Nie H
Lu Z
Wang D
Electrical Conduction in BaTiO3-δ in its Mixed n/p Regime Under Oxygen Potential Gradients [Invited]	511	(12)
Yoo H-I
Re-examination of Oxide-Ion Conductivity of 7Bi2O3.2WO3	523	(6)
Watanabe A
Water Solubility in Ceria and Zirconia Doped with Rare Earth Oxides	529	(8)
Inami S
Yamaguchi S
Yokokawa H
Sakai N
Horita T
Yamaji K
Oxygen Permeability of 60-volume% Bi1.6Y0.4O3 and 40-volume% Ag Composite Prepared by Citrate Sol-Gel Method	537	(8)
Kobayashi K
Tsunoda T
Conductivity Studies of Bi2W1-xMoxO6 Solid Solutions	545	(8)
Sim L T
Lee C K
Halim S A
West A R
Synthesis and Ionic Conductivity of PbBi6M2O15 (M=V, P, As) and Pb1-xSrxBi6V2O15 Solid Solutions	553	(8)
Lee C S
Lee C K
Sinclair D C
Zainal Z
Hashim M
Preparation and Characterization of Ionic Conductor Bi23V4O44.5	561	(8)
Lee S L
Lee C K
Sinclair D C
Chong F K
Shaari A H
Fluoride Ion Conductors RPbF3 (R=Rb,Cs) Studied by X-ray Diffraction and NMR	569	(6)
Okuda T
Fukutomi S
Takesako K
Ohki H
Yamada K
Effect of Milling Time on the Particles Size and Microstructure of Millscale Derived BaFe12O19	575	(8)
Raba'ah S A
Hashim M
Yahya N
Saiden N M
Hari Z
Effect of Copper Oxide Additions on the Grain Boundary Resistivity in Yttria-Tetragonal Zirconia	583	(8)
Ramesh S
Ceria-doped Yttria Crystals, their Structure and Electrical Conductivity	591	(8)
Hartmanova M
Lomonova E E
Navratil V
Kundracik F
Kostic I
AC Impedance Spectroscopic Studies on Li2-xPb2xBaP2O7	599	(6)
Vijayakumar M
Selvasekarapandian S
Synthesis and Electrical Characterization of Gd doped Lithium Phosphate	605	(8)
Hirankumar G
Vijayakumar M
Selvasekarapandian S
Lithium Ionic Conduction in LiAlO2-based Oxides at Elevated Temperatures	613	(8)
Shimura T
Murahashi D
Iwahara H
Yogo T
Impedance Spectroscopy and Structural Investigation of the Li+ Conductor Li3InBr6	621	(8)
Yamada K
Iwaki K
Okuda T
Tomita Y
Frequency Dependent Electrical Properties of the Na3Fe2P3O12 and Na4FeCdP3O12 NASICON Material	629	(8)
Mariappan C R
Govindaraj G
Part V: Electrochemical Promoted Reactions and Supercapacitors	637	(40)
Synthesis, Structure and Electronic Properties of Anionically Modified Anatase [Invited]	639	(6)
Ramanujachary K V
Lofland S E
Butterick R
Lanci C J
Studies on Heat Treated Co-Cr2O3 and Ni-Cr2O3 Electrodeposited Surfaces Under Tribological Conditions	645	(6)
Kalyanaraman D
Chandramohan R
A Catalytic SnO2 Based Electrodes for Electrosynthesis and Energy Device Applications	651	(6)
Kulandainathan M A
Kulangiappar K
Raju T
Muthukumaran A
Conductive Additive Carbon for High Voltage Electrochemical Double Layer Capacitors (EDLCs)	657	(10)
Michael M S
Shah Y R
Vimala R
Prabaharan S R S
Effects of Chemical Pretreatment in the Preparation of Aluminum Electrolytic Capacitor Anode	667	(8)
Lee J W
Shin Y
Tak Y
Lee J
Power Sources for Future Road Transport: Electrochemical Systems and Fuel Cells	675	(2)
Sakthivel T G
Smart R
Krishnan A M
Part VI: Proton Conductors and Amorphous Conductors/Glasses	677	(72)
Ion Conducting Porous Alcogels: Some Interesting Possibilities [Invited]	679	(10)
Chandra S
Srivastava R
Chandra A
Stochastic Modeling of Ion Dynamics in Glasses [Invited]	689	(12)
Dieterich W
Maass P
Preparation and Characterization of Solid Electrolyte Ceramic of SrCe1-xZrxO3 doped Y2O3 as Protonic Conductor at High Temperature	701	(8)
Elvaswer
Talib I A
Bond Strength-Coordination Number Fluctuations and the Fragility of Some Superionic Glass Forming Liquids	709	(8)
Aniya M
An Unusual Anomalous Relaxation Function and its Applications in Ion Conducting Disordered Solids	717	(8)
Govindaraj G
Ag-109 NMR of AgI Based Superionic Conductor glasses	725	(10)
Kawamura J
Kuwata N
Hattori T
Nakamura Y
Polarization / Self-depolarization Studies on Some Fast Ag+ Ion Conducting Glasses	735	(6)
Agrawal R C
Verma M L
Bhatt A
DC and AC Conductivity Studies on Ag2O-P2O5-V2O5 Glass System	741	(8)
Anavekar R V
Eraiah B
Part VII: Experimental Techniques and Modeling	749	(66)
Study on Ion Dynamics in Ionic Conductors by Hole Burning Spectroscopy [Invited]	751	(12)
Hattori T
Exploring Fast Ion Conduction by NMR [Invited]	763	(12)
Brinkmann D
NMR Investigations of Mass Transport in Composite Polymer Electrolytes for Batteries and Fuel Cells [Invited]	775	(2)
Greenbaum S
Oscillatory Diffuse Neutron Scattering From β-AgI	777	(8)
Thazin A
Arai M
Sakuma T
Ishii Y
Studies on Fast Ion Transport in Silver Sulphide Halogenides	785	(8)
Ramasekaran B
Haridasan T M
Thermal Conductivity of Al0.3Ga0.7As by Photo Acoustic and Molecular Dynamics Simulation	793	(8)
Chitra S
Ramachandran K
Phonon Dispersion Relation of Silver Ternary Compounds	801	(4)
Ono S
Ogawa H
Kobayashi M
Tomoyose T
The Effect of DC and AC Electric Fields on Heat Transfer in R11	805	(10)
Nasif M S
Reizes J
Part VIII: Biological/Organic Ion Conductors	815	(32)
Synthesis and Crystal Structure Studies of Cu(I) Complexes with Pyrazolyborateo Ligands: An Approach to Synthetic Model of the Active Site of Blue Copper Proteins such as Plastocyanin	817	(6)
Beheshti A
Rahmani A R
Sadr M H
An Experimental Study of Electrical Character of Proteins	823	(8)
Gupta N
Mallik H
Sarkar A
Force Exerted by Polypyrrole/dodecylbenzenesulphonate Artificial Muscles	831	(8)
Vidanapathirana K P
Careem M A
Skaarup S
West K
The Influence of Hydrogen Ions on the Lattice Parameters of Pure Copper	839	(8)
El-Amoush A S
Part IX: Semiconductor Ionics	847	(24)
Photoacoustic and X-ray Studies on H+ Ion Implanted n-GaAs	849	(8)
Roy S D D
Chandrasekaran K S
Ramachandran K
Nano Cd(Se,Te) Thin Films Prepared by Pulse Plating Technique	857	(6)
Saaminathan V
Murali K R
Photoacoustic Study on a Photonic System CdS and Doped CdS	863	(8)
Sankar N
Ramachandran K
Sanjeeviraja C
Author Index	871	(4)
Tentative List of Participants	875