Structure, Passivation and localized corrosion of metal surfaces | |
Introduction | p. 1 |
Nucleation and Growth of Passive Films | p. 3 |
Hydroxide Ion Adsorption and Growth of 2D Passive Layers | p. 3 |
Copper | p. 3 |
Silver | p. 7 |
Nickel | p. 12 |
Influence of 2D Passive Films on Dissolution | p. 16 |
Silver | p. 16 |
Nickel | p. 19 |
Structure of 3D Passive Films on Metals and Alloys | p. 22 |
Crystalline Passive Films | p. 22 |
Copper | p. 22 |
Nickel | p. 25 |
Iron | p. 28 |
Ageing Effects on Chromium-Rich Passive Films | p. 29 |
Chromium | p. 29 |
Stainless Steels | p. 30 |
Dissolution in the Passive State | p. 31 |
Nanostructure of Passive Film and Passivity Breakdown | p. 34 |
Effect of Chlorides on Coalescence and Crystallization of the Passive Film | p. 34 |
Breakdown at Oxide Grain Boundaries | p. 39 |
Grain Boundary Model of Passivity Breakdown and Pit Initiation | p. 44 |
Local Redistribution of the Potential Drop | p. 44 |
Local Thinning of the Passive Film | p. 46 |
Voiding at the Metal/Oxide Interface | p. 49 |
Stress-Induced Fracture of the Passive Film | p. 51 |
Conclusion | p. 52 |
References | p. 54 |
Anodic Oxide Films on Aluminum: their significance for corrosion Protection and Micro-and Nano-Technologies | |
Applications of Anodic Oxide Films | p. 59 |
Structure and Properties of Oxide and Hydroxide Films | p. 61 |
Pretreated-Surface Film | p. 62 |
Thermal Oxide Film | p. 64 |
Hydroxide Film | p. 66 |
Barrier-Type Anodic Oxide Film (BAOF) | p. 72 |
Porous Type Anodic Oxide Film (PAOF) | p. 80 |
Structure | p. 80 |
Growth under Steady Conditions | p. 89 |
Growth under Transient Conditions | p. 94 |
Changes in Film Structure by Combination of Treatments | p. 98 |
Change of PAOF Structure by Heating, Boiling, and Anodizing in a Neutral Solution | p. 98 |
Change in BAOF Structure by Heating, Boiling, and Anodizing in an Acid Solution | p. 107 |
Change of the Structure of Thermal Oxide Films by Boiling, and Anodizing in a Neutral solution and in an Acid Solution | p. 107 |
Changes in the Structure of Hydroxide Films by Heating and Anodizing in Acid and Neutral Solutions | p. 111 |
Other Combination of Treatments | p. 117 |
Role of Anodic Oxide Films in Corrosion Protection of Aluminum | p. 117 |
Immersion of BAOF-Covered Aluminum in a Solution | p. 118 |
Role of Anodic Oxide Films in Pitting Corrosion during Cathodic Polarization | p. 119 |
Role of Anodic Oxide Films in the Corrosion of Aluminum Alloys in Alcohol at High Temperatures | p. 127 |
Micro-and Nano-Technologies Based on Anodized Aluminum | p. 130 |
Micro-Technologies with Laser Irradiation | p. 131 |
Applications of Laser Irradiation Techniques | p. 140 |
Printed Circuit Boards | p. 140 |
Plastic Injection Molds | p. 141 |
Electrochemical Micro-Reactor | p. 142 |
Free-Standing Microstructures | p. 145 |
Micro-Actuator | p. 145 |
Printing Roll | p. 150 |
Micro-and Nano-Patterning with AFM Probe Processing | p. 151 |
Formation of Composite Oxide Films by the Combination of Anodizing with Other Coating Methods | p. 157 |
Pore-Filling Method | p. 159 |
Combination of Metal-Organic Chemical Vapor Deposition with Anodizing | p. 160 |
Combination of Sol-Gel Dip Coating and Anodizing | p. 161 |
Combination of Electrophoretic Sol-Gel Coating and Anodizing | p. 163 |
Combination of Liquid Phase Deposition with Anodizing | p. 165 |
Conclusions | p. 167 |
References | p. 168 |
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