Progress in Corrosion Science and Engineering 1

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  • Format: Hardcover
  • Copyright: 2009-12-30
  • Publisher: Springer Verlag

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Topics in Number 46 include:

Table of Contents

Structure, Passivation and localized corrosion of metal surfaces
Introductionp. 1
Nucleation and Growth of Passive Filmsp. 3
Hydroxide Ion Adsorption and Growth of 2D Passive Layersp. 3
Copperp. 3
Silverp. 7
Nickelp. 12
Influence of 2D Passive Films on Dissolutionp. 16
Silverp. 16
Nickelp. 19
Structure of 3D Passive Films on Metals and Alloysp. 22
Crystalline Passive Filmsp. 22
Copperp. 22
Nickelp. 25
Ironp. 28
Ageing Effects on Chromium-Rich Passive Filmsp. 29
Chromiump. 29
Stainless Steelsp. 30
Dissolution in the Passive Statep. 31
Nanostructure of Passive Film and Passivity Breakdownp. 34
Effect of Chlorides on Coalescence and Crystallization of the Passive Filmp. 34
Breakdown at Oxide Grain Boundariesp. 39
Grain Boundary Model of Passivity Breakdown and Pit Initiationp. 44
Local Redistribution of the Potential Dropp. 44
Local Thinning of the Passive Filmp. 46
Voiding at the Metal/Oxide Interfacep. 49
Stress-Induced Fracture of the Passive Filmp. 51
Conclusionp. 52
Referencesp. 54
Anodic Oxide Films on Aluminum: their significance for corrosion Protection and Micro-and Nano-Technologies
Applications of Anodic Oxide Filmsp. 59
Structure and Properties of Oxide and Hydroxide Filmsp. 61
Pretreated-Surface Filmp. 62
Thermal Oxide Filmp. 64
Hydroxide Filmp. 66
Barrier-Type Anodic Oxide Film (BAOF)p. 72
Porous Type Anodic Oxide Film (PAOF)p. 80
Structurep. 80
Growth under Steady Conditionsp. 89
Growth under Transient Conditionsp. 94
Changes in Film Structure by Combination of Treatmentsp. 98
Change of PAOF Structure by Heating, Boiling, and Anodizing in a Neutral Solutionp. 98
Change in BAOF Structure by Heating, Boiling, and Anodizing in an Acid Solutionp. 107
Change of the Structure of Thermal Oxide Films by Boiling, and Anodizing in a Neutral solution and in an Acid Solutionp. 107
Changes in the Structure of Hydroxide Films by Heating and Anodizing in Acid and Neutral Solutionsp. 111
Other Combination of Treatmentsp. 117
Role of Anodic Oxide Films in Corrosion Protection of Aluminump. 117
Immersion of BAOF-Covered Aluminum in a Solutionp. 118
Role of Anodic Oxide Films in Pitting Corrosion during Cathodic Polarizationp. 119
Role of Anodic Oxide Films in the Corrosion of Aluminum Alloys in Alcohol at High Temperaturesp. 127
Micro-and Nano-Technologies Based on Anodized Aluminump. 130
Micro-Technologies with Laser Irradiationp. 131
Applications of Laser Irradiation Techniquesp. 140
Printed Circuit Boardsp. 140
Plastic Injection Moldsp. 141
Electrochemical Micro-Reactorp. 142
Free-Standing Microstructuresp. 145
Micro-Actuatorp. 145
Printing Rollp. 150
Micro-and Nano-Patterning with AFM Probe Processingp. 151
Formation of Composite Oxide Films by the Combination of Anodizing with Other Coating Methodsp. 157
Pore-Filling Methodp. 159
Combination of Metal-Organic Chemical Vapor Deposition with Anodizingp. 160
Combination of Sol-Gel Dip Coating and Anodizingp. 161
Combination of Electrophoretic Sol-Gel Coating and Anodizingp. 163
Combination of Liquid Phase Deposition with Anodizingp. 165
Conclusionsp. 167
Referencesp. 168
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