Progress in Fullerene Research

by Kuzmany, Hans; Fink, Jorg; Mehring, Michael; Roth, Siegmar

• ISBN13: 9789810218874
• ISBN10: 9810218877
• Format: Hardcover
• Copyright: 1994-09-01
• Publisher: World Scientific Pub Co Inc

Summary

Proceedings of the International Winterschool on Electronic Properties of Novel Materials, held March 5-12, 1994 in Kirchberg, Tyrol, Austria.

Table of Contents

Preface
Fullerene Balls, Tubes, and Onions	p. 1
Fullerenes: Purification, Stability and Functional Covalent Derivatives	p. 13
The Regiochemistry of Nucleophilic Additions to C[subscript 60]	p. 19
Thermally and Photochemically Induced Cycloadditions to Fullerene C[subscript 60]: Addition of 6b,10a-Dihydrofluoranthene and 2,3-diphenyl-2H-Azirine to C[subscript 60]	p. 24
Addition Chemistry of C[subscript 60]: Synthesis, Characterization and Functionalization of Fulleropyrrolidines	p. 28
Synthesis and Electrochemical Properties of Ferrocenyl Fulleropyrrolidines	p. 33
Electron Transfer Reactions with C[subscript 60]	p. 37
Electrochemical Properties of Fullerol Aqueous Solutions	p. 41
Cluster Origin of Fullerene Solubility	p. 45
Ion-Fullerene Interaction: Effects of Energy Transfer	p. 49
Interactions of Free Electrons with C60: Unusual Attachment Properties	p. 53
The Use of Different Ionization Methods in Mass Spectrometric Studies of Fullerenes	p. 58
Fullerenes Production by Laser Ablation	p. 62
Growth Mode and Interface Study of C[subscript 60], on GeS(001)	p. 66
An Analysis of Annealed C[subscript 60] Films	p. 70
Influence of Hafnium Carbide on Fullerene Formation	p. 74
Thermal Properties, Structures and Preparation of Iron Containing Fullerides	p. 78
Iron in Fullerites	p. 82
Implantation of [superscript 57]Fe into Fullerites	p. 87
Trends in the Structural and Electronic Properties of Metallofullerenes	p. 93
Production and Properties of Fullerene Relatives: Metallofullerenes and Single-Layer Carbon Nanotubes	p. 102
Preparation and Separation of Lanthanum Metallofullerenes	p. 108
Paramagnetic States in Lanthanum, Yttrium, Scandium, and Holmium Containing Fullerenes	p. 112
Nanotube Properties and Graphite Origami	p. 116
Coiled Carbon Nanotubes	p. 122
Resonance Raman Spectroscopy of Multishell Carbon Nanotubes	p. 126
Electronic Structure of Coaxial Carbon Tubules	p. 130
Two New Discharges for Production of Fullerenes and Nanotubes	p. 135
Growth Types and Stable Configurations of Small Carbon Clusters Determined by High Resolution Electron Spectroscopy	p. 139
Order and Disorder in the Fullerenes	p. 149
Rotational Thermodynamics and Isotope Effect in C[subscript 60]	p. 157
Intermolecular Potentials and Theory for the Optical Observation of the Lattice Modes in Solid C60	p. 162
Order and Disorder from High Resolution Raman Spectra of C[subscript 60] Single Crystals	p. 167
Pulse Method Measurements of Thermal Properties of C[subscript 60]	p. 173
Structure and Surface Studies of C[subscript 60] Crystals	p. 177
Structure of Sb Fulleride Single Crystals	p. 181
Orientational Disorder of C[subscript 60] Powder Below the 260 K Transition	p. 184
Phase Transitions in Fullerene C[subscript 60]	p. 188
Temperature Dependence of the Structure of C[subscript 60]-Thin Films on MICA(001)	p. 193
Phase Transitions in C[subscript 60]-Clathrates	p. 197
Structural Phase Transitions in Single-Crystal C[subscript 70]	p. 201
Application of [mu]SR to the Study of the Dynamics of C70	p. 207
Alkali-Intercalated Structures of C[subscript 60]	p. 211
Thermal Expansion of [actual symbol not reproducible]	p. 217
Anharmonicity of Low-Frequency Phonons in Fullerite and Fullerides	p. 222
Disorder and Interactions in the Doped Fullerides	p. 226
Orientational Order/Disorder in NaxC[subscript 60]	p. 235
Alkaline-Earth Doped Fullerites	p. 239
Alkali-Metal-Fulleride Phase Diagram Determination with X-Ray Photoemission Spectroscopy	p. 247
Structural Study of Rb[subscript 1]C[subscript 60] and K[subscript 1]C[subscript 60] Fullerides	p. 257
Phase Transition in a Rb[subscript 1]C[subscript 60] Single Crystal from IR Reflectivity	p. 261
Optical Transmission Studies of Rb[subscript 1]C[subscript 60]	p. 265
Doping and Vibrational Analysis of Single Crystal Fulleride Phases	p. 271
Optical, Raman and Infrared Study of TDAE-C[subscript 60]	p. 275
Zero Field [mu]SR and NMR on Magnetic TDAE-C[subscript 60]	p. 279
Pulsed ESR and NMR in Magnetic TDAE-C[subscript 60]	p. 283
Susceptibility Above and Below Tc in TDAE-C[subscript 60]	p. 289
Doping of C60 with Tertiary Amines: A Comparative Study - Evidence for Itinerant Meta-Magnetism?	p. 293
[actual symbol not reproducible] A Model Substance for Single Charged C[subscript 60] Molecules	p. 297
Electronic Structure of C[subscript 60] Fullerites and Nanotubes	p. 303
Electronic Structure of Fullerenes from High-Energy Spectroscopy	p. 309
Corrections to Migdal's Theorem for Photoemission Spectra	p. 317
Electron Energy Loss Spectroscopy of Free Fullerenes	p. 323
High Energy Spectroscopic Studies of Fulleride Compounds	p. 327
Topology and Electronic Structure in C[subscript 60]	p. 334
On the Electrical Properties of Undoped C[subscript 60] Solids	p. 338
Electronic Structure of Two-Dimensional C[subscript 60] Layers Adsorbed on Metal Surfaces	p. 342
IR Reflection-Transmission of Vibrational Modes in Single Crystal C[subscript 60]	p. 349
Infrared Studies of Single Crystal C[subscript 60]: Silent and Higher Order Vibrational Modes	p. 353
Infrared Spectra of C[subscript 60] and [actual symbol not reproducible] Crystals	p. 357
Calculation of the Infrared and Raman Spectra of Short Linear Carbon Chains	p. 362
Optical Studies of Photopolymerized Solid C[subscript 60] and C[subscript 70] Films	p. 366
The Raman Spectroscopy of C[subscript 60] Solid Films	p. 372
Optical Investigation of Carbon Onions	p. 376
Polarizability of Onion-Like Fullerene	p. 380
Redox States of C[subscript 60] and C[subscript 70] Measured by EPR and Optical Absorption Spectroscopy	p. 384
Calculation of the UV-VIS Spectra of C[subscript 60]H[subscript 2n] (n=1, 2, 3)	p. 389
A One Parameter Model of the UV Spectra of Carbon	p. 393
Triplet Excitons in Molecular Crystals: The Case of Crystalline C[subscript 60]	p. 397
Photoexcited Triplet State of Dimethoxybenzene-C[subscript 60]: A Pulsed EPR Investigation	p. 403
Location of the Lowest Forbidden Exciton in Solid C60 by Non Linear Spectroscopy	p. 407
Electronically Excited States of the C[subscript 60] van der Waals Dimer: Localized Versus Charge Transfer Excitations	p. 412
Photoluminescence Studies of Solid C[subscript 60]	p. 416
Light-Induced Insulator to Metal Transition in Fullerenes	p. 421
Nonlinear Transient Photoconductive Response of Fullerene Crystals	p. 426
Reversible, Metastable, Ultrafast Photoinduced Electron Transfer in Conjugated Polymer and Fullerene Composites and Heterojunctions: A Comparative Study	p. 430
An Investigation of Time Resolved Electroluminescence in Fullerene Crystals	p. 435
The Nonlinear Optical Properties of C60: Z-Scans and Switching Measurements	p. 439
Complex Dielectric Constant Spectra Measurements by Means of Surface Waves Interferometry. Principles, Realizations, Examples for HTSC-Materials	p. 443
Pressure Effects on Thermodynamic and Electronic Properties of C[subscript 60] and K[subscript 3]C[subscript 60] Studied by [superscript 13]C-NMR	p. 451
[superscript 13]C and [superscript 87]Rb NMR in K[subscript 4]C[subscript 60] and Rb[subscript 3]C[subscript 60]	p. 456
High-Resolution [superscript 13]C NMR in Alkali Intercalated C[subscript 60]	p. 460
[superscript 13]C NMR in Rb[subscript 3]C[subscript 60] Samples - Temperature and Pressure Dependence of Relaxation	p. 466
Br NMR Study of [actual symbol not reproducible]	p. 470
Paramagnetic States in Pristine Fullerenes	p. 474
Magnetic Properties of Na[subscript 2]C[subscript 60] and K[subscript 4]C[subscript 60]	p. 478
In-Situ ESR-Spectroscopic Studies of Charge Transfer at Fullerenes	p. 482
FT-EPR Investigations of Fullerenes and Fullerides	p. 488
Structure and Dynamics of Superconducting Fullerides	p. 495
Allen's Formula and Raman Scattering from the Metallic Fullerides	p. 501
Microwave Conductivity and Conduction Electron Spin Relaxation of Rb[subscript 3]C[subscript 60]	p. 506
New Fullerene Charge Transfer Materials: A Search for New Magnetic Materials and Superconductors by ESR	p. 514
Low-Frequency Phonons, Superconductivity and Resistivity of Fullerides	p. 518
Multi-Band Effects on the Superconductivity in Orientationally Ordered Doped C[subscript 60]	p. 522
Polaronic Signatures in Cuprate and Fullerene Superconductors	p. 526
Are there Applications in Fullerene Research?	p. 535
Index of Contributors	p. 539
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