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9780841235946

Metal-Ion Separation and Preconcentration Progress and Opportunities

by ; ;
  • ISBN13:

    9780841235946

  • ISBN10:

    0841235945

  • Format: Hardcover
  • Copyright: 1999-02-11
  • Publisher: American Chemical Society

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Summary

Metal ion separation and preconcentration constitute the pivotal step in numerous analytical, purification, and waste treatment processes. Increasing environmental regulations and growing economic incentives imply that separation science will be essential to the future of industrial processing. This volume offers a broad perspective of advances in the field while also including up-to-date work in a number of specialized areas. It begins with an overview which describes the objectives the book, summarizes each chapter, and presents some immediate challenges for the future. Two review chapters then address the status of metal ion separations in nuclear energy and defense-related programs. These are followed by twenty chapters covering a range of topics, including aqueous phases in separations, extractant design and synthesis, solvent extraction, solid-liquid distribution, separations using membranes, centrifugal partition and countercurrent chromatography, and supercritical fluid extraction systems. Together the essays provide a fine balance of fundamental and applied research, making the book invaluable for both novice and experienced practitioners.

Table of Contents

Preface xi
Overviews 2(50)
1. Progress in Metal Ion Separation and Preconcentration: An Overview
2(11)
Andrew H. Bond
Mark L. Dietz
Robin D. Rogers
2. Future of Separation Science in U.S. Department of Energy Processing and Remediation
13(7)
Gregory R. Choppin
3. Solvent Extraction in the Treatment of Acidic High-Level Liquid Waste: Where Do We Stand?
20(32)
E. Philip Horwitz
Wallace W. Schulz
Aqueous Systems 52(50)
4. Aqueous Complexes in f-Element Separation Science
52(27)
Kenneth L. Nash
5. Metal Ion Separations in Aqueous Biphasic Systems and Using Aqueous Biphasic Extraction Chromatography
79(23)
Jonathan G. Huddleston
Scott T. Griffin
Jinhua Zhang
Heather D. Willauer
Robin D. Rogers
Extractant Design and Synthesis 102(44)
6. A Molecular Mechanics Method for Predicting the Influence of Ligand Structure on Metal Ion Binding Affinity
102(12)
Benjamin P. Hay
7. Ligand Design for Small Cations: The Li^(+)/14-Crown-4 System
114(19)
Richard A. Sachleben
Bruce A. Moyer
8. Synthesis of Novel Azamacrocyclic Metal Ion Receptors Using a Modified Mannich Aminomethylation Reaction
133(13)
Jerald S. Bradshaw
Andrei V. Bordunov
Xian Xin Zhang
Victor N. Pastushok
Reed M. Izatt
Separations Using Liquid-Liquid Systems 146(22)
9. Metal Ion Separations with Proton-Ionizable Lariat Ethers
146(10)
Richard A. Bartsch
10. Redox-Recyclable Extraction and Recovery of Heavy Metal Ions and Radionuclides from Aqueous
156(12)
Steven H. Strauss
Separations Using Solid-Liquid Systems 168(112)
11. Structural Basis of Selectivity in Tunnel Type Inorganic Ion Exchangers
168(15)
Abraham Clearfield
Damodara M. Poojary
Elizabeth A. Behrens
Roy A. Cahill
Anatoly I. Bortun
Lyudmila N. Bortun
12. Metal Ion Separations with Lariat Ether Ion-Exchange Resins
183(11)
Richard A. Bartsch
Takashi Hayashita
13. Design of Novel Polymer-Supported Reagents for Metal Ion Separations
194(12)
Spiro D. Alexandratos
Latiff A. Hussain
14. Recent Advances in the Chemistry and Applications of the Diphonix Resins
206(13)
E. Philip Horwitz
Renato Chiarizia
Spiro D. Alexandratos
Michael Gula
15. Reillex-HPQ Anion Exchange Column Chromatography: Removal of Pertechnetate Ion from DSSF-5 Simulant
219(15)
Norman C. Schroeder
Susan D. Radzinski
Jason R. Ball
Kenneth R. Ashley
Glenn D. Whitener
16. Extraction Chromatography: Progress and Opportunities
234(17)
Mark L. Dietz
E. Philip Horwitz
Andrew H. Bond
17. Metal-Ion Separations Using SuperLig or AnaLig Materials Encased in Empore Cartridges and Disks
251(9)
Garold L. Goken
Ronald L. Bruening
Krzysztof E. Krakowiak
Reed M. Izatt
18. Biologically Generated Materials for Metal-Ion Binding: Answers to Some Fundamental Chemical Questions
260(20)
Gary D. Rayson
Lawrence R. Drake
Hongying Xia
Shan Lin
Paul J. Jackson
Separations Using Membranes 280(53)
19. Use of Ligand-Modified Micellar-Enhanced Ultrafiltration to Selectively Remove Copper from Water
280(14)
Susan B. Shadizadeh
Richard W. Taylor
John F. Scamehorn
Annette L. Schovanec
Sherril D. Christian
20. Water-Soluble Metal-Binding Polymers with Ultrafiltration
294(39)
Barbara F. Smith
Thomas W. Robison
Gordon D. Jarvinen
Separations Using Chromatographic and Supercritical Fluid Extraction Systems 333(70)
21. Different Two-Phase Liquid Systems for Inorganic Separations by Countercurrent Chromatography
333(14)
Boris Ya. Spivakov
Tatiana A. Maryutina
Petr S. Fedotov
Svetlana N. Ignatova
22. Fundamental Aspects of Metal-Ion Separations by Centrifugal Partition Chromatography
347(43)
Subramaniam Muralidharan
Henry Freiser
23. Extraction and Separation of Uranium and Lanthanides with Supercritical Fluids
390(13)
Chien M. Wai
Yuehe Lin
Min Ji
Karen L. Toews
Neil G. Smart
Indexes 403
Author Index 403(2)
Subject Index 405

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The New copy of this book will include any supplemental materials advertised. Please check the title of the book to determine if it should include any access cards, study guides, lab manuals, CDs, etc.

The Used, Rental and eBook copies of this book are not guaranteed to include any supplemental materials. Typically, only the book itself is included. This is true even if the title states it includes any access cards, study guides, lab manuals, CDs, etc.

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