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9783527311613

Handbook of Homogeneous Hydrogenation, 3 Volume Set

by ;
  • ISBN13:

    9783527311613

  • ISBN10:

    3527311610

  • Edition: 1st
  • Format: Hardcover
  • Copyright: 2006-12-15
  • Publisher: Wiley-VCH

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Summary

This multi-volume handbook is the first to cover all questions concerning homogeneous hydrogenation. As such, it presents the catalysts, the scope of their application, mechanistic aspects, asymmetric methods, combinatorials catalysis, recycling methods and industrial examples. In 45 clearly structured chapters, the book includes all hydrogenation reactions catalyzed by soluble transition metal-based catalysts. All authors adopt an applied approach, emphasizing those aspects important for industrial use. With some 2,000 illustrations and 50 tables, this is a must-have for everyone working in the chemicals and pharmaceutical industries, as well as for graduate students in chemistry.

Author Biography

Kees Elsevier was born in 1957 in Den Haag, The Netherlands. He obtained his masters and PhD in chemistry at Utrecht University (1984) with Dr P. Vermeer and Professor H.J.T. Bos, on the topic of "transition-metal mediated synthesis of chiral allenes". Subsequently he moved to the University of Amsterdam, where he has developed his interests in organometallic chemistry and catalysis employing late-transition-metal compounds. He became associate professor in 1991, and then occupied the John van Geuns chair for developing transition-metal-NMR spectroscopy from 1995 till 1999. Since 1999 he holds the chair of Molecular Inorganic Chemistry at the University of Amsterdam. He has been visiting professor twice at the Weizmann Institute of Science, Israel, and at the Universities of Strasbourg and Toulouse (France). He is co-author of about 180 scientific papers on various topics in organometallic chemistry, homogeneous catalysis, and (transition metal) NMR spectroscopy, including contributions to several books. He has lately focused on Pd-catalyzed hydrogenations, involving N-ligands and N-heterocyclic carbenes, as well as catalysis involving aggregates (micelles and vesicles) of metallo-amphiphiles. He has supervised 20 PhD graduations. Kees serves on the advisory board of several scientific journals and he is scientific director of the Holland Research School of Molecular Chemistry.

Hans de Vries was born in Amsterdam, the Netherlands (1951). In 1979 he received his Ph.D from the University of Groningen, were he worked under the guidance of Richard M. Kellogg on chiral, bridged dihydropyridines as NADH-mimetics. After a postdoctoral stint at Brandeis University, Waltham, USA with Jim Hendrickson (total synthesis of Methoxatin or PQQ) from 79-81 he moved back to Europe. From 1982-1988 he worked as medicinal chemist for Sandoz, first in Vienna, afterwards in London. Being more interested in chemistry than drugs he moved back to the Netherlands, were he took up employment with DSM, a multinational specialty chemicals company. His current job is Principal Scientist Homogeneous Catalysis for Fine Chemicals. Since 1998 he has been appointed as part-time professor at the University of Groningen. In 2000 he was appointed visiting industrial professor at the Univeristy of Bristol. During 2005 he was a visiting professor at the Universit+¬ Louis Pasteur, Strasbourg. His research interests are in the area of asymmetric hydrogenation (MonoPhos), aromatic substitution ("homeopathic" palladium), hydroformylation, metathesis, combinations of enzymes with transition metal catalysis, HTS, combinatorial catalysis and process intensification. He is (co-)author of 20 patents and over 100 publications. He is married and has three children.

Table of Contents

Foreword
Preface
List of Contributors
Introduction: Organometallic Aspects and Mechanism of Homogeneous Hydrogenation
Rhodium (Luis A. Oro and Daniel Carmona)
Introduction
The Early Years (1939-1970)
The [RhH(CO)(PPh3)3] Catalyst
The [RhCl(PPh3)3] Complex and Related Catalysts
The Cationic[Rh(diene)(PR3)X]+ Catalysts
Enantioselective Rhodium Catalysts
Some Dinuclear Catalyst Precursors
Concluding Remark
Abbreviations
References
Iridium (Robert H. Crabtree)
Introduction
Historical Aspects
Organometallic Aspects
Catalysis
Acknowledgments
Abbreviations
References
Ruthenium and Osmium (Robert H. Morris)
Introduction
Ruthenium
Osmium
Acknowledgment
Abbreviations
References
Palladium and Platinum (Paolo Pelagatti)
Introduction
Palladium
Platinum
Abbreviations
References
Nickel (Elisabeth Bouwman)
Introduction
Coordination Chemistry and Organometallic Aspects of Nickel
Hydrogenation Catalysis
Concluding Remarks
Abbreviations
References
Hydrogenation with Early Transition Metal, Lanthanide and Actinide Complexes (Christophe Coperet)
Introduction
Mechanistic Considerations
Group IV Metal Hydrogenation Catalysts
Hydrogenation Catalysts Based on Group III, Lanthanide, and Actinide Complexes
Hydrogenation Catalysts Based on Groups V-VII Transition-Metal Complexes
Supported Early Transition-Metal Complexes as Heterogeneous Hydrogenation Catalysts
Conclusions.Acknowledgments
Abbreviations
References
Ionic Hydrogenations (R. Morris Bullock)
Introduction
Stoichiometric Ionic Hydrogenations
Catalytic Ionic Hydrogenation
Ruthenium Complexes Having an OH Proton Donor and a RuH as Hydride Donor
Catalytic Hydrogenation of Ketones by Strong Bases
Conclusion
Acknowledgments
Abbreviations
References
Homogeneous Hydrogenation by Defined Metal Clusters
Introduction
Hydrogenation of C=C Bonds
Hydrogenation of CC Bonds
Hydrogenation of Other Substrates
Concluding Remarks
Abbreviations
References
Homogeneous Hydrogenation: Colloids - Hydrogenation with Noble Metal Nanoparticles
Introduction
Concepts
Hydrogenation of Compounds with C=C Bonds
Hydrogenation of Compounds with CC Bonds
Arene Hydrogenation
Hydrogenation of Compounds with C=O Bonds
Enantioselective Hydrogenation
Conclusion.Abbreviations.References
Kinetics of Homogeneous Hydrogenations: Measurement and Interpretation
Introduction
The Basics of Michaelis-Menten Kinetics
Hydrogenation From a Kinetic Viewpoint
Abbreviations
References
Spectroscopic Methods in Homogeneous Hydrogenation
Nuclear Magnetic Resonance Spectroscopy in Homogeneous Hydrogenation Research
Introduction
NMR Methods
Outlook.Abbreviations
References
Parahydrogen-Induced Polarization: Applications to Detect Intermediates of Catalytic Hydrogenations
In-Situ Spectroscopy
Ortho- and Parahydrogen
Applications of PHIP-NMR Spectroscopy
Catalyst-Attached Products as
Table of Contents provided by Publisher. All Rights Reserved.

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