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Dennis W. Smith Jr. is a Professor of Chemistry at The University of Texas at Dallas, Texas. Previously, he was at The Dow Chemical Company Central Research Laboratory and worked in synthesis and characterization. His research interests include synthesis, mechanism, structure/property relationships, and applications of polymer materials and composites.
Scott T. Iacono is an Associate Professor of Chemistry and concurrently serves as the Chemistry Research Center Director at US Air Force Academy. His research focuses on organofluorine methodologies for monomer development for fluorosiloxane polymers, metalized fluoropolymer composites, and fulvene-based conjugated polymers for light emissive applications.
Foreword ix Patrick E. Cassidy
In Memoriam xi
Preface xiii
Contributors xv
About the Editors xxi
1 Fluorinated Polyphosphazenes 1 Harry R. Allcock
2 Mn2 (CO)10-Visible Light Photomediated, Controlled Radical Polymerization of Main Chain Fluorinated Monomers and Synthesis of Block Copolymers Thereof 21 Alexandru D. Asandei, Olumide I. Adebolu, and Christopher P. Simpson
3 Interfacial Response of Semifluorinated Multi-block Copolymers 43 Anupriya Agrawal, Dipak Aryal, Dvora Perahia, and Gary S. Grest
4 Fluoropolymer Nanocomposites 57 Hideo Sawada
5 Thermal Degradation and Pyrolysis of Polytetrafluoroethylene 81 Gerard Puts, Philip Crouse, and Bruno Ameduri
6 Molecular Simulation of Fluoropolymers 105 Armand Soldera, Francois Porzio, and Nasim Anousheh
7 Vapor Deposition of Fluoropolymer Surfaces 131 Jose Yague and Karen K. Gleason
8 Functionalized and Functionalizable Fluoropolymer Membranes 149 Tao Cai, Koon-Gee Neoh, and En-Tang Kang
9 Poly[Methyl(3,3,3-Trifluoropropyl)Siloxane] 183 Michael J. Owen
10 Functional Fluorous Copolyoxetane Polymer Surface Modifiers 201 Kenneth J. Wynne, Pinar Kurt, Umit Makal, Tomoko Fujiwara, Kennard Brunson, Asima Chakravorty, Lynn Wood, and Dennis E. Ohman
11 Self-Organizing Semifluorinated Methacrylate Copolymers 235 Doris Pospiech and Dieter Jehnichen
12 Synthesis of Fluoropolymers Using Borane-Mediated Control Radical Polymerization for Energy Storage Applications 291 T.C. Mike Chung
13 Fluoropolymers in Supercritical Carbon Dioxide: Phase Behavior, Self-Assembly, and Stabilization of Water/CO2 Emulsions 315 Etienne Girard, Jean-Daniel Marty, and Mathias Destarac
14 Semifluorinated Polymers from Trifluorovinyl Aromatic Ether Monomers 343 Jianyong Jin, Scott T. Iacono, and Dennis W. Smith Jr.
15 Combustion Characterization of Energetic Fluoropolymer Composites 363 Oliver Mulamba and Michelle Pantoya
16 Amorphous Perfluoropolymers 377 Yoshiyuki Okamoto, Frantisek Mikes, Kotaro Koike, and Yasuhiro Koike
17 Fluoropolymers for Sustainable Energy 393 Vincenzo Arcella, Luca Merlo, Riccardo Pieri, Paolo Toniolo, Francesco Triulzi, and Marco Apostolo
18 Evolution of Academic Barricades for the Use of Tetrafluoroethylene (TFE) in the Preparation of Fluoropolymers 413 Daniel A. Hercules, Darryl D. DesMarteau, Richard E. Fernandez, James L. Clark Jr., and Joseph S. Thrasher
19 Fluoropolymer Surfaces/Interfaces 433 Yuji Higaki, Ryohei Ishige, and Atsushi Takahara
20 Fluoropolymer Dielectrics 451 Mustapha Raihane and Bruno Ameduri
21 Fluoropolymers—Environmental Aspects 495 Klaus Hintzer and Werner Schwertfeger
22 Fluorinated Ionomers and Ionomer Membranes Containing the bis[(perfluoroalkyl) sulfonyl]imide Protogenic Group 521 Iqbal Sharif, Stephen Creager, and Darryl D. DesMarteau
23 Fluorinated Silsesquioxanes 545 Sean Ramirez and Joseph Mabry
24 Multidimensional NMR of Fluoropolymers 565 Xiaohong Li, Jessi Baughman, Chun Gao, Linlin Li, Peter L. Rinaldi, Eric B. Twum, Elizabeth F. McCord, and Faith J. Wyzgoski
25 Melt Processible Perfluoroplastics for Demanding Applications 599 Paul Brothers, Gregory Chapman, Kimberly Farnsworth, and Richard Morgan
Index 623
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