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9780124666153

Handbook of Palladium-Catalysed Organic Reactions: Synthetic Aspects and Catalytic Cycles

by ; ;
  • ISBN13:

    9780124666153

  • ISBN10:

    0124666159

  • Edition: CD
  • Format: Paperback
  • Copyright: 1997-01-01
  • Publisher: Academic Pr
  • Purchase Benefits
List Price: $137.00
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Summary

This comprehensive handbook will be an indispensable research tool for chemists. Handbook of Palladium Catalysed Organic Reactions provides a synoptic description of the main types of reactions which are catalyzed by Palladium and the mechanism which causes these reactions. Each reaction is presented in graphical form and classified according to the type of transformation involved. Other books covering the use of Palladium complexes as catalysts have been written, but the Handbook is the only to offer a synoptic view, showing the catalytic cycle of each reaction. This complete coverage provides the reader with a good understanding of the parameters involved. The tables included can be viewed from the point of view of the reagents, the product of the reaction, or the mechanism involved. The Handbook is a companion to the Database of Palladium Chemistry: Reactions andCatalytic Cycles, published on CD-ROM. Key Features * Begins with explicit instructions from the authors, facilitating use of the Handbook * Details the associated catalytic cycle for each class of reactions * Offers a choice of references, allowing the reader to find the closest example for solving a given problem * 84 types of mechanism covered, plus over 2500 references * Presents graphical abstracts for all reactions described, making it easy to search a type of reaction * Comb-bound for easy reference * Free demo disk included for the Database of Palladium Chemistry * A versatile tool for chemists in the academic community, this handbook will be an invaluable tool in the laboratory * 84 types of mechanism covered, plus over 2500 references * Presents graphical abstracts for all reactions described, making it easy to search a type of reaction * Comb-bound for easy reference * Free demo disk included for the Database of Palladium Chemistry * A versatile tool for chemists in the academic community, this handbook will be an invaluable tool in the laboratory.

Table of Contents

Foreword ix(1)
Abbreviations x
I Introduction
1(4)
II Graphical abstracts of reaction numbers (RXN)
5(18)
III Reactions catalysed by palladium complexes
23
RXN1 Cross-Coupling of Organometallics with RX Derivatives
23(25)
RXN2 Cross-Coupling of Organometallics with RCOX Derivatives
48(5)
RXN3 Cross-Coupling of Siloxycyclopropanes with RX and RCOX Derivatives
53(2)
RXN4 Cross-Coupling of Terminal Alkynes with RX Derivatives
55(6)
RXN5 Intermolecular HECK Reaction
61(11)
RXN6 Intramolecular HECK Reaction
72(8)
RXN7 Intramolecular Coupling of Di(Vinyl Halides)
80(2)
RXN8 Tandem HECK-Anion Capture Process of Alkenes, Alknes, Allenes and Dienes
82(4)
RXN9 Tandem HECK-Anion Capture Process of Norbornene and Related Compounds
86(3)
RXN10 Tandem Arylsulfonation-Cyclization Process
89(2)
RXN11 Tandem Cyclization-Anion Capture(-Carbonylation) Process of Alkenes, Allenes and Alkynes
91(4)
RXN12 Tandem Cyclization-Anion-Capture Process of Ene-Vinyl, Ene-Aryl and Ene-Alkyl Halides
95(4)
RXN13 Tandem Cyclization-Anion Capture (-Carbonylation) Process of Yne-Vinyl and Yne-Aryl Halides
99(3)
RXN14 Hydroarylation and Hydrovinylation of Alkenes and Alkynes
102(4)
RXN15 Reduction of Alkenes
106(2)
RXN16 Semihydrogenation of Alkynes and 1,3-Dienes
108(2)
RXN17 Hydroboration, Hydrogermylation, Hydrosilylation and Hydrostannation of Alkynes, Allenes, Dienes and Enynes
110(3)
RXN18 Hydroselenation of Alkynes
113(2)
RXN19 1,4-Disilylation of Conjugated Enones
115(2)
RXN20 Hydrocarboxylation, Hydrocarboalkoxylation and Hydrocarboamination of Alkenes and Alkynes
117(3)
RXN21 Tandem Carbonylation-Arylation with Alkynes
120(3)
RXN22 1,2-Dimetallation of Alkynes and Alkenes and Related Reactions
123(3)
RXN23 1,2-Dimetallation of Isonitriles
126(2)
RXN24 1,2-Dimetallation of Allenes or 1,3-Dienes
128(3)
RXN25 Coupling of Aryl Derivatives with Alkenes Involving a Pd(II) Catalyst
131(2)
RXN26 Homocoupling of Aryl and Vinyl Derivatives
133(2)
RXN27 Codimerization of Alkynes
135(3)
RXN28 codimerization of Terminal Alkynes with Allenes
138(2)
RXN29 Codimerization of Alkynes and Allyl Halides
140(3)
RXN30 Cyclopropanation of Alkenes and 1,3-Dienes by Diazomethane
143(2)
RXN31 Rearrangement of a-Hydroxy Diazo Compounds
145(2)
RXN32 Substitution, Addition and Elimination on Pro-Allyl Substrates
147(24)
RXN33 [3,3]-Sigmatropic Rearrangement and [1,3]-Shift on Allylic Derivatives
171(4)
RXN34 1,3-Diene Monoepoxide Rearrangement
175(2)
RXN35 Ring Extension of Cyclobutane Derivatives
177(3)
RXN36 [3+2],[3+4],[3+6],[1+2] Cycloadditions
180(4)
RXN37 Intramolecular Ene-Like Reactions
184(4)
RXN38 Cyclization of Hexatrienolate Derivatives
188(2)
RXN39 Amination or Amidation of Alkenes
190(2)
RXN40 Alkoxylation of Alkenes and Alkynes
192(2)
RXN41 Acetalization of Alkenes
194(2)
RXN42 Allylic Acyloxylation of Cycloalkenes
196(2)
RXN43 Tandem Acyloxylation-Cyclization of 1,5-Dienes
198(2)
RXN44 Tandem Acyloxychlorination-Cyclization of 1,6-Dienes
200(2)
RXN45 1,4-Acyloxychlorination of 1,3-Dienes
202(2)
RXN46 1,4-Diacyloxylation of 1,3-Dienes and Related Reactions
204(2)
RXN47 Intramolecular Amination, Alkoxylation or Acyloxylation of Alkynes
206(2)
RXN48 Tandem Intramolecular Amination, Alkoxylation or Acyloxylation-Allylation of Alkynes and Allenes
208(2)
RXN49 Tandem Intramolecular Amination, Alkoxylation or Acyloxylation-Carbonylation of Alkynes
210(3)
RXN50 Intramolecular Amination or Alkoxylation of Alkenes
213(3)
RXN51 Tandem Intramolecular Amination or Alkoxylation-Carbonylation of Alkenes and Allenes
216(4)
RXN52 Reductive Cyclization with Diynes and Enynes
222(4)
RXN53 Cycloisomerization of Diynes and Enynes
222(4)
RXN54 Cycloaddition of Aziridines with Carbodiimides
226(2)
RXN55 Telomerization of 1,3-Dienes with Nucleophiles
228(4)
RXN56 WACKER Process
232(3)
RXN57 Preparation of Ketones from Alcohols or Derivatives via a B-Hydride Elimination
235(3)
RXN58 Preparation of a,B-Unsaturated Carbonyl Derivatives via a B-Hydride Elimination
238(3)
RXN59 Preparation of a-Diketones Derivatives via an Oxidative Rearrangement of a Propargyl Acetate
241(2)
RXN60 Carbonylation
243(10)
RXN61 Isomerization of Alkynes
253(3)
RXN62 Addition of Thiols to Alkynes
256(2)
RXN63 Preparation of Allylic Acetates from Alkynes by Tandem Redox-Addition
258(2)
RXN64 Tandem Cyclization-Capture Process of Enynes
260(2)
RXN65 Aldol-Like Condensation of Enol Esters with Aldehydes
262(2)
RXN66 Addition of Fluroalkyl Iodides to Alkenes or Alkynes via a Pd(I) Species
264(2)
RXN67 Intermolecular Tandem Carbonylation-Coupling-Cyclization Process of Aryl Halides with Terminal Alkynes
266(2)
RXN68 Intramolecular Coupling of Aryl Halides with Arenes
268(2)
RXN69 Tandem Intramolecular Alkoxylation-Vinylation of Alkenes
270(2)
RXN70 Carbonylative [2+2] Cycloaddition
272(2)
RXN71 Dicarboalkoxylation of Alkenes
274(2)
RXN72 Addition of Pronucleophiles on 1,3-Dienes or Allenes
276(3)
RXN73 Tandem Cycloisomerization-Cycloaddition of Dienynes with 1,3-Dienes via Metallodienes
279(2)
RXN74 Acylcyanation of Terminal Alkynes
281(2)
RXN75 1,4-Carbochlorination of 1,3-Dienes
283(2)
RXN76 Tandem Chlorination-Cyclization and Tandem Chlorination-Carbonylation-Cyclization of 1,6-Enynes
285(3)
RXN77 Intramolecular Cyclocarbonylation of Alkanes
288(2)
RXN78 Tandem Carbonylation-Cyclization of (Z)-B-Iodoenones and Related Reaction from Aryl Iodides and Internal Alkynes
290(2)
RXN79 Cross-Coupling of Organometallics with Terminal Alkynes and lodotrimethysilane
292(2)
RXN80 Preparation of a, B-Unsaturated Carbonyl Derivatives from Enol Silanes
294(2)
RXN81 1,3-Butadien-2-ylaminocyclization of Allenyl Tosylcarbamates
296(2)
RXN82 Addttion of Pronucleophiles on Aldehydes
298(3)
RXN83 Allylation of Pronucleophiles with Allylstannanes
301(2)
RXN84 Cross-Coupling Carbonylation of Aryl lodides with Five-Membered Cyclic Olefins
303

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