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9780444899095

Synthetic Metals for Non-Linear Optics and Electronics: Proceedings of Symposium E on Synthetic Metals for Non-Linear Optics and Electronics of the

by ; ;
  • ISBN13:

    9780444899095

  • ISBN10:

    044489909X

  • Format: Hardcover
  • Copyright: 1993-04-01
  • Publisher: Elsevier Science Ltd

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Summary

Recent progress in organic and LED structures, in photorefractive response in molecular ferromagnetism, as well as the ultrafast and large non-linear optical response in conjugated systems are attracting great interest from the scientific community. The discovery of fullerenes has added further impetus to this field. Two areas bear particular promise for the development of a new electronics based on SEM materials: the integration of organic materials into the planar silicon technology such as, for instance, the advances in "all organic" field-effect transistors (FET) and the new organic light emitting diodes (LED); and secondly the appearance of a totally new electronics in which photons, rather than electrons, carry the information and SEM materials act as switching devices. Both aspects and more are covered in this volume. The quality of the 52 contributions attests to the fact that this subject area has progressed from the level of a scientific curiosity to a mature field of materials science introducing important technological perspectives for electronic applications.

Table of Contents

Preface
Sponsors
Molecular crystals: past and presentp. 1
Photoconduction and photorefraction in molecularly doped polymersp. 9
Nonlinear optical properties of sublimed C[subscript 60] thin filmsp. 21
Electronic excitations and alternation of conjugated polymersp. 35
Anion and cation absorption spectra of conjugated oligomers and polymerp. 49
Electronic levels ordering in [alpha]-sexithienylp. 57
Sample dependence of the magnetic behaviour of polyacetylene. A pulsed ESR comparative studyp. 67
Ultrafast relaxation in conjugated polymersp. 75
Picosecond transient resonant Raman scattering in partially isomerized polyacetylene filmsp. 93
Studies of photoexcitations in conducting polymers by the absorption-detected magnetic resonance techniquep. 99
Intrachain photogeneration of polarons in poly(3-methylthiophene)p. 113
New advances in molecular engineering for quadratic nonlinear opticsp. 123
Quadratic nonlinear optical properties of thermally crosslinkable polymersp. 139
Electro-optic modulator and second-harmonic generator with nonlinear polymersp. 147
Recent advances in the synthesis and characterization of nonlinear optical materials: second-order materialsp. 155
Transport properties of Q1D metals (electron-electron scattering)p. 163
Two-phonon Raman scattering in Q1D conducting materials with soft phonon modep. 169
Theoretical investigation on the effects of methyl substitution on the electronic properties of polysilanep. 173
Electronic properties of poly(pyrrylene vinylenes): a theoretical approachp. 181
New conductive polymeric systemsp. 187
Electrochemical behaviour and structural characterization of highly crystalline poly(p-phenylene) films obtained by oxidation of benzene in a concentrated sulfuric acid emulsionp. 195
Thermal dedoping of poly(3-n-hexylthiophene) filmsp. 203
Electron spectroscopic studies of models for PPP and PT on p- and n-dopingp. 209
Stability of thick polypyrrole films electrogenerated on stainless steelp. 217
Polymerization of pyrrole by laser induced photolysis of onium saltsp. 223
Langmuir-Blodgett and vacuum sublimed films of terbium bisphthalocyaninep. 229
Femtosecond dynamics, photoexcitation and ESR spectra of MX chain solidsp. 237
Light induced conversion of chlorine containing polymers in the presence of pyrrole into conducting patternsp. 243
Physical properties of achiral mesomorphic ferroelectricsp. 253
Photoluminescence of solid state fullerenesp. 265
ODMR spectroscopy of photoexcitations in C[subscript 60] and C[subscript 70] polystyrene glassesp. 273
Time-resolved luminescence measurements in poly(p-phenylenevinylene)p. 281
Non-linear optical properties modification in some substituted polydiacetylenes due to change of basicity constant of the side groupsp. 289
Non-linear optical properties of conjugated polymers in the SSH model: third harmonic generationp. 295
Characterization of optical third-order non-linearities by prism coupling and pulse shape analysis on a ps timescalep. 301
Surface-plasmon-resonance investigations of Langmuir-Blodgett films of donor-acceptor substituted polyenes: linear optical and electro-optic propertiesp. 307
Dynamic light modulation in an electrochromic window consisting of polyaniline, tungsten oxide and a solid polymer electrolytep. 315
Magneto-optical characterization of excited states in short trans chains of partially isomerized polyacetylenep. 321
Second optical harmonic generation in the vicinity of insulator-to-metal transition in polyaniline filmp. 327
Photoexcitations in polyacetylene with controlled conjugation lengthp. 331
Scanning tunnelling microscopy of several alkylated molecular moieties in monolayers on graphitep. 339
Epitaxial phthalocyanine thin films and phthalocyanine/C[subscript 60] multilayersp. 351
Processing of conducting DCNQI radical ion salt films by solid state reactionsp. 363
Photoinduced orientation of azo dyes in polymeric films. Characterization of molecular angular mobilityp. 373
Photoinduced electron-hole charge separation, intrinsic self-doping and novel device applications of Q1D heterojunction materials: mixed-halide MX solidsp. 385
Exciton kinetics in poly(di-n-hexylsilane)p. 391
Conjugated polymer electroluminescencep. 401
Trap-free charge transport in polymers, with tunable mobilitiesp. 417
Electrical and optical characterization of poly(phenylene-vinylene) light emitting diodesp. 427
All-organic field-effect transistors made of [pi]-conjugated oligomers and polymeric insulatorsp. 435
Electrical characteristics of field-effect transistors formed with ordered [alpha]-sexithienylp. 447
The application of polypyrrole as counterelectrode in electrolytic capacitorsp. 453
Author Indexp. 461
Subject Indexp. 463
Table of Contents provided by Blackwell. All Rights Reserved.

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