Selectivity in Catalysis

by Davis, Mark E.; Suib, Steven L.

• ISBN13: 9780841225190
• ISBN10: 0841225192
• Format: Hardcover
• Copyright: 1993-05-05
• Publisher: American Chemical Society

Summary

Discusses recent research and provides tutorial chapters on enhancing selectivity in catalysis through stereoselectivity, reaction pathway control, shape selectivity, and alloys and clusters. Presents an interdisciplinary approach to increasing selectivity in homogeneous and heterogeneous catalysis research. Includes an overview chapter that discusses the current state of the field and offers a perspective on future directions.

Table of Contents

Selectivity in Catalysis: An Overview

Stereoselectivity: The Ultimate Challenge in Catalysis

Asymmetric Catalytic Hydrogenation of 2-Arylacrylic Acids as a Low-Cost Route to Pharmaceutical Products

Chiral Rhodium(II) Carboxamides: Remarkably Effective Catalysts for Enantioselective Metal Carbene Transformations

Discrete Chiral Rhodium Phosphine Complexes as Catalysts for Asymmetric Hydrosilation of Ketones

Catalytic Asymmetric Heck Reaction

Clusters, Alloys, and Poisoning: An Overview

Platinum-Tin-Alumina Catalysts: Comparison of Alkane Dehydrocyclization Activity and Characterization Data

Alkyne Coordination, Dimerization, and Scission on a Tungsten-Triiridium Cluster Core: Reaction Modeling Studies Related to Cluster-Derived Butane Hydrogenolysis Catalysts

Platinum-Tin and Gold-Tin Bimetallic Particles Prepared from Solvated Metal Atoms: Structure and Catalysis

Mechanism and Selectivity in Catalytic Olefin Polymerization

Effect of A Model Hydrogenation on a Catalytic Palladium Membrane

Vanadium Migration between Model Components of Fluid Cracking Catalysts: SEM-EDX Studies

Shape Selective Catalysis with Zeolites and Molecular Sieves

Reactions of meta-Diisopropylbenzene on Acid Molecular Sieves

Methyl tert-Butyl Ether and Ethyl tert-Butyl Ether: Synthesis over Triflic Acid Modified Y-Zeolite

Design of Layered Phosphate Hosts Containing Multiply Bonded Bimetallic Guest Species

Nuclear Magnetic Resonance Imaging of Anisotropic Solid-State Chemical Reactions

Homogeneous Adsorption of Benzene on NaX and NaY Zeolites

Reaction Pathway Analysis: Global Molecular and Mechanistic Perspectives

Preparation, Characterization, and Catalysis of a Modified ZSM-5 Zeolite

Effect of Catalyst Preparation on the Aromatization of n-Hexane over Pt Clusters Supported on Hydrotalcite

Reactions of Ethylene over

Activation of C-H, C-C, and C-O Bonds of Oxygenates on Rh(111)

Continuous Catalytic Conversion of Acetylene to Higher Hydrocarbons over a Metal Modified Shape Selective Zeolite Catalyst

Characterization of RuCl3-Impregnated NaY Zeolite

Non-Flory Product Distributions in Fischer-Tropsch Synthesis Catalyzed by Ruthenium, Cobalt and Iron

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