Silicon-Based Polymer Science A Comprehensive Resource

by Zeigler, John M.; Fearon, F. W. Gordon

• ISBN13: 9780841215467
• ISBN10: 0841215464
• Format: Hardcover
• Copyright: 1989-05-05
• Publisher: American Chemical Society

Summary

This book provides the first unified reference work for silicon-based polymers. It brings together in one volume research on the synthesis, properties, chemistry, electronic structure, applications, and technology of these materials. The volume is built around a series of critical overviews ofthese rapidly advancing fields and is supplemented by a substantial number of shorter papers that focus on current findings. It also provides insight into possible directions for future scientific and technological advances in the field.

Table of Contents

Introduction: My Favorite Element Organosilicon Chemistry

A Brief Overview Silicon-Containing Polymers

Formation of Linear Siloxane Polymers

Thermal and Rheological Properties of Alkyl-Substituted Polysiloxanes

Pyrid- and 1-Oxypridinyl-Substituted Silanes and Siloxanes

New Catalysts for Interfacial Transacylation Reactions

Polysiloxane-Based Polymer-Electrolyte Complexes Conformational

Analysis of Substituted Polysiloxane Polymers

Synthesis and Fractionation Studies of Functionalized Organosiloxanes Novel Poly(imide-siloxane)

Polymers and Copolymers Polysiloxane-Thermoplastic

Interpenetrating Polymer Networks Non-Gaussian

Effects and Intermolecular Correlations in Bimodal Networks of Poly(dimethyisiloxane)

New Inorganic-Organic Hybrid Materials

Through the Sol-Gel Approach Structure and Growth of Silica Condensation Polymers

Hydrolysis and Condensation Kinetics of Dimeric Sol-Gel Species by 29Si NMR Spectroscopy

A Silicate Substitution Route to Organosilicon Compounds

Organosilicon Polymers for Microlithographic Applications

Modifications of Well-Defined Polysilanes

Mechanistic Studies of Polysilane Polymerization

Polymers and Copolymers of Disilacyclohexadiene

A Non-Alkali-Metal Route to Polysilanes

Transition-Metal-Substituted Oligo- and Polysilanes

Structures, Phase Transitions, and Morophology of Polysilylenes

Order-Disorder Transitions and Thermochromism of Polysilylenes in Solution

Theory and Experiment Configurational Properties of a Stiff-Chain

Diaryl-Substituted Polysilane in Dilute Solution Radiation

Sensitivity of Soluble Polysilane Derivatives Exciton

Exciton Annihilation in Polysilanes Electronic Transport in Polysilylenes

Synthesis and Properties of Silicon-Branched Organosilicon Polymers

Electronic Structures of Silicon

Based Polymers Band Structure and Optical Absorption

Properties of Polysilane Chains Ground States and Ionization

Energies of Polysilane Oligomers

Synthesis of Some Organosilicon Polymers and Their Pyrolytic Conversion to Ceramics

Polymeric Routes to Silicon Carbide and Silicon Nitride Fibers

New Polymer Precursors for Silicon Nitride Oxidation

Reaction of Polycarbosilane Synthesis and Properties of Silicon-Containing

Polyacetylenes Brominated Poly(1-trimethylsilyl-1-propyne)

Lithography and Photochemistry Stereoregular

Anionic Ring-Opening Polymerization of Silacyclopent-3-enes

Stereoregular 1,4 Polymerization of 2-Triethylsilyl-1,3-butadiene

Synthesis and Lithographic Evaluation of a Poly(acylsilane)

Siloxane Surface Activity Synthesis, Properties, and Potential

Applications of Silphenylene-Siloxane Polymers Future

Directions for Silicon-Based Polymers

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