Solid State Ionics: Materials and Devices : Fuzhou, China 29 October-4 November 2000

by Chowdari, B. V. R.; Wang, Wenji

• ISBN13: 9789810244927
• ISBN10: 9810244924
• Format: Hardcover
• Copyright: 2001-02-01
• Publisher: WORLD SCIENTIFIC PUB CO INC

Summary

Solid atate ionics, being a multidisciplinary area, is expected to grow at a faster rate in the new millennium, prompting the discovery of new materials and devices, as well as helping to optimize the known devices, especially the portable power sources and display systems. The Asian Society for Solid State Ionics (ASSSI) plays a significant role in bringing together researchers from the Asian countries, every two years, to exchange notes and ideas, to foster friendship and collaboration, and to discuss the prospects.The topics covered in this volume are: ion dynamics, theoretical modeling, ion-conducting polymers, gels and ceramics, glasses, crystalline materials including nano-phases, composites, electrode/electrolyte interfaces and novel experimental techniques. Papers on crystalline materials deal with ion conduction in Li, Na, Ag, Tl, F and O-containing compounds. Materials and device aspects have received wide coverage, especially the areas of lithium ion batteries (LIBs) and solid oxidefuel cells,(SOFCs).Rechargeable high energy density LIBs, especially those employing immobilized gel or polymer electrolyte, are the favorite portable power sources in the new millennium. As expected, a large number of papers on both cathodes and polymer electrolytes for LIBs were presented at the conference. The papers on fuel cells almost exclusively deal with SOFCs, indicating the great importance being given to this area in Japan and China. A breakthrough in materials and technology of SOFC is expected in the coming decade. This volume will be useful not only to the active researchers in the field but also to youngsters entering the exciting area of solid state ionics.

Table of Contents

Preface	vii
[A] CRYSTALLINE MATERIALS
Concepts and materials aspects of developing solid state ionic devices (Invited)	3	(10)
Werner Weppner
Failure of the Nernst--Einstein equation in mixed conductor compounds (Invited)	13	(10)
Han-III Yoo
Ion dynamics in superionic crystals by means of hole burning spectroscopy (Invited)	23	(10)
Takeshi Hattori
Fluoride ion conductor RSn2F5 (R=K and Rb) studied by X-ray diffraction and 19F, 119Sn NMR (Invited)	33	(8)
Tsutomu Okuda
Keiji Saisho
Yasuhiko Ogiso
Koji Yamada
Jun Chikami
Gerhard Miehe
Helmut Ehrenberg
Hartmut Fuess
Development of electrochemical measurements in ionics materials: Neutron radiography (Invited)	41	(10)
Takao Esaka
Estimation of the superionic transition temperature from the variation of bond orbital energy	51	(6)
Masaru Aniya
The effect of sintering on the electrical conductivity of lithium lanthanum titanates	57	(6)
Chang Wan Ban
Gyeong Man Choi
The study of new lithium fast ion conductor Li1+2x+yAlxYyTi2-x-ySixP3-xO12 based on Kaolinite	63	(6)
Yurong Zhang
Wenji Wang
The synthesis and characterization of new lithium fast ion conductors Li1+2x+2yAlxZnyTi2-x-ySixP3-xO12 system	69	(6)
Yurong Zhang
Wenqing Chen
Wenji Wang
The synthesis and characterization on lithium fast ion conductors of Li14-xZn1-xYbx (GeO4)4 system	75	(4)
Liu Huiyong
Wenji Wang
Hydrothermally coprecipitants as a candidate for beta-alumina precursors	79	(6)
Z. Y. Wen
J. H. Yang
Z. X. Lin
D. L. Jiang
A Study of a superionic system: Agl-PbI2-Ag2O-B2O3	85	(16)
S. Selvasekarapandian
R. Chithra Devi
M. Vijayakumar
A study on Agl-MCl2-Ag2O-V2O5 (M=Cu, Zn, Ca & Hg) fast ionic conductors	101	(6)
M. Vijayakumar
B. Balasundaram
S. Selvasekarapandian
R. Chithra Devi
R. Manimozhi
P. Geethalakshimi
AgI Nanoparticles: Preparation, characterization and conductive properties	107	(6)
Yuxai Wang
Liang Huang
Shan Guan
Yunfei Zhang
Amorphization of ionic salts in nanocomposites	113	(8)
N. F. Uvarov
A. A. Politov
B. B. Bokhonov
Disorder, phonons and superionic conductivity in silver iodide	121	(4)
P. Senthil Kumar
N. S. Kini
A. M. Umarji
C. S. Sunandana
Preparation of superionic conductor AgI nano-wires in alumina template by electrochemical dual liquor deposition (EDLD)	125	(4)
Xiaodong Wu
Hong Li
Xuejie Huang
Liquan Chen
Diffusion of T1+ ions through the interface of solid NaCl or KCl and liquid TlCl	129	(6)
W. Yu
A. Fuji
Electrical properties of heavily doped fluorite-structured BaF2: RF3 (R=Rare earth element, Y, Sc) single crystals	135	(8)
V. Trnovcova
N. I. Sorokin
P. P. Fedorov
E. A. Krivandina
T. S. Sramkova
B. P. Sobolev
Fast ionic conductivity of rare earth trifluorides with orthorhombic and tysonite structures	143	(6)
V. Trnovcova
E. A. Krivandina
P. P. Fedorov
L. S. Garashina
B. P. Sobolev
Dynamic structure and ionic conduction in RMF4 (R=Na, K, Rb, Cs; M=Sb, Bi) as studied by NMR	149	(6)
K. Yamada
Y. Ohonuki
S. Fukutomi
H. Ohki
T. Okuda
Oxygen nonstoichiometry and oxygen transport properties of YBa2Cu2CoO6+δ	155	(4)
S. Ran
C. H. Zheng
W. Liu
D. K. Peng
C. S. Chen
Growth and ionic conductivity of the A2TiGeO5 (A=Na, Li) single crystals	159	(8)
A. K. Ivanov-Schitz
V. V. Kireev
O. K. Mel'nikov
N. G. Chaban
J. Schoonman
[B] GLASSES
Exploring glasses on the microscopic level by NMR: xLiF(1-x)LiPO3 (Invited)	167	(10)
D. Brinkmann
S. Berger
J. Roos
Development of lithium ion conducting oxysulfide glasses (Invited)	177	(10)
Akitoshi Hayashi
Ryoichi Komiya
Masahiro Tatsumisago
Tsutomu Minami
Conductivity spectrum and relaxations in mixed alkali fluorophosphate glasses (Invited)	187	(10)
A. R. Kulkarni
Relationship between average electronegativity and the properties of superionic glasses	197	(6)
Masaru Aniya
A new non-Debye response function and a novel power law	203	(6)
G. Govindaraj
R. Murugaraj
Anomalous conductivity of glassy Li2O:4MnO2-x: 4B2O3 during heat treatment	209	(6)
Sumin Wang
Xuejie Huang
Cailu Xu
Ji Liang
Liquan Chen
Dehai Wu
Cation doping into the sodium borate glass using the solid oxide electrochemical doping method	215	(8)
Kai Kamada
Shintaro Udo
Yasumichi Matsumoto
[C] LITHIUM BATTERIES
Cathode Materials
Lithium ion battery materials: recent trends (Invited)	223	(8)
B. V. R. Chowdari
G. V. Subba Rao
Charging-discharging properties by cut-off voltage changes of Co- and Ni-doped LiMn2O4 cathodes in Li-ion secondary batteries	231	(6)
Jae Hong Park
Woo Sik Um
Seung-Won Lee
Byung-Won Cho
Kwang Soo Yoo
A simplified preparation of overlithiated spinel phase LiMn2O4 and its electrochemical characterization	237	(6)
Zheng Zishan
Tang Zilong
Zhang Zhongtai
Sheng Wanci
Dong Jian
Capacity compensated substituted spinel LiMyMn2-yO4 with LiMyMn2-yO4-zFz (M=A1/Cr) for lithium secondary batteries	243	(6)
Xiaomei Wu
Qinghe Yang
Zhongkao Jin
Qingmei Song
Xiaohua Ma
Xiangfu Zong
Electrochemical performance of lithium-rich spinel Li1+xMn2O4 oxides at elevated temperature	249	(6)
Yanbin Chen
Yujuan Zhao
Cuiwei Du
Qingguo Liu
O2-type Li2/3(Ni1/3Mn2/3)O2 as cathode material for Li-ion batteries	255	(6)
K. M. Shaju
G. V. Subba Rao
B. V. R. Chowdari
Improved cycling performance of spinel LiMn2O4 by cation doping	261	(6)
Chuan Wu
Hong Li
Feng Wu
Xuejie Huang
Modification of spinel LiMn2O4 using an electrochemical method	267	(4)
Chuan Wu
Feng Wu
Xuejie Huang
Preparation of spinel-type LixMn2O4 cathode materials by melt-impregnation method for lithium-ion rechargeable batteries	271	(6)
Liu Xing-Quan
Chen Zhao-Yong
Li Qing
Yu Zuo-Long
Synthesis and electrochemical properties of doped LiMn2O4 system as cathode material for Li-ion batteries	277	(4)
Ye Shihai
Bin Xiaomin
Lin Dongfeng
Gao Xueping
Song Deying
Synthesis and performance of doped LiMxMn2-xAyO4-y spinel electrode materials	281	(6)
Z. R. Zhang
Z. T. Liu
Y. Yang
Z. G. Lin
Synthesis of doped LiMn2O4 by microwave-polymer process and lithium diffusion behaviour	287	(8)
Shu Ting Yang
Yan Feng Zhang
Qing Zhang Lu
Ming Chun Zhang
Li Ding
Template synthesis of nano-structured material for Li-ion batteries	295	(6)
J. Zhao
Q. Y. Gao
G. T. Wu
Y. Yang
Z. G. Lin
The structure and electrochemical performance of the spinel LiMn2O4, modified by using solid state reaction	301	(4)
Lu Shigang
Liu Renming
Sun Yucheng
Investigation of lithium cobalt nickel oxide as lithium ion battery cathode material prepared by a new citrate sol-gel method	305	(6)
Jingli Han
Qingguo Liu
Preparation of layered LiCoO2 by microwave-polymer network process and its electrochemistry performance investigation	311	(4)
S. T. Yang
Y. F. Zhang
J. H. Jia
Q. Z. Lu
M. C. Zhang
L. Di
Structural changes of Ni(OH)2 prepared from different nickel salt during charge/discharge process	315	(6)
Yang Shuting
Yin Yanhong
Lu Qingzhang
Zhang Mingchun
Ding Li
Structural properties and lithium insertion kinetics of layered oxides with Li1+xV3O8-related structure	321	(6)
A. K. Ivanov-Schitz
S. V. Pouchko
J. B. Schoonman
N. G. Chaban
Low-temperature synthesized Li1+XV3O8 as a cathode material for rechargeable lithium-ion batteries	327	(4)
Jianrui Liu
Meng Wang
Dachuan Yin
Weidong Huang
Preparation and electrochemical properties of Li-doped BaFeO4 as electrode material for lithium-ion batteries	331	(4)
Lin Dongfeng
Ye Shihai
Song Deying
Yuan Huatang
Shen Panwen
Yan Deyi
Gong Weilin
Flatband potentials and charge transfer at γ-MnO2/[Fe(CN)6]3-interface	335	(8)
Yuan Guo
Yong-Jun Li
Mao-Xia He
Xi Xia
Anode Materials
Nanosized alloy-based anode materials for Li-ion batteries (Invited)	343	(8)
Hong Li
Lihong Shi
Wei Lu
Xuejie Huang
Liquan Chen
Advanced anode systems based on tin-containing hosts and Li2.6Co0.4N for lithium-ion batteries	351	(6)
Y. Takeda
J. Yang
N. Imanishi
J. Y. Xie
O. Yamamoto
Electrochemical performance of nano-SnSb alloy deposited on carbon as anode active materials for Li ion batteries	357	(4)
Lihong Shi
Hong Li
Wei Lu
Xuejie Huang
Liquan Chen
Electrochemical performance of Ni-deposited graphite anodes for lithium secondary batteries	361	(4)
Lihong Shi
Qing Wang
Hong Li
Xuejie Huang
Liquan Chen
Structure and performance of epoxy resin cladded graphite used as anode	365	(6)
Zhou Zhentao
Li Haijun
Studies on intercalation/deintercalation mechanism of high polymer modified graphite anode for lithium ion battery	371	(6)
Yang Shuting
Liu Lijun
Lu Qingzhang
Raman spectral studies on solid state interphase in Li batteries	377	(8)
Hong Li
Guifeng Li
Yujun Mo
Xuejie Huang
Liquan Chen
Polymer Electrolytes
Polymer electrolytes based on modified natural rubber	385	(10)
M. D. Glasse
R. Idris
R. J. Latham
R. G. Linford
W. S. Schlindwein
Characteristics of composite polymer electrolytes based on poly(ethelyene oxide) and inorganic fiber	395	(6)
Z. Y. Wen
Z. X. Lin
J. D. Cao
T. Itoh
O. Yamamoto
Conductivity enhancement in the plasticized solid polymer electrolyte PEO:LiCF3SO3:EC by the addition of α-Al2O3	401	(6)
L. R. A. K. Bandara
M. A. K. L. Dissanayake
B. E. Mellander
Conductivity of anion polymer electrolyte	407	(4)
Xie Haifen
Li Guangyuan
Wang Rong
Conductivity studies on lithium perchlorate containing liquid and gel electrolytes	411	(6)
Narinder Arora
S. S. Sekhon
Electrical properties of PVDF-HFP microporous membrane for lithium ion battery	417	(4)
Xumei Ren
Hui Gu
Feng Wu
Xuejie Huang
Ion movement in poly-N-methylpyrrole films during redox processing	421	(6)
K. P. Vidanapathirana
M. A. Careem
Ionic conductivity of polymer electrolyte prepared in electrical field	427	(6)
Li Guangyuan
Ning Chaofeng
Jin Guozheng
Polymer ion conductivity and DSPP grain sizes	433	(4)
Wang Rong
Li Guangyuan
Cheng Jianhua
Xie Haifen
Methanol permeability and conductivity of alkali ion-doped Nafion membrane	437	(6)
Shi Meng
Qiu Xinping
Zhu Wentao
PMMA based gel electrolytes in mixed solvents for wider temperature range applications	443	(6)
S. S. Sekhon
Narinder Arora
Polymer-in-salt electrolytes based on PAN-LiTFSI	449	(6)
Jingze Li
Zhaoxiang Wang
Hong Li
Xuejie Huang
Liquan Chen
Preparation of microporous membranes for lithium ion battery	455	(6)
Xumei Ren
Hui Gu
Feng Wu
Xuejie Huang
Sodium ion conducting composite polymer electrolytes for battery applications	461	(6)
S. A. Hashmi
H. M. Upadhyaya
Awalendra K. Thakur
Study on redox shuttles used as overcharge protection additives for lithium ion rechargeable batteries	467	(4)
Yanyan
Zhou Zhentao
The compatibility of electrolyte with the electrodes in lithium ion batteries	471	(6)
Xu Zhongyu
Zheng Honghe
He Yuede
Han Shaochang
Cycling performance and interface properties of Li/PEO-LiX-ceramic filler/LiNi0.8Co0.2O2 cell	477	(6)
Li Qi
Y. Takeda
N. Imanishi
J. Yang
H. Y. Sun
O. Yamamoto
Preparation of PAN: EC: PC: LiTf polymer electrolytes and characterization of Li/PAN: EC: PC: LiTf/PPy: DBS cells	483	(6)
Kumudu Perera
M. A. K. L. Dissanayake
P. W. S. K. Bandaranayake
Determination of chemical diffusion coefficient of lithium ion in host materials and electrolyte simultaneously with potential relaxation technique	489	(4)
Qing Wang
Hong Li
Xuejie Huang
Liquan Chen
Agglomeration and surface passivating film Ag nano-brush electrode in lithium batteries	493	(8)
Xiaodong Wu
Hong Li
Xuejie Huang
Liquan Chen
[D] FUEL CELLS
Proton conductivity of tungsten trioxide hydrates at intermediate temperature (Invited)	501	(2)
T. Kudo
Y.-M. Li
Y. Tanaka
M. Hibino
Protonic conduction in ceramics of non-perovskite-type oxides at elevated temperatures (Invited)	503	(10)
Tetsuo Shimura
Hiroyasu Iwahara
Research and development of planar SOFC stack system (Invited)	513	(10)
T.-L. Wen
D. Wang
M. Chen
H. Y. Tu
Z. Lu
H. Nie
Z. Zhang
Effect of Nano-Al2O3 on the densification properties of normal pressure sintering and the conductivity of nano-ZrO2(4Y)	523	(6)
Yuan Wangzhi
Lao Linger
Tian Wei
Liu Yi
Wang Dazhi
Yao Kun
Wang Zheng
Phase characterization and electrical properties of LSM-LSGM system	529	(6)
Jae Yeon Yi
Gyeong Man Choi
Chemical reactivity of RE0.6Ca0.4Mn0.5Co0.5O3-δ (RE = La, Pr, Nd, Sm and Gd) and yttria stabilized zirconia	535	(6)
H. Y. Tu
J. H. Yang
Z. L. Zhan
Z. Y. Lu
D. Q. Wang
T. L. Wen
Intermediate temperature solid oxide fuel cells using ceria-based composite electrolytes	541	(6)
Fu Qingxi
Fan Xing
Peng Dingkun
Meng Guangyao
Novel ceramic fuel cells based on ceria-salt composite electrolyte	547	(6)
Zha Shaowu
Xia Changrong
Peng Dingkun
Meng Guangyao
Performance of solid oxide fuel cell using BaCe0.9Y0.1O3-α as a solid electrolyte	553	(6)
Ma Gui Lin
Jia Ding-Xian
Qiu Li-Gan
Study of proton conduction in yttrium-doped BaZrO3 at high temperature	559	(6)
Ibrahim Abu Talib
Mouloud Laidoudi
Ramli Omar
The conductivity of Pr-xMxGaO3 (M=Ca, Sr) persovskites	565	(6)
Liu Zhi-Guo
Huang Xi-Qiang
Lu Zhe
Liu Wei
Pei Li
Su Wen-Hui
Electronic conductivity of La0.9Sr0.1InO3-δ	571	(6)
Hongpeng He
Xuejie Huang
Liquan Chen
Sol-gel synthesis and properties of Sr-doped LaInO3 perovskite oxide	577	(6)
Hongpeng He
Xuejie Huang
Liquan Chen
Study on the manufacture technology of the zirconia tubes III. Research on the slip casting processes of the zirconia tubes	583	(6)
Suntai Qiu
Jiayin Xu
Changgui Shao
Study on TZP membranes as electrolytes in planar SOFCs	589	(6)
Ming Chen
Ting-Lian Wen
Zhi Yi Lu
Da Qian Wang
Fabrication of nano ZrO2(4Y) by fast sintering at ultra-high pressure	595	(6)
Yuan Wangzhi
Lao Linger
Wang Dazhi
Guo Jie
Tian Wei
Liu Yi
Influence of alumina addition on properties of YSZ membranes	601	(6)
Ming Chen
Ting-Lian Wen
Zhi-Yi Lu
Da-Qian Wang
Preparation of 8mo1% yttria stabilized zirconia powders by phase-transfer-separation process	607	(6)
Yao Weihua
Tang Zilong
Zhang Zhongtai
Zheng Zishan
Structure and electrical properties of Ce-doped Al2O3/8YSZ electrolyte	613	(6)
Ji Yuan
Liu Jiang
Liu Zhi-Guo
Lu Zhe
Pei Li
Su Wen-Hui
Impedance spectroscopy of alumina-zirconia eutectic composites	619	(6)
R. Cicka
V. Trnovcova
M. Starostin
Molecular dynamics study on vibrational properties of yttria stabilized zirconia	625	(6)
Takeo Tojo
Hitoshi Kawaji
Tooru Atake
Dehydration and crystallization of amorphous hydrous zirconia	631	(6)
Wang Dazhi
Xiu Xiangqian
Wang Zheng
Yao Kuen
Tan Honggao
Yuan Wangzhi
Lao Ling-er
Structure of zirconia precursor	637	(6)
Wang Dazhi
Xiangqian Xiu
Chunlin Song
Weng Huimin
Wang Zheng
Honggao Tang
Studying of positron-annihilation spectra on zirconia precursor	643	(6)
Song Chunlin
Wang Dazhi
Xiu Xiangqian
Tang Honggao
Weng Huimin
Zhang Xianfeng
Han Rongdian
Ye Bangjie
Wang Zheng
The influence of H2O to hydrogen permeation in CSZ at high temperatures	649	(8)
Y. Nigara
K. Yashiro
K. Kawada
J. Mizusaki
Thermodynamic evaluation of salt-alumina composites as electrolytes for fuel cells	657	(6)
Q. X. Fu
S. W. Tao
D. K. Peng
G. Y. Meng
Hydroxide-doped plastic crystal electrolytes based on pyrrolidinium imide salts	663	(6)
J. Sun
D. R. MacFarlane
M. Forsyth
Glycine-urea-nitrate combustion synthesis for γ-LiAlO2	669	(6)
M. M. Wu
Z. Y. Wen
Z. Z. Fan
Z. X. Lin
A new application of ZrO2 solid electrolyte	675	(8)
Fushen Li
Xionggang Lu
Xiaojun Hu
Lifen Li
K.-C. Chou
[E] SENSORS, ELECTROCHROMIC DISPLAYS & OTHER DEVICES
The progress in ion transport inorganic membranes (Invited)	683	(10)
Guangyao Meng
Chusheng Chen
Changrong Xia
Dingkun Peng
The antibacterial application of zirconium phosphate cation exchanger (Invited)	693	(10)
Yunfa Chen
Ziqiang Li
Yiben Yan
Yusheng Xie
The oxygen sensor made by PIM	703	(6)
Xianghua Kong
Xiaofeng Wang
Yi Luo
Qingguo Liu
Electrochemical sensors based on solid state ionic electrolyte	709	(6)
Chen Aifan
Du Junqi
Sun Kunpeng
Zhang Maihong
Yang Ming
Luo Ruixian
New family of the electrochemical cell for decomposition of NOx from exhaust gas	715	(6)
S. Bredikhin
M. Awano
K. Maeda
Electrochromic and surface effects in MoO3 thin films	721	(6)
Muhammad Yahaya
M. M. Salleh
Ibrahim A. Talib
Mursyidah
Fabrication and characterization of tungsten trioxide electrochromic films for emissivity modulation purposes	727	(6)
Yuzhi Zhang
Sulan Kuai
Yinsong Huang
Xingfang Hu
Study on electrochromic process and technology of WO3 films	733	(4)
Huang Shiyong
Qu Fengqin
Miao Ye
Xin Zhirong
Titanium dioxide films prepared by screen-printing technique for self-powered electrochromic windows	737	(6)
Muhamad Mat Salleh
Muhamad Yahaya
Mursyidah
Research on NiOx/KOH/C electrochemical capacitor	743	(6)
Wang Xiaofeng
Kong Xianghua
Liu Qingguo
Effects of Cl-and F- adsorption on methanol oxidation on polycrystalline platinum electrode	749	(6)
Liu Yicheng
Qiu Xinpin
Zhu Wentao
Author Index	755