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Summary

Supramolecular chemistry in inorganic hosts is treated in two parts in this Volume. The first part focuses on layered solids and their intercalation chemistry, the second on molecular sieves and zeolites. In the first part, after a preliminary chapter on typical behavior and general properties of two dimensional solids, the structural aspects and the chemistry of specific classes of layered solids, including graphite intercalation compounds, layered metal chalcogenides, phosphates, phosphonates, clays, layered double hydroxides and layered perovskites are treated. Attention is given to intercalation reactions and pillared solids with open porosity, including covalently pillared materials. Additional chapters deal with special topics such as film growth of layered materials, exfoliation reactions, photochemistry/electron transfer and ionic conductivity. In the second part, after discussing structural aspects of molecular sieves, the volume treats the multitude of synthetic strategies and current theories about hydrothermal synthesis mechanisms, followed by a discussion of molecular interactions with micropore hosts. Aspects of adsorption, molecular dynamics and diffusion are developed, and specific examples of inclusion chemistry are covered, including metal clusters in zeolites, and intrazeolite synthesis of organometallic complexes. The reactivity of molecules in micropore hosts, and relevant applications of molecular sieves are discussed in chapters on molecular shape selectivity in hydrocarbon catalysis, oxidation reactions, supramolecular photochemistry in zeolites, and novel materials such as sensors, membranes, and nonlinear optical effects in intrazeolite assemblies.

Layered Solids and their Intercalation Chemistry
Molecular Sieves: Inclusion Chemistry and Reactivity
Layered solids and their intercalation chemistry
Graphite intercalation compounds
Layered metal chalcogenides and their intercalates
Layered metal phosphates and their intercalation chemistry
Layered metal phosphonates and covalently pillared diphosphonates
Film growth in layered materials
Clays and pillared clays
Hydrotalcitelike anionic clays (layered double hydroxides)
Layered perovskites
Colloidal dispersion of compounds with layer and chain structures
Photochemistry and electron transfer in layered hosts
Ionic conductivity in layered materials
Molecular sieve zeolites: historical perspective
Structural aspects of molecular sieves
Synthesis of molecular sieves: a survey
Synthetic mechanisms and strategies for zeolite synthesis
Adsorption in porous materials
Molecular dynamics and diffusion in microporous materials
Metal clusters in zeolites
Inclusion chemistry in zeolites
Molecular shape selective conversion of hydrocarbons in zeolites
Oxidation catalysis with zeolites and related molecular sieves
Molecular sieves
Organic reactions in zeolites
Zeolites as supramolecular hosts for photochemical transformations
Novel materials based on zeolites
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