Spectroscopic Properties of Inorganic and Organometallic Compounds

by Yarwood, Jack; Belkova, Natalia (CON); Douthwaite, Richard; Dines, Trevor (CON); Duckett, Simon

• ISBN13: 9781849733953
• ISBN10: 1849733953
• Format: Hardcover
• Copyright: 2012-07-12
• Publisher: Royal Society of Chemistry

Summary

Spectroscopic Properties of Inorganic and Organometallic Compounds: Techniques, Materials and Applications provides a unique source of information in an important area of chemistry.

Table of Contents

Preface	p. v
IR spectroscopy of hydrides and its application to hydrogen bonding and proton transfer studies	p. 1
Introduction	p. 1
M-H stretching vibrations	p. 2
Hydrogen bonding and proton transfer	p. 11
Conclusions	p. 24
References	p. 25
Raman spectroscopy of graphene	p. 29
Introduction	p. 29
Graphene	p. 30
Raman spectroscopy	p. 34
Other spectroscopic techniques	p. 49
Conclusions	p. 52
Acknowledgments	p. 53
References	p. 53
Solid-state NMR: a key tool for the understanding at a molecular level of well-defined heterogeneous catalysts and surface chemistry on top of oxide materials	p. 57
ID NMR of spin 1/2 nuclei	p. 58
Chemical shift anisotropy for the molecular comprehension of the active sites (structure and dynamics)	p. 63
NMR of quadrupolar nuclei (spin > 1/2)	p. 65
Connectivity by multidimensional NMR	p. 69
Measuring J coupling constants and structural considerations	p. 73
Surface enhanced solid-state NMR spectroscopy	p. 75
Conclusions	p. 79
References	p. 79
Raman spectroscopy for solid oxide fuel cells	p. 84
Introduction and overview	p. 84
The solid oxide fuel cell	p. 85
Ex-situ characterisation studies	p. 87
In-situ characterisation studies	p. 108
Conclusion and outlook	p. 116
References	p. 116
Integrated analytical techniques for analysing individual environmental particles	p. 123
Introduction	p. 123
First era: CCSEM/EDX or EPXMA for SPA	p. 125
Second era: low-Z and beam sensitive particles	p. 128
Third era: the addition of complementary techniques	p. 130
Expectations and challenges for the future	p. 136
References	p. 138
Materials sciences using synchrotron infrared light sources	p. 141
Introduction	p. 141
Synchrotron infrared sources	p. 142
Synchrotron IR opportunities in polymer science	p. 143
Synchrotron IR studies in catalysis	p. 148
Synchrotron IR studies in extreme conditions	p. 152
Synchrotron IR ellipsometry	p. 155
Novel condensed matter compounds	p. 157
Some future directions	p. 159
Conclusions	p. 162
References	p. 162
Metal-based molecular switches generated from dithienyl ethene (DTE)	p. 166
Introduction	p. 166
Pendant Pt(II) acetylides	p. 188
Alternative metal acetylides (Au(I), Ru(II), CpFe)	p. 195
Coordinating acac-derived metal complexes	p. 200
Future directions	p. 204
References	p. 214
Nuclear quadrupole resonance spectroscopy	p. 216
Introduction	p. 216
Main group elements	p. 216
Transition metals	p. 223
References	p. 226
Simulation of spectroscopic properties of inorganic compounds	p. 229
Introduction	p. 229
Main groups	p. 232
Transition metals	p. 235
Lanthanides and actinides	p. 247
Summary and future directions	p. 249
References	p. 249
Combined time-resolved X-ray scattering and spectroscopy methods	p. 257
Introduction	p. 257
Synchrotron radiation	p. 258
X-ray scattering	p. 260
X-ray spectroscopy	p. 265
Technique combinations experimental issues	p. 270
Technique combinations examples	p. 275
Conclusions	p. 284
Acknowledgements	p. 284
References	p. 285
Solid state NMR of immobilized catalysts and nanocatalysts	p. 289
Introduction	p. 289
Solid state NMR spectroscopy	p. 293
Applications to immobilized catalysts	p. 296
Characterization of reaction intermediates in heterogeneous catalysis by solid state NMR	p. 307
Outlook and perspectives	p. 308
Conclusions	p. 312
Appendix	p. 312
Acknowledgments	p. 315
References	p. 315
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