Synthesis and Properties of Silicones and Silicone-Modified Materials

by Clarson, Stephen J.; Fitzgerald, John J.; Owen, Michael J.; Smith, Steven D.; Van Dyke, Mark E.

• ISBN13: 9780841238046
• ISBN10: 0841238049
• Format: Hardcover
• Copyright: 2003-03-27
• Publisher: American Chemical Society

Summary

Synthesis and Properties of Silicones and Silicone-Modified Materials includes sections on synthesis, characterization, elastomers and reinforcement, surfaces and interfaces, copolymers, and reinforcing fillers. Synthesis and Properties of Silicones and Silicone-Modified Materials reviewsrecent academic and technological developments behind silicones and silicone-modified materials. Synthesis and Properties of Silicones and Silicone-Modified Materials includes sections on synthesis, characterization, elastomers and reinforcement, surfaces and interfaces, copolymers, and reinforcingfillers. Synthesis and Properties of Silicones and Silicone-Modified Materials reviews recent academic and technological developments behind silicones and silicone-modified materials.

Table of Contents

Preface	xvii
1. Silicones and Silicone-Modified Materials: A Concise Overview:	1	(11)
Stephen J. Clarson
Synthesis
2. Controlled Synthesis of All Siloxane-Functionalized Architectures by Ring-Opening Polymerization	12	(14)
J. Chojnowski, M. Cypryk, W. Fortuniak, K. Kazmierski, K. R=zga-Wijas, and M. Scibiorek
3. Novel Methods of Catalyzing Polysiloxane Syntheses	26	(14)
C. J. Embery, J. G. Matisons, and S. R. Clarke
4. Anionic Ring-Opening Polymerization of cis-2,4,6-Trimethyl 2',4',6'-triphenyl Cyclotrisiloxane (cis-P3) in Cyclohexane	40	(10)
H. W. Ahn and S. J. Clarson
5. Ru-Catalyzed Hydrosilylation Polymerization: An Overview of RuH2(CO)(PPh3)3-Catalyzed Hydrosilylation Copolymerizations of a,w-Diketones with a,w-Dihydrido-oligo-dimethylsiloxanes and Polymerizations of w-Dimethylsilyloxy Ketones	50	(11)
Joseph M. Mabry, Matthew K. Runyon, Jyri K. Paulasaari, and William P. Weber
6. Synthesis and Characterization of Siloxane-Containing Polymers Obtained by Dehydrocoupling Polymerization	61	(11)
Yusuke Kawakami and Ichiro Imae
7. Synthesis of Linear Copolysiloxanes with Regular Microstructures and Synthesis of Soluble Polysiloxanes with Trifunctional RSiO3/2 (T) or Tetrafunctional Si04/2 (Q) Units	72	(7)
William P. Weber, Jyri Kalevi Paulasaari, and Guoping Cai
8. Polysiloxanes in Compressed Carbon Dioxide	79	(17)
Sarah L. Folk and Joseph M. DeSimone
Characterization
9. Neutron Scattering Studies of Cyclic and Linear Poly(dimethylsiloxanes)	96	(9)
A. C. Dagger, V. Arrighi, S. Gagliardi, M. J. Shenton, S. J. Clarson, and J. A. Semlyen
10. Photoexcitation and Photoemission Spectra of Phenyl Substituted Cyclosiloxanes	105	(12)
Michael W. Backer, and Udo C. Pernisz
11. Measuring the Size and Shape of Silicones: The Utilization of Chemometrics and Spectroscopy	117	(10)
Martyn J. Shenton, Henryk Herman, and Anthony C. Dagger
12. Thermally Stable Siloxane Polymers for Gas Chromatography	127	(11)
G. M. Day, A. I. Hibberd, J. Habsuda, and G. J. Sharp
Elastomers and Reinforcement
13. The Effect of Thermal Aging on the Non-Network Species in Room Temperature Vulcanized Polysiloxane Rubbers	138	(13)
Mogon Patel and Anthony R. Skinner
14. Prediction of the Elastomeric Modulus of Poly(dimethylsiloxane) Networks Formed by Endlinking	151	(12)
R. F. T. Stepto, J. I. Cail, and D. J. R. Taylor
15. Structure-Property Relationships for Poly(dimethylsiloxane) Networks In Situ Filled Using Titanium 2-Ethylhexoxide and Zirconium n-Butoxide	163	(7)
S. Murugesan, J. E. Mark, and G. Beaucage
16. Modulus Reduction Mechanism of Trimethylsiloxy Silicates in a Polyorganosiloxane	170	(11)
Randall G. Schmidt, Linda R. Badour, and Glenn V. Gordon
17. NMR Spin Relaxation, Self-Diffusion and Viscosity Studies of Poly(dimethylsiloxane)s Blended with Silicate Nanoparticles	181	(15)
Claire Roberts, Terence Cosgrove, Randall G. Schmidt,Glenn V. Gordon, Andrew J. Goodwin, and Axel Kretschmer
Surfaces and Interfaces
18. Investigating the Energetics of Bioadhesion on Microengineered Siloxane Elastomers: Characterizing the Topography, Mechanical Properties, and Surface Energy and Their Effect on Cell Contact Guidance	196	(16)
Adam W. Feinberg, Amy L. Gibson, Wade R. Wilkerson,Charles A. Seegert, Leslie H. Wilson, Lee C. Zhao,Ronald H. Baney, James A. Callow, Maureen E. Callow,and Anthony B. Brennan
19. Exploiting Favorable Silicone-Protein Interactions: Stabilization against Denaturation at Oil-Water Interfaces	212	(10)
Paul M. Zelisko, Vasiliki Bartzoka, and Michael A. Brook
20. Association of Siloxane Polymeric Surfactants in Aqueous Solution	222	(14)
Yining Lin and Paschalis Alexandridis
Copolymers
21. Poly(amidoamine organosilicon) Dendrimers and Their Derivatives of Higher Degree of Structural Complexity	236	(24)
Petar R. Dvornic and Michael J. Owen
22. Surfactant Properties of Poly(dimethylsiloxane)-Containing Block Copolymers from Living Radical Polymerization	260	(13)
Laurence Bes, Kim Huan, David M. Haddleton, and Ezat Khoshdel
23. Organic-Inorganic Hybrid Materials from Polysiloxanes and Polysilsesquioxanes Using Controlled/Living Radical Polymerization	273	(12)
Jeffrey Pyun, Jianhui Xia, and Krzysztof Matyjaszewski
24. Preparation and Properties of Silicone-Urea Copolymers Doped with Cobalt(II) Chloride	285	(11)
E. Yilg÷r, M. G÷rdeslioglu, B. Dizman, and I. Yilg÷r
25. Block and Graft Copolymers Containing Poly(dimethylsiloxane) and Poly(4-vinyl-pyridine) Segments by Free Radical Polymerization	296	(10)
Yongsin Kim, Daniel Graiver, Gary T. Decker,Fernando J. Hamilton, and H. James Harwood
26. Poly(dimethylsiloxane)graft-oligo(hexafluoropropeneoxide) Via Ring-Opening Polymerization	306	(12)
Mark A. Buese, Jose F. Gonzalez, Curtis G. Harbaugh, Garrett M. Stearman, and Michael S. Williams
27. Silicone Graft Copolymers with Acrylonitrile, Chloroprene, Styrene, Methylmethacrylate, and an Olefin	318	(11)
Allan H. Fawcett, Andrew B. Foster, Majid Hania,Marcia Hohn, Judge L. Mazebedi, Gerry O. McCaffery,Eddie Mullen, and Declan Toner
28. Synthesis and Properties of Poly(butylene terephthalate) Poly (dimethylsiloxane) Block Copolymers	329	(12)
David A. Schiraldi
29. The Synthesis of Vinyloxyacetate-Siloxane Copolymer and Its Absorption onto E Glass Fibers	341	(25)
Rosalind P. Ma, Christopher Le-Huy, Leanne G. Britcher, and Janis G. Matisons
Reinforcing Fillers
30. Silicification and Biosilicification: Part 2. Silicification at pH 7 in the Presence of a Cationically Charged Polymer in Solution and Immobilized on Substrates	366	(9)
Siddharth V. Patwardhan, Michael F. Durstock,and Stephen J. Clarson
31. Diffusion-Controlled Titanate-Catalyzed Condensation of Alkoxysilanes in Nonpolar Solvents	375	(14)
Xiaobing Zhou, Sanlin Hu, Nick E. Shephard,and Dongchan Ahn
Author Index	389	(2)
Subject Index	391