Thermodynamics

by Fermi, Enrico

• ISBN13: 9780486603612
• ISBN10: 048660361X
• Format: Paperback
• Copyright: 1956-06-01
• Publisher: Dover Publications

Summary

In this classic of modern science, the Nobel Laureate presents a clear treatment of systems, the First and Second Laws of Thermodynamics, entropy, thermodynamic potentials, and much more. Calculus required.

Author Biography

Enrico Fermi: Father of the Atomic Age
Enrico Fermi (1901–1954) received the 1938 Nobel Prize in Physics "for his demonstrations of new radioactive elements produced by neutron irradiation, and for his related discovery of nuclear reactions brought about by slow neutrons." Just a year before winning the Nobel Prize, Fermi published Thermodynamics, based on a course of lectures at Columbia University, an enduring work which Dover first reprinted in 1956 and which has been in print continuously since then, one of the foundations of Dover's physics program.

Both a theorist and an experimentalist, Fermi packed an immense amount of science into his relatively short life, which ended prematurely as a consequence of the radiation he received working on the development of the atomic bomb. His work, of course, was not just in the realm of nuclear physics: Fermi will always be the most remembered for the events of December 2, 1942, when he and other scientists at the University of Chicago's Stagg Field produced the world's "first self-sustaining chain reaction . . . instituting the controlled release of atomic energy."

In the Author's Own Words:
"There are two possible outcomes: If the result confirms the hypothesis, then you've made a measurement. If the result is contrary to the hypothesis, then you've made a discovery." — Enrico Fermi

Critical Acclaim for Enrico Fermi:
"He was simply unable to let things be foggy. Since they always are, this kept him pretty active." — J. Robert Oppenheimer

Table of Contents

PREFACE
INTRODUCTION
CHAPTER
I. THERMODYNAMIC SYSTEMS
  1. The state of a system and its transformations
  2. Ideal or perfect gases
II. THE FIRST LAW OF THERMODYNAMICS
  3. The statement of the first law of thermodynamics
  4. "The application of the first law to systems whose states can be represented on a (V, p) diagram"
  5. The application of the first law to gases
  6. Adiabatic transformations of a gas
III. THE SECOND LAW OF THERMODYNAMICS
  7. The statement of the second law of thermodynamics
  8. The Carnot cycle
  9. The absolute thermodynamic temperature
  10. Thermal engines
IV. THE ENTROPY
  11. Some properties of cycles
  12. The entropy
  13. Some further properties of the entropy
  14. "The entropy of a system whose states can be represented on a (V, p) diagram"
  15. The Clapeyron equation
  16. The Van der Waals equation
V. THERMODYNAMIC POTENTIALS
  17. The free energy
  18. The thermodynamic potential at constant pressure
  19. The phase rule
  20. Thermodynamics of the reversible electric cells
VI. GASEOUS REACTIONS
  21. Chemical equilibria in gases
  22. The Van't Hoff reaction box
  23. Another proof of the equation of gaseous equilibria
  24. Discussion of gaseous equilibria; the principle of Le Chatelier
VII. THE THERMODYNAMICS OF DILUTE SOLUTIONS
  25. Dilute solutions
  26. Osmotic pressure
  27. Chemical equilibria in solutions
  28. The distribution of a solute between two phases
  29. "The vapor pressure, the boiling point, and the freezing point of a solution"
VIII. THE ENTROPY CONSTANT
  30. The Nernst theorem
  31. Nernst's theorem applied to solids
  32. The entropy constant of gases
  33. Thermal ionization of a gas; the thermionic effect
INDEX