Preface | |
Introduction | |
Basic Calculations | |
Introduction | |
Units and Dimensions | |
Conversion of Units | |
The Gravitational Constant, gc | |
Significant Figures and Scientific Notation | |
References | |
Process Variables | |
Introduction | |
Temperature | |
Pressure | |
Moles and Molecular Weights | |
Mass and Volume | |
Viscosity | |
Heat Capacity | |
Thermal Conductivity | |
Reynolds Number | |
pH | |
Vapor Pressure | |
Property Estimation | |
References | |
Gas Laws | |
Introduction | |
Boyle's and Charles' Laws | |
The Ideal Gas Law | |
Standard Conditions | |
Partial Pressure and Partial Volume | |
Critical and Reduced Properties | |
Non-Ideal Gas Behavior | |
Non-Ideal Mixtures | |
References | |
Conservation Laws | |
Introduction | |
The Conservation Laws | |
The Conservation Law for Momentum | |
The Conservation Law for Mass | |
The Conservation Law for Energy | |
References | |
Stoichiometry | |
Introduction | |
Combustion of Methane | |
Excess and Limiting Reactant(s) | |
Combustion of Ethane | |
Combustion of Chlorobenzene | |
References | |
The Second Law of Thermodynamics | |
Introduction | |
Qualitative Review of the Second Law | |
Quantitative Review of the Second Law | |
Ideal Work and Lost Work | |
The Heat Exchanger Dilemma | |
Chemical Plant and Process Applications | |
The Third Law of Thermodynamics | |
References | |
Enthalpy Effects | |
Sensible Enthalpy Effects | |
Introduction | |
The Gibbs Phase Rule (GPR) | |
Enthalpy Values | |
Heat Capacity Values | |
Predictive Methods for Heat Capacity | |
References | |
Latent Enthalpy Effects | |
Introduction | |
The Clausius-Clapeyron (C-C) Equation | |
Predictive Methods: Normal Boiling Point | |
Predictive Methods: Other Temperatures | |
Industrial Applications | |
References | |
Enthalpy of Mixing Effects | |
Introduction | |
Enthalpy-Concentration Diagrams | |
H2SO4-H2O Diagram | |
NaOH-H2O Diagram | |
Enthalpy of Mixing at Infinite Dilution | |
Evaporator Design | |
References | |
Chemical Reaction Enthalpy Effects | |
Introduction | |
Standard Enthalpy of Formation | |
Standard Enthalpy of Reaction | |
Effect of Temperature on Enthalpy of Reaction | |
Gross and Net Heating Values | |
References | |
Equilibrium Thermodynamics | |
Phase Equilibrium Principles | |
Introduction | |
Psychometric Chart | |
Raoult's Law | |
Henry's Law | |
Raoult's Law vs Henry's Law | |
Vapor-Solid Equilibrium | |
Liquid-Solid Equilibrium | |
References | |
Vapor-Liquid Equilibrium Calculations | |
Introduction | |
The DePriester Charts | |
Raoult's Law Diagrams | |
Vapor-Liquid Equilibrium in Nonideal Solutions | |
NRTL Diagrams | |
Wilson Diagrams | |
Relative Volatility | |
References | |
Chemical Reaction Equilibrium Principles | |
Introduction | |
Standard Free Energy of Formation, DG0f | |
Standard Free Energy of Reaction, DG0 | |
The Chemical Reaction Equilibrium Constant, K | |
Effect of Temperature on DG0 and K: Simplified Approach | |
Effect of Temperature on DG0 and K: a, b, and g Data | |
Effect of Temperature on DG0 and K: a, b, and c Data | |
Procedures to Determine K | |
References | |
Chemical Reaction Equilibrium Applications | |
Introduction | |
Rate vs Equilibrium Considerations | |
Extent of Reaction | |
The Reaction Coordinate | |
Gas Phase Reactions | |
Equilibrium Conversion Calculations: Simplified Approach | |
Equilibrium Conversion Calculations: Rigorous Approach | |
Other Reactions | |
References | |
Other Topics | |
Economic Considerations | |
Introduction | |
Capital Costs | |
Operating Costs | |
Project Evaluation | |
Perturbation Studies in Optimization | |
References | |
Open-Ended Problems | |
Introduction | |
Developing Students' Power of Critical Thinking | |
Creativity | |
Brainstorming | |
Inquiring Minds | |
References | |
Other ABET Topics | |
Introduction | |
Environmental Management | |
Health, Safety, and Accident Management | |
Numerical Methods | |
Ethics | |
References | |
Fuel Options | |
Introduction | |
Fuel Properties | |
Natural Gas | |
Liquid Fuels | |
Coal | |
Fuel Selection | |
Stoichiometric Calculations | |
References | |
Exergy: The Concept of "Quality Energy" | |
Introduction | |
The Quality of Heat vs Work | |
Exergy | |
Quantitative Exergy Analysis | |
Environmental Impact | |
Exergy Efficiency | |
References | |
Appendix | |
Steam Tables | |
Saturated Steam | |
Superheated Steam | |
Saturated Steam-Ice | |
SI Units | |
Conversion Constants | |
Selected Common Abbreviations | |
References | |
Index | |
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