Transition Metal Catalysis in Macromolecular Design

by Boffa, Lisa Saunders; Novak, Bruce M.

• ISBN13: 9780841236738
• ISBN10: 0841236739
• Format: Hardcover
• Copyright: 2000-07-20
• Publisher: American Chemical Society
• More Book Details
• Purchase Benefits

Summary

Metal-mediated polymerization is fast becoming an essential tool for the fine control of macromolecular architecture. Advanced Catalysis demonstrates how the field of transition metal-catalyzed polymer syntheses has moved beyond the simple use of single-site catalysts to new applications and "advanced" techniques of architectural control. This book defines and presents "next generation" techniques and trends for polymer architecture control for an immediate grasp on the future of this exciting field.

Table of Contents

Preface	ix
The Organometallic Polymerization of (Meth)acrylates: An Overview	1	(23)
Lisa Saunders Boffa
New Chain-Building Mechanisms
New Applications of ``Carbonylbis(triphenylphosphine)ruthenium'' Catalysis in Polymer Synthesis	24	(14)
William P. Weber
Jyri K. Paulasaari
Diyun Huang
Shashi Gupta
Timothy M. Londergan
Jonathan R. Sargent
Joseph M. Marbry
Transition Metal-Catalyzed Alkyne Cycloaddition Polymerization	38	(21)
Tetsuo Tsuda
Synthetic Control over Substituent Location on Carbon-Chain Polymers Using Ring-Opening Polymerization of Small Cycloalkanes	59	(18)
J. Penelle
Nucleophilic Polymerization of Methyl Methacrylate Activated by a Bronsted Acid	77	(17)
Masatoshi Miyamoto
Hirotomo Katano
Chika Kanda
Yoshiharu Kimura
Polymer Modification Using Transition Metals
Modification of Polybutadiene by Transition Metal Catalysts: Hydroacylation of Polybutadiene	94	(14)
Chul-Ho Jun
Hyuk Lee
Jun-Bae Hong
Dae-Yon Lee
Metallocene Catalysts Used for the Hydrogenation of Polystyrene-b-Polybutadiene-b-Polystyrene Block Copolymers	108	(19)
Raymond Chien-chao Tsiang
Wen-shen Yang
Ming-der Tsai
E-Glass Fiber Supported Hydrosilation Catalysts	127	(19)
L. G. Britcher
J. G. Matisons
Olefin/Alkyne Addition Polymerization
New Catalysts for Polymerizations of Substituted Acetylenes	146	(19)
Ben Zhong Tang
Kaitian Xu
Qunhui Sun
Priscilla P. S. Lee
Han Peng
Fouad Salhi
Yuping Dong
Addition Polymerization of Norbornene: Catalysis of Monocyclopentadienyltitanium Compounds Activated with Methylaluminoxane	165	(9)
Qing Wu
Yingying Lu
Zejian Lu
Transfer and Isomerization Reactions in Propylene Polymerization with the Isospecific, Highly Regiospecific rac-Me2C(3-t-Bu-1-Ind)2ZrCl2/MAO Catalyst	174	(22)
Isabella Camurati
Anna Fait
Fabrizio Piemontesi
Luigi Resconi
Stefano Tartarini
Controlled Radical Polymerization
Living Radical Polymerization of Acrylates with Rhenium(V)-Based Initiating Systems: ReO2I(PPh3)2/Alkyl Iodide	196	(11)
Hiroko Uegaki
Yuzo Kotani
Masami Kamigaito
Mitsuo Sawamoto
The Effect of Ligands on Copper-Mediated Atom Transfer Radical Polymerization	207	(17)
Jianhui Xia
Xuan Zhang
Krysztof Matyjaszewski
Structural Chemistry and Polymerization Activity of Copper(I) Atom Transfer Radical Polymerization Catalysts	224	(12)
Amy T. Levy
Timothy E. Patten
Atom Transfer Polymerization Mediated by Solid-Supported Catalysts	236	(18)
David M. Haddleton
Arnaud Radigue
Dax Kukulj
David J. Duncalf
Mechanistic Aspects of Catalytic Chain Transfer Polymerization	254	(21)
John P. A. Heuts
Darren J. Forster
Thomas P. Davis
Indexes
Author Index	275	(1)
Subject Index	276