Vibronic Interactions

by Kaplan, Michael D.; Zimmerman, George O.

• ISBN13: 9781402000447
• ISBN10: 1402000448
• Format: Hardcover
• Copyright: 2002-01-01
• Publisher: Kluwer Academic Pub

Summary

The Jahn-Teller effect is manifested in a variety of phenomena in physics, chemistry and biochemistry, in many types of crystals and molecules. This book deals with fundamental questions of the quantum mechanics of systems with orbital electrons, concentrating on novel phenomena and materials such as colossal magnetoresistance, high Tc superconductivity, buckminsterfullerenes, magnetic materials and biologically important clusters. All chapters share a common general approach to the problems, based on the analysis of vibronic interaction: electron-vibrational interaction in molecules and electron-phonon interaction in crystals. With an introductory address by Edward Teller.

Table of Contents

Preface	xi
Professor Edward Teller's Address to the Meeting Participants	1	(4)
Teller, E.
The Jahn-Teller Effect: A permanent presence in the frontiers of science	5	(10)
Englman, R.
Yahalom, A
Orbital Ordering and Vibronic States in Manganese Perovskites	15	(8)
Zhou, J.-S.
Goodenough, J. B.
Sum Rules for Jahn-Teller Reduction Factors	23	(8)
Bates, C. A.
Dunn, J.L.
Oliete, P. B.
Stedman, G. E.
Chemistry of Vibronic Coupling	31	(16)
Grochala, W.
Hoffmann, R.
Field-Induced Crossover and Colossal Magnetoresistance in La0.7Pb0.3MnO3	47	(10)
Chu, C.W.
Xue, Y.Y.
Lorenz, B.
Heilman, A. K.
Gospodinov, M.
Dobreva, S.G.
Jahn-Teller Effect and Doping in Manganites	57	(16)
Dzero, M.
Gor'kov, L.
Kresin, V.
Degenerate and Nondegenerate States in John-Teller Problems	73	(10)
Bersuker, I.B.
DFT Calculations of the ``Lone-Pair'' Effect - A Tool for the Chemist to Predict Molecular Distortions?	83	(14)
Reinen, D.
Atanasov, M.
The {E⊗E}⊗e Vibronic Coupling Case: A Prototypal Product Jahn-Teller System	97	(6)
Qiu, Q.C.
Ceulemans, A.
Exchange Variation of Zero-Field Splitting in Polynuclear Clusters with High-Spin Ground State	103	(8)
Belinsky, M.J.
Double Exchange in Orbitally Degenerate Mixed Valence Clusters: Magnetic Anisotropy, Vibronic Effects	111	(12)
Borras-Almenar, J.J.
Clemente-Juan, J.M.
Coronado, E.
Mirovitskii, V. Yu.
Palii, A.V.
Tsukerblat, B.S.
Singlet Pairing Amongst Degenerate Electronic States: ``Softening Bipolarons''	123	(10)
Emin, D.
Giant Negative Magnetoresistance and Strong Electron-Lattice Coupling in Amorphous Semiconductors with Magnetic Impurities	133	(8)
Bratkovsky, A.M.
Jahn-Teller Effect in Transition Metal Oxides	141	(12)
Louca, D.
Magnetoelastic Properties of Jahn-Teller Crystals with Colossal Magnetoresistance	153	(12)
Kaplan, M.D.
Vekhter, B.
Zimmerman, G.O.
Vibronic Effects in Spectroscopy of Heme Proteins	165	(8)
Stavrov, S.S.
Jahn-Teller Clusters in Dielectrics and cuprates	173	(10)
Yablokov, Yu. V.
Miscibility in Jahn-Teller Systems	183	(14)
Fishman, A. Ya.
Ivanov, M.A.
Tkachev, N.K.
Jahn-Teller Levels of Defects in AIVBVI Semiconductors Doped by High Dose Ion Implantation	197	(8)
Dashevsky, Z.
Chaikovsky, I.
The Dynamic Jahn-Teller Effect in High-Tc Superconductors and Water Buckyballs	205	(4)
Johnson, K.
X-ray Scattering Studies of Correlated Polarons in La0.7Ca0.3MnO3	209	(6)
Nelson, C.S.
Zimmermann, M.V.
Hill, J.P.
Gibbs, D.
Kiryukhin, V.
Koo, T.Y.
Cheong, S-W.
Dopant Induced Enhancement of the Jahn-Teller Effect in Perovskite Cuprates	215	(6)
Polinger, V.
Haskel, D.
Stern, A.E.
EPR Study of Cu2+ Doped (CnH2n+1NH3)2CdCl4 Crystals (n = 1;3) with Layer Structure	221	(8)
Valiente, R.
Rodriguez, F.
Moreno, M.
Lezama, L.
Nondegenerate Ground Vibronic States in the Linear T⊗ (e+t2) Jahn-Teller Problem	229	(6)
Bevilacqua, G.
Bersuker, I.B.
Martinelli, L.
Vibronic Model of Double Triangular Mixed-Valence Clusters with Spin Frustration Effects	235	(8)
Fainzilberg, V.E.
Jahn-Teller Effect in Corannulene Anion	243	(4)
Sato, T.
Yamamoto, A.
Tanaka, H.
Franck-Condon Approximation for Second Order Reduction Factors: Application to Vibronic Reduction in Fullerenes	247	(4)
Abou-Ghantous, M.
Dunn, J.L.
Polinger, V. Z.
Bates, C.A.
Symmetries of Jahn-Teller States in Charged Fullerenes	251	(12)
Wang, C.-L.
Yi, Y.-A.
Tian, L.
Su, Z-B.
Quantum-Chemical Approach to Zero-Dimensional Anti-Ferroelectrics and Quantum Paraelectrics of the K3H(SO4)2 Family	263	(6)
Dolin. S.P.
Levin, A.A.
Mikhailova, T.Yu.
Solin, M.V.
Influence of Jahn-Teller lons on Spin-Lattice Relaxation in Ferrimagnets	269	(4)
Dionne, G.F.
Berryonic Matter in the Cuprates	273	(4)
Markiewicz, R.S.
Microscopic Mechanism of Stripe Pairing Phase Formation	277	(8)
Kaplan, M.D.
Zimmerman, G.O.
Vibronic Coupling in Fullerene Systems: An Analysis of Theoretical and Experimental Studies	285	(6)
Hands, I.D.
Dunn, J.L.
Bates, C.A.
EPR and x-ray Studies of the Vibronic Effects in Cs2Cu(ZrF6)2.6(H2O) Crystal	291	(4)
Augustyniak-Jablokow, M.A.
Yablokov, Yu. V.
Lukaszewicz, K.
Pietraszko, P.E.
Tomaszewski, P.E.
Petrashen, V.E.
The Dynamics of the Jahn-Teller Oxides	295	(6)
Chernishov, V.A.
Nikiforov, A.E.
Popov, S.E.
Zaharov, A.Yu.
Molecular Mechanisms of Proton Ordering and Formation of Ferroelectric Properties in Systems with 3D, 2D and 0D H-bond Networks	301	(6)
Levin, A.A.
Dolin, S.P.
Kirilova, N.I.
The Crucial Role of Jahn-Teller Effect in the Formation of Orbital and Magnetic Structures of Charge Ordered Manganite R0.5A0.5MnO3	307	(6)
Gontchar, L.E.
Nikiforov, A.E.
Popov, S.E.
Ferroelectric Phase Transitions in a Lattice Pseudo-Jahn-Teller Model	313	(4)
Clougherty, D.P.
Jahn-Teller Polarons in Lightly Doped La1-xSrxMnO3 as Studied by EPR	317	(6)
Ivanshin, V.A.
Eremin, M.V.
Krug van Nidda, H.A.
Deisenhofer, J.
Loidl, A.
Cubic Ni3+ Centres in LaSrAl1-xNixO4±δ	323	(6)
Ivanova, T.A.
Jacyna-Onyszkiewicz, I.
Mrozinski, J.
Yablokov, Yu. V.
Zelentsov, V.V.
Physical Mechanism of the Crossover of Ground State Energy Levels in Linear H⊗h Systems	329	(6)
Polinger, V.
Huang, R.
Bates, C.A.
Dunn, J.L.
Jahn-Teller and A1g Vibrations for Mn2+ Doped Fluoroperovskites:Stokes Shift	335	(8)
Barriuso, M.T.
Moreno, M.
Aramburu, J.A.
Anharmonic Gap Modes in Alkali Halides	343	(6)
Nevedrov, D.
Hizhnyakov, V.
Sievers, A.J.
Free and Spin-Polaron States in Hight Tc Superconductors	349	(8)
Shelkan, A.
Hizhnyakov, V.
Seibold, G.
Sigmund, E.
Formation of the Jahn-Teller Glassy State in the Mixed Potassium-Ammonium Tuton Salts	357	(6)
Augustyniak-Jablokow, M.A.
Role of Jahn-Teller Coupling in G-Values in C60-	363	(4)
Anderson, F.G.
Fine Interactions and the Jahn-Teller Effect in Luminescence of Fe2+ in II-VI Compounds	367	(10)
Bevilacqua, G.
Martinelli, L.
Russo, G.
Pastori Parravicini, G.
Mualin, O.
Vogel, E.E.
de Orue, M.A.
Rivera-Iratchet, J.
Index	377	(4)
List of Contributions	381