Zeolite Synthesis

by Occelli, Mario L.; Robson, Harry E.

• ISBN13: 9780841216327
• ISBN10: 0841216320
• Format: Hardcover
• Copyright: 1989-07-01
• Publisher: American Chemical Society

Summary

This volume is a complete progress report on the various aspects of zeolite synthesis on a molecular level. It provides many examples that illustrate how zeolites can be crystallized and what the important parameters are that control crystallization. Forty-two chapters cover such topics as: crystallization techniques; gel chemistry; crystal size and morphology; the role of organic compounds; and novel synthesis procedures. It offers a complete review of zeolite synthesis as well as the latest finding in this important field. Contains benchmark contributions from many notable pioneers in the field, including R.M. Barrer, H. Robson, and Robert Milton.

Table of Contents

Molecular Sieve Science and Technology: A Historical Perspective

Zeolites Their Nucleation and Growth Precursors in Zeolite Synthesis

A Critical Review Structure and Properties of Aluminosilicate

Solutions and Gels Applications of NMR Spectroscopy to the Study of Zeolite

Synthesis Observed and Calculated Silicate and Aluminosilicate

Oligomer Concentrations in Alkaline Aqueous

Solutions Influence of D20 and Alcohols on the Crystallization of Zeolites

Influence of Autocatalytic Nucleation on Zeolite

Crystallization Processes Role of Gel Aging in Zeolite

Crystallization Silicate Species with Cagelike Structure in Solutions and Rapid Solidification with Organic

Quaternary Ammonium Ions Role of the Tetramethylammonium Cation in the Synthesis of Zeolites ZK-4, Y, and HS Stabilizing

Role of Linear Polyamines as Pore Fillers During the Crystallization of Zeolite NU-10 Zeolite

Synthesis in the Presence of Fluoride Ions: A Comparison with Conventional

Synthesis Methods Cancrinite Crystallization from Alkaline Aluminosilicate

Systems Containing Large and Small Cations Nonaqueous

Synthesis of Silica Sodalite Contribution of Propylammonium

Species to the Stabilization of the MFI-Type Structure

Effect of Gravity on Silicalite Crystallization

Crystallization of Pentasil Zeolite in the Absence of Organic

Templates Crystal Growth Regulation and Morphology of Zeolite

Single Crystals of the MFI Type Synthesis of Pentasil Zeolites With and Without Organic

Templates Synthesis of VPI-5

Synthesis of Microphorous Silicaluminophosphates in Hexanol-Water Biphasic

Systems Synthesis and Characterization of Metal Aluminophosphate

Molecular Sieves Significant Parameters in the Synthesis of Large Alkaline-Free MFI-Type Zeolites and AFI-type

Aluminophosphates Disordered Pentasil-Type Borosilicates: Synthesis and Characterization Isomorphous

Substitution of Boron in Mordenite and Zeolite Y Hydrothermal

Isomorphous Substitution of Iron in the Faujasite lattice Zeolite Chemistry: Substitution of Iron or Titanium for Aluminum in Zeolites via

Reaction with the Respective Ammonium Fluoride

Salts High-Silica Faujasite by Direct Synthesis

Secondary Synthesis of Faujasitic

Catalysts Quadrupole Mutation NMR Studies of Second

Generation Faujasitic Catalysts Mechanism of Rapid Zeolite

Crystallizations and its Applications to Catalyst

Synthesis Kinetics and Mechanism of Crystal Growth of Zeolite

Omega Synthesis of the New Large-Pore Zeolite ECR-1 Directing

Parameters in the Synthesis of Zeolites ZSM-20 and Beta

Syntheses and Characterization of Zeolite ZSM-20 Studies on the Kinetics of ZSM-23 Crystallization

High Resolution Electron Microscopic Studies of Zeolite ZSN-48

Competitive Role of Organic and Inorganic Cations Phase

Identification of Hydrothermal Crystallization

Computational Studies of Zeolite Framework Stability

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