9780306472459

A. Nano Materials

Lanthanide (III) Oxide Nanocomposites with Hexafluoroisopropylidine-Based Polyimides

(14)

D. Scott Thompson

D. W. Thompson

Robin E. Southward

Introduction

(4)

Hexafluoroisopropylidene-containing polyimides

(2)

Potential applications of fluorinated polyimides

(1)

Oxo-metal-polyimide composites

(1)

Research focus of paper

(1)

Experimental

(1)

Materials

(1)

Preparation of diquotris(2,4-pentanedionato)-lanthanum(III) and diaquotris(2,4-pentadionato)gadolinium(III) monohydrate

(1)

Preparation of polyimides

(1)

Preparation and characterization of oxo-lanthanum-polyimide composite films

(1)

Results and Discussion

(5)

Film synthesis

(1)

Film properties: linear coefficients of thermal expansion and thermal and mechanical properties

(4)

Rationale for the use of lanthanide(III)-based inorganic phases

(1)

Conclusions

(1)

References

(4)

Fumaryl Chloride and Maleic Anhydride Derived Crosslinked Functional Polymers and Nano Structures

(14)

Sam-Shajing Sun

Shahin Maaref

Carl E. Bonner

Introduction

(5)

Need for functional polymer nano structures

(3)

Polymer NLO waveguide

(2)

A Brief Survey of Crosslinked NLO Polymers

(2)

Thermally crosslinked systems

(1)

Photo crosslinked systems

(1)

Fumaryl Chloride and Maleic Anhydride Derived Crosslinked NLO Polymers

(4)

Fumarate type crosslinkable polymers

(2)

NLO Polymers from fumarate type crosslinked polymers

(2)

Summary and Future Research

(1)

References and Notes

(2)

Humeral Immune Response to Polymeric Nanomaterials

(12)

Stephen C. Lee

R. Parthasarathy

K. Botwin

D. Kunneman

E. Rowold

G. Lange

J. Zobell

T. Beck

T. Miller

R. Jansson

C. F. Voliva

Introduction

(4)

General

(1)

Antigens, immunization and antibodies

(3)

Current studies

(1)

Experimental

(1)

Results and Discussion

(3)

Immune responses to PAMMAN dendrimers

(1)

Antibody recognition to PAMAN dendrimers

(2)

Summary and Prospects

(1)

References

(3)

Preparation and Characterization of Novel Polymer/Silicate Nanocomposites

(12)

Mason K. Harrup

Alan K. Wertsching

Michael G. Jones

Introduction

(3)

Nanocomposite classification system

(3)

Experimental

(1)

Synthesis

(1)

Mechanical analysis

(1)

ESEM Measurements

(1)

Results and Discussion

(4)

Polyphosphazone nanocomposites

(3)

Organic polymer nanocomposites

(1)

Applications

(2)

Acknowledgments

(1)

References

(2)

Metallocene Hematoporphyrins as Analytical Reagents---Nickel (II) Metal Adsorption Studies of Group IVB Metallocene Polymers Derived from Hematoporphyrin IX

(8)

Charles E. Carraher, Jr.

Jerome E. Haky

Alberto Rivalta

Introduction

(2)

Experimental

(1)

Results and Discussion

(3)

References

(2)

Polyester Ionomers as Functional Compatibilizers for Blends with Condensation Polymers and Nanocomposites

(20)

Robert B. Moore

Timothy L. Boykin

Grant D. Barber

Introduction

(3)

Experimental

(3)

Materials

(1)

Preparation of blend samples

(1)

Blend characterization

(1)

Preparation of nanocomposite samples

(1)

Nanocomposite characterization

(1)

Results and Discussion

(8)

AQ/PET Blends

(1)

AQ/N66 Blends

(1)

NaSPET/PBT Binary blends

(1)

NaSPET/N66 Binary blends

(1)

NaSPET/PET/N66 Compatibilized blends

(2)

PET Nanocomposites

(1)

PA Nanocomposites

(1)

Conclusions

(1)

Acknowledgments

(1)

References

(5)

B. Light and Energy

Sulfonated and Carboxylated Copoly(Arylenesulfone)s for Fuel Cell Applications

(12)

Dirk Poppe

Torsten Zerfaß

Rolf Mulhaupt

Holger Frey

Introduction

(3)

Polyarylene Synthesis

(5)

Polyarylenesulfones with SO3H groups

(2)

Polyarylenes with COOH groups

(2)

COOH/SO3H-Blends

(1)

Membrane Properties

(2)

Summary

(1)

Acknowledgment

(1)

References

(2)

Preparation and Properties of Sulfonated or Phosphonated Polybenzimidazoles and Polybenzoxazoles

(10)

Yoshimitsu Sakaguchi

Kota Kitamura

Junko Nakao

Shiro Hamamoto

Hiroshi Tochimori

Satoshi Takase

Introduction

(2)

Experimental

(1)

Results and Discussion

(5)

Conclusions

103

(1)

References

103

(2)

Design of Conjugated Polymers for Single Layer Light Emitting Diodes

105

(16)

Zhonghua Peng

Introduction

105

(1)

Conjugated Polymers Exhibiting High Solid State PL Efficiencies

106

(3)

Exploring Approaches Toward Balanced Charge Injection and Transport

109

(7)

Polymers with Both High PL Efficiency and Balanced Charge-Injection Properties

116

(2)

Conclusions

118

(1)

References

119

(2)

Synthesis and Characterization of Novel Blue Light-Emitting Polymers Containing Dinaphthylanthracene

121

(14)

Shiying Zheng

Jianmin Shi

Introduction

121

(2)

Experimental

123

(5)

Results and Discussion

128

(5)

References

133

(2)

Novel Two-Photon Absorbing Polymers

135

(16)

Kevin D. Belfield

Alma R. Morales

Stephen Andrasik

Katherine J. Schaefer

Ozlem Yavuz

Victor M. Chapela

Judith Percino

Introduction

135

(2)

Results and Discussion

137

(6)

Experimental

143

(3)

Measurements

143

(1)

Synthesis

143

(1)

General

143

(1)

2,7-Dicyclo-9,9-didecylfluorene(3)

144

(1)

Poly(benzo[1,2-d:4,5-d']bisthiazole-9,9-didecylfluorene)(5)

144

(1)

7-Benzothiazol-2-yl-9,9-didecylfluoren-2-ylamine-modified poly(styrene-co-maleic anhydride)(7)

145

(1)

7-Benzothiazol-2-yl-9,9-didecylfluorene-2-ylamine-modified poly(ethylene-g-maleic anhydride)(8)

146

(1)

Conclusions

146

(1)

Acknowledgments

146

(1)

References

147

(4)

C. Bioactivity and Biomaterials

Natural Functional Condensation Polymer Feedstocks

151

(34)

Charles E. Carraher, Jr.

Introduction

151

(2)

Polysaccharides

153

(16)

Inorganic esters

155

(1)

Organic esters

156

(4)

Other polysaccharides

160

(1)

Homopolysaccharides

160

(2)

Chitin and chitosan

162

(3)

Heteropolysaccharides

165

(4)

Nucleic Acids

169

(6)

Primary structure

170

(2)

Secondary structure

172

(1)

Higher structures

173

(1)

Supercoiling

173

(1)

Compaction

173

(2)

Replication

175

(1)

Proteins

175

(6)

General structures

175

(2)

Secondary structure

177

(1)

Keratines

177

(2)

Collagen

179

(1)

Tertiary structure

180

(1)

Globular proteins

180

(1)

Lignin

181

(2)

Readings

183

(2)

Functional Polymers Derived from Condensation of Itaconic Andydride with Poly(ε-Caprolactone)diol and with Poly(Ethylene glycol)

185

(14)

Monica Ramos

Samuel J. Huang

Introduction

185

(1)

Experimental

186

(3)

Materials

186

(1)

Instrumentation

187

(1)

Synthesis of polycaprolactone diitaconates

187

(1)

Synthesis of poly(ethylene glycol) diitaconates

187

(1)

Crosslinkning procedure

188

(1)

Gel swelling

189

(1)

Results and Discussion

189

(6)

Spectral characteristics of PCLDIs and PEGDIs macromonomers

189

(2)

Characterization of the hydrogels

191

(4)

Conclusions

195

(1)

Acknowledgments

196

(1)

References

196

(3)

Organometallic Condensation Polymers as Anticancer Drugs

199

(8)

Deborah W. Siegmann-Louda

Charles E. Carraher, Jr.

Fred Pflueger

David Nagy

John R. Ross

Introduction

199

(2)

Experimental

201

(1)

Results and Discussion

202

(3)

References

205

(2)

Synthesis and Structural Characterization of Chelation Products Between Chitosan and Tetrachloroplatinate Towards the Synthesis of Water Soluble Cancer Drugs

207

(16)

Charles E. Carraher, Jr.

Ann-Marie Francis

Deborah W. Siegmann-Louda

Introduction

207

(6)

Chitosan

207

(1)

Platinum-containing anticancer drugs

208

(5)

Experimental

213

(1)

Results and Discussion

214

(7)

Synthesis

214

(2)

Structural characterization

216

(5)

References

221

(2)

Condensation Polymers as Controlled Release Materials for Enhanced Plant and Food Production: Influences of Gibberellic Acid and Gibberellic Acid-Containing Polymers on Food Crop Production

223

(14)

Charles E. Carraher, Jr.

Herbert Stewart

Shawn M. Carraher

Donna M. Chamely

Wesley W. Learned

James Helmy

Kumudi Abey

Alicia R. Salamone

Introduction

223

(8)

General

223

(3)

Gibberellins

226

(2)

Auxins

228

(1)

Cytokinetins

229

(1)

Current study

230

(1)

Experimental

231

(1)

Results and Discussion

231

(2)

References

233

(4)

D. Enhanced Physical Properties

2,6-Anthracenedicarboxylate-Containing Polyesters and Copolyesters

237

(12)

David M. Collard

David A. Schiraldi

Introduction

237

(1)

Monomer Synthesis and Polymerization

238

(3)

Monomer synthesis

238

(2)

Polymerization

240

(1)

Poly(alkylene anthracene 2,6-dicarboxylate)s, PnA

241

(1)

Poly(ethylene 2,6-anthracenedicarboxylate-co-terephthalate)s, PET-A

242

(1)

Diels-Alder Crosslinking and Grafting Reactions of PET-A

242

(1)

Photocrosslinking of PET-A

243

(2)

Chain Extension of Anthracene-terminated PET

245

(2)

Conclusions

247

(1)

References

248

(1)

Synthesis and Characterization of Ionic and Non-ionic Terminated Amorphous Poly(Ethylene isophthalate)

249

(14)

Huaiying Kang

R. Scott Armentrout

Jianli Wang

Timothy E. Long

Introduction

249

(1)

Experimental

250

(4)

Materials

250

(1)

Preparation of catalyst solutions

251

(1)

Synthesis of non-terminated high molecular weight poly(ethylene isophthalate) (PEI)

251

(1)

Synthesis of sulfonate terminated PEI ionomers (PEI-SSBA)

251

(1)

Synthesis of dodeconol terminated poly(ethylene isophthalate) (PEI-Dode-OH)

252

(1)

Polymer characterization

253

(1)

Results and Discussion

254

(6)

GPC and NMR Analysis

254

(2)

FTIR Analysis

256

(1)

DSC and TGA Analysis

256

(2)

Solution viscometry study

258

(1)

Melt rheology study

259

(1)

Conclusions

260

(1)

References

261

(2)

Synthesis, Characterization and Application of Functional Condensation Polymers from Anhydride Modified Polystyrene and Their Sulfonic Acid Resins

263

(24)

Sakuntala Chatterjee Ganguly

Introduction

263

(5)

Functional condensation polymer

263

(1)

Synthesis and chemical modification of a polymer in bulk

263

(3)

Surface modification of a polymer by chemical modification

266

(2)

Surface modification of a polymer by interpenetrating network (IPN) formation

268

(1)

Experimental

268

(3)

Material

268

(1)

Synthesis

269

(1)

Preparation of PSPA, PSTM, PSTHPA, PSPMDA

269

(1)

Synthesis of sulfonic acid resins PSPAS, PSTMAS, PSTHPAS, PSPMDAS and their sodium salts

269

(1)

Preparation of PSNTDA, PSPTDA and PS6FDA

269

(1)

Preparation of PSPMDA film

270

(1)

Preparation of dianhydride coated Teflon membrane

270

(1)

Characterization

270

(1)

Results and Discussion

271

(14)

Characterization of PSPA, PSTMA, PSTHPA, PSPMDA

271

(5)

Novel membrane from pyromellitic dianhydride modified polystyrene with controlled pore size on micro- and macrolevels

276

(1)

Structural characterization of sulfonic acids resins PSPAS, PSTMAS, PSTHPAS and PSPMDAS

276

(4)

Structural characterization of PSPTDA, PS6FDA and PSNTDA

280

(3)

Low voltage scanning electron microscopy of a surface modified K-100 teflon membrane and thermal analysis studies of several anhydride modified Nafioin 417 membranes

283

(2)

Conclusion

285

(1)

References

286

(1)

Condensation Copolymerization via Ru-Catalyzed Reaction of o-Quinones or α-Diketones with α,σ-Dihydrido-oligodimethylsiloxanes

287

(12)

Joseph M. Mabry

William P. Weber

Introduction

287

(1)

Poly(silyl ether)s

287

(1)

Transition metal catalysis

287

(1)

Poly (silyl enol ether)s

288

(1)

Experimental

288

(4)

Results

292

(5)

Results

292

(1)

NMR Spectra

293

(2)

Mechanism

295

(1)

Luminescence

296

(1)

References

297

(2)

Gel-Drawn Poly(p-phenylenepyromellitimide)

299

(12)

Jiro Sadanobu

Rei Nishio

Introduction

299

(2)

History

299

(1)

New procedure

300

(1)

Experimental

301

(1)

Preparation of polyamic acid solution

301

(1)

Film fabrication

302

(1)

Characterization of polymer

302

(1)

Results and Discussion

302

(5)

Effects of gel-drawing

302

(3)

Microstructure developed in imidized film

305

(2)

Properties of PPPI film

307

(2)

Conclusions

309

(1)

References

309

(2)

Subject Index

311

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Functional Condensation Polymers

0306472457

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