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9780792374312

Soft Mechanochemical Synthesis

by ; ;
  • ISBN13:

    9780792374312

  • ISBN10:

    0792374312

  • Format: Hardcover
  • Copyright: 2001-06-01
  • Publisher: Kluwer Academic Pub
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Summary

Mechanical methods of the activation of chemical processes are currently widely used for the synthesis of various compounds. The present monograph deals with the development of a novel approach to mechanochemical synthesis based on reactions of solid acids, bases, hydrated compounds, crystal hydrates, basic and acidic salts. This method has been called soft mechanochemical synthesis. The monograph includes the papers published by the present authors. They describe the results of their investigations n the last two decades. New theoretical and experimental data on kinetics and mechanism of soft mechanochemical reactions in the mixtures of compounds mentioned above to give complex oxide compounds are presented. The description of new high energetic and high efficient mills providing effective occurrence of these reactions is delivered. The possibilities of applying soft mechanochemical synthesis for materials used in catalysts, material science, electronics, etc., are discussed. The advantages of the method proposed in comparison with other methods are demonstrated. The monograph is designed for researchers, engineers and technicians engaged in chemical and ceramic industry, for scientists and students specialized in the area of development, and application of new materials.

Table of Contents

Preface ix
Introduction to Soft Mechanochemistry
1(8)
Chemical Bonds, Structure and Preparation of Hydrated Oxides
9(30)
Chemical bonds in hydrated oxides and their structures
9(11)
Properties of hydrated oxides
20(10)
Acid-base properties
20(6)
The solubility of hydroxides
26(3)
Thermal properties
29(1)
The preparation of hydroxides
30(9)
Some Theoretical Aspects of Mechanochemical Reactions
39(20)
Thermodynamics of acid-base reactions
39(4)
The kinetics of mechanochemical reactions
43(3)
Energy yield of mechanochemical reactions
46(1)
Comparison of soft mechanochemical synthesis with other methods
47(12)
Specific features of the preparation of complex oxides from coprecipitated hydroxides
48(4)
Peculiarities of hydrothermal synthesis
52(7)
Apparatus For Mechanochemical Reactions
59(10)
Planetary mills
59(5)
Vibratory-centrifugal mills
64(1)
Ring roll mills
65(4)
Mechanical Activation of Hydrated Oxides
69(10)
Ordinary hydrated oxides
69(4)
Hydrated complex oxides
73(6)
Mechanochemical Synthesis of Double Oxides
79(66)
Aluminates
79(5)
Silicates
84(11)
Titanates
95(10)
Vanadates
105(8)
Managanates
113(10)
Ferrites
123(6)
Cobaltites
129(5)
Indium tin oxide
134(11)
Mechanochemical Synthesis of Multicomponent Oxide Compounds
145(22)
Aluminosilicates of alkaline earths
145(3)
Complex Compounds with superconductive properties
148(2)
Synthesis of phase pure perovskite compounds
150(3)
Hydroxyapatite
153(6)
Heteropolyacids
159(8)
Some Features and Possible Mechanisms of Mechanochemical Reactions of Hydrated Oxides
167(20)
Mechanism of formation of new bonds
168(5)
Computational methods - DV-Xα calculation
173(3)
Role of water in soft mechanochemical reactions
176(3)
Mechanochemical ligand exchange as a new concept of solid state synthesis
179(8)
Industrial Applications of Soft Mechanochemical Synthesis
187(10)
The preparation of ceramic concrete based on cement-free ceramic binding systems
187(2)
Improvement of cement binders
189(1)
Preparation of sorbents, catalysts and their supports
190(7)
Conclusions 197(2)
Subject Index 199(2)
Author Index 201

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