9783540051763

Condensed Matter
Magnetic and Other Properties of Oxides and Related Compounds


Introductory material
Non-iron garnets	p. 1
Introduction	p. 1
Magnetic susceptibility data	p. 2
Paramagnetic susceptibility above the ordering temperature	p. 2
Susceptibility data at low temperatures in the vicinity of an ordering temperature	p. 4
Summary of susceptibility parameters and transition temperatures	p. 7
Magnetization	p. 8
Crystallographic and structural data	p. 12
Location and environment of ions in the unit cell of the garnet lattice	p. 12
Oxygen coordinates, interionic spacings, and angles of compounds with garnet structure	p. 13
Lattice parameters and density of garnet systems	p. 15
Magnetic structure of DyAlG and ErGaG	p. 16
Results of magnetic resonance experiments	p. 18
Paramagnetic resonance of rare earth impurities in diamagnetic garnets	p. 18
Paramagnetic resonance of impurities with d electrons in diamagnetic garnets	p. 20
Paramagnetic resonance of impurities in paramagnetic garnets	p. 23
Nuclear magnetic resonance experiments	p. 24
Results from optical spectra	p. 26
Crystal field analysis and parameters	p. 26
Summary of references for some results from optical measurements	p. 27
Spin-lattice relaxation of paramagnetic ions in garnets	p. 28
Temperature dependence of the spin-lattice relaxation time T₁	p. 28
The dependence of the spin-lattice relaxation time on magnetic field	p. 33
Thermal properties near the transition temperature	p. 34
Specific heat of rare earth gallium garnets	p. 34
Specific heat of two rare earth aluminium garnets	p. 36
Faraday rotation in paramagnetic non-iron garnets	p. 38
Magnetomechanical properties	p. 41
Magnetostriction of rare earth gallates and germanates with a garnet structure	p. 41
Macroscopic magnetoelastic tensors for paramagnetic rare earth ions in diamagnetic garnet hosts	p. 42
Magnetoacoustic properties	p. 42
Neutron diffraction results near and below the magnetic ordering point	p. 43
References	p. 45
Primary references	p. 45
Supplementary references	p. 47
Spinels	p. 50
Arrangement	p. 50
Introduction	p. 51
General remarks	p. 51
Structure	p. 51
Fe³⁺ spinels (cubic ferrites)	p. 54
Ferrimagnetism; magnetic behaviour of ferrites	p. 54
A-B exchange interaction; magnetization	p. 54
A-A, B-B exchange interaction; magnetic order	p. 56
Hyperfine interactions (Môssbauer and NMR methods)	p. 57
Anisotropy	p. 59
Ferrimagnetic resonance	p. 60
Accuracy	p. 63
References for 6.0 and 6.1.0	p. 64
Fe²⁺-Fe³⁺ spinels (magnetite) and Fe²⁺-Fe³⁺ spinels with substitutions	p. 65
Tables and figures	p. 65
References for 6.1.1.1	p. 73
NiFe³⁺ spinels (Ni ferrites) and NiFe³⁺ spinels with substitutions	p. 75
Introduction	p. 75
Ni ferrite NiFe₂O₄	p. 75
Zn substituted Ni ferrite	p. 82
Ni ferrite with Co substitutions	p. 89
Dilute Mn and Co substitutions in Ni ferrite and Ni ferrite aluminate	p. 91
Ge substituted Ni ferrite	p. 96
Ni ferrite chromite	p. 97
Ni ferrite vanadate	p. 99
Ni ferrite aluminate	p. 100
Ni gallate ferrite	p. 103
References for 6.1.2.0 - 6.1.2.9	p. 103
Mn-Fe³⁺ spinels (Mn ferrites) and Mn-Fe³⁺ spinels with substitutions	p. 106
Introduction	p. 106
Phase equilibria and structure	p. 106
Phase equilibria	p. 106
Equilibrium oxygen partial pressure	p. 109
Lattice constants	p. 117
Ionic distribution	p. 124
Spin arrangement	p. 127
Thermal properties	p. 128
Specific heat	p. 128
Thermal conductivity	p. 129
Thermal expansion	p. 130
Diffusion and oxidation coefficients	p. 130
Ferrite thermodynamics	p. 131
Solid crystal growth	p. 133
Reactivity and sintering	p. 135
Mechanical properties	p. 136
Electrical properties	p. 139
Electrical resistivity	p. 139
Magnetoresistance and thermomagnetic effect	p. 147
Hall effect	p. 149
Seebeck effect	p. 151
Spontaneous magnetization	p. 152
Saturation moment at 0 K	p. 152
Magnetization as a function of temperature	p. 155
Magnetization in the region of the Curie point	p. 156
Curie temperatures	p. 158
Magnetocrystalline anisotropy	p. 160
Magnetocrystalline anisotropy in Mn ferrite	p. 160
Magnetocrystalline anisotropy in Mn ferrite with substitutions	p. 164
Linear magnetostriction	p. 170
Magnetic annealing	p. 173
Domains and domain walls	p. 176
Domain wall motion experiments	p. 176
Domain structure	p. 179
Response of magnetization to a field	p. 179
High temperature susceptibility	p. 180
High field susceptibility in the ferrimagnetic state	p. 181
Permeability variation with composition, impurities, irradiation, and grain size	p. 181
Permeability vs. temperature	p. 184
Permeability vs. pressure	p. 186
Permeability vs. frequency	p. 187
After-effect, disaccommodation, and viscosity	p. 188
Microwave properties	p. 200
Resonance line width	p. 200
Spectroscopic splitting factor	p. 206
Optical properties (absorption)	p. 207
References for 6.1.3.0 - 6.1.3.10	p. 208
Mg-Fe³⁺ spinels (Mg ferrites) and Mg-Fe³⁺ spinels with substitutions	p. 216
Mg ferrite MgFe₂O₄	p. 216
MgMn ferrites and MgMn ferrites with substitutions	p. 228
Introductory remarks	p. 228
Crystallographic properties, physical properties, phase data, magnetic moments	p. 228
Anisotropy	p. 239
Losses	p. 243
Square-loop properties	p. 247
Microwave properties	p. 268
Other ferrite systems containing Mg	p. 280
Introductory remarks	p. 280
Systems containing Zn²⁺	p. 280
Systems containing Cu²⁺	p. 283
Systems containing Ni²⁺	p. 286
Systems containing Al²⁺	p. 290
Systems containing Cr³⁺	p. 296
Systems containing Al³⁺ + Cr³⁺	p. 301
Other systems containing trivalent and higher valency cations	p. 302
Systems containing F⁻ and Li⁺	p. 310
References for 6.1.4.1 - 6.1.4.3	p. 311
Zn-Fe³⁺ spinels (Zn ferrites) and Zn-Fe³⁺ spinels with substitutions	p. 315
Zn, Zn-Fe, Zn-Ti, Zn-Li, Zn-Ti-Li, Zn-Cd, Zn-Mg, Zn-Co, and Zn-Cu ferrites	p. 315
Zn-Ni, Zn-Ni-Ge, and Zn-Ni-Sb ferrites	p. 320
References for 6.1.5.1 and 6.1.5.2	p. 324
Li-Fe³⁺ spinels (Li ferrites) and Li-Fe³⁺ spinels with substitutions	p. 325
Li ferrite	p. 325
Li-Cr ferrites	p. 332
Li-Zn, Li-Zn-Co, Li-Ti, Li-Zn-Ti, and Li-Zn-Ti-Al-Mn ferrites	p. 334
Li-A1, Li-Ga, Li-Cd ferrites and Li-Fe ferrites	p. 338
Li-Mn, Li-V, and Li-Ge ferrites	p. 341
References for 6.1.6.1 - 6.1.6.5	p. 342
Cu-Fe³⁺ spinels (Cu ferrites) and Cu-Fe³⁺ spinels with substitutions	p. 343
Cu ferrite CuFe₂O₄	p. 343
Cu-Zn and Cu-Cd ferrites	p. 351
Cu-Cr ferrites	p. 356
Cu-Mg ferrites	p. 357
Other ferrites, oxide compounds, and oxide mixtures containing Cu	p. 360
References for 6.1.7.1 - 6.1.7.5	p. 365
Co-Fe³⁺ spinels (Co ferrites) and Co-Fe³⁺ spinels with substitutions	p. 366
Co ferrite	p. 366
Co ferrite and Co-Fe mixed oxides	p. 377
Co-Zn ferrites	p. 384
Co-Cd, Co-Mg, Co-Ni, and Co-Cr ferrites	p. 391
References for 6.1.8.1 - 6.1.8.4	p. 392
Cr spinels	p. 394
Cr oxide-spinels	p. 394
Binary Cr oxide-spinels	p. 394
Ternary and quarternary Cr oxide-spinels	p. 404
References to 6.2.1.1 and 6.2.1.2	p. 418
Cr sulfide, selenide and telluride spinels	p. 619
Comparison of the crystallographic, electrical, and magnetic properties of Cr spinels containing S, Se and Te	p. 619
Comparative properties of CdCr₂Se₄, CdCr₂S₄, HgCr₂Se₄, and HgCr₂S₄	p. 621
Cd-Cr selenide spinel	p. 622
Cd-Cr selenide spinel with substitutions	p. 625
Cd-Cr sulfide spinel and substituted compounds	p. 629
Hg-Cr selenide, Hg-Cr sulfide spinels and their substituted compounds	p. 632
Cu-Cr S, Se and Te spinels	p. 634
Cu-Cr S, Se and Te spinels with substitutions	p. 638
Fe-Mn-, Co- and Zn-Cr S and Se spinels and their substituted compounds	p. 642
References for 6.2.2.1 - 6.2.2.9	p. 645
Further spinels	p. 422
V spinels and substituted V spinels	p. 422
V spinels with V³⁺	p. 422
V spinels with V⁴⁺	p. 426
V spinels with V⁵⁺	p. 430
V spinels with V³⁺ and V⁴⁺	p. 430
Ge spinels and substituted Ge spinels	p. 436
Rh spinels and substituted Rh spinels	p. 441
References to 6.3.1 - 6.3.3	p. 444
Al spinels and substituted Al spinels	p. 446
Ga spinels and substituted Ga spinels	p. 467
In spinels and substituted In spinels	p. 474
References to 6.3.5 - 6.3.7	p. 476
Co spinels and substituted Co spinels	p. 481
Ni spinels and substituted Ni spinels	p. 488
Te spinels and substituted Te spinels	p. 488
Mn spinels and substituted Mn spinels	p. 488
Ti spinels and substituted Ti spinels	p. 512
References to 6.3.9 - 6.3.13	p. 528
Mo spinels and substituted Mo spinels	p. 533
W spinels and substituted W spinels	p. 533
Nb spinels and substituted Nb spinels	p. 533
Zr spinels	p. 534
Sb spinels and substituted Sb spinels	p. 534
Sn spinels and substituted Sn spinels	p. 535
Si spinels and substituted Si spinels	p. 543
References to 6.3.15 - 6.3.21	p. 545
Hexagonal ferrites	p. 547
Introduction	p. 547
Quantities and units	p. 547
List of symbols	p. 552
Chemical compositions and phase diagrams of hexagonal ferrites	p. 555
Crystal structures	p. 557
Paramagnetic properties of ferrites with hexagonal crystal structures	p. 561
M (magnetoplumbite)-type ferrites	p. 562
Survey of the chemical substitutions in the M structure and room temperature lattice constants	p. 562
Electric and dielectric properties	p. 564
Môssbauer spectra, saturation magnetization, and Curie temperature	p. 567
Effective spectroscopic splitting factor g_eff	p. 573
Magneto-crystalline anisotropy	p. 573
Hysteresis properties	p. 577
High-frequency magnetic properties	p. 580
Magnetic spectrum	p. 580
Line width of the ferromagnetic resonance	p. 583
W-type ferrites	p. 584
Survey of chemical substitutions in the W structure	p. 584
Electric and dielectric properties	p. 585
Saturation magnetization and Curie temperature	p. 586
Effective spectroscopic splitting factor g_eff	p. 588
Magneto-crystalline anisotropy	p. 588
Magnetostriction	p. 592
High-frequency magnetic properties	p. 593
Y-type ferrites	p. 593
Lattice parameters	p. 593
Electric and dielectric properties	p. 593
Mössbauer spectra, saturation magnetization, spectroscopic splitting factor, and Curie temperature	p. 594
Magneto-crystalline anisotropy	p. 597
Magneto-crystalline anisotropy derived from static measurements	p. 597
Magneto-crystalline anisotropy field derived from the ferromagnetic resonance frequency	p. 598
Hysteresis properties	p. 599
High-frequency magnetic properties	p. 600
Magnetic spectrum of the initial permeability	p. 600
Ferromagnetic resonance properties	p. 600
Non-linear effects in the ferromagnetic resonance	p. 603
Z-type ferrites	p. 606
Lattice parameters	p. 606
Resistivity	p. 606
Saturation magnetization and Curie temperature	p. 606
Magneto-crystalline anisotropy	p. 607
High-frequency magnetic properties	p. 608
U-type ferrites	p. 608
Calcium ferrites	p. 609
References for 7	p. 614
Index of substances for III/4a and III/4b	p. 647
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Magnetic and Other Properties of Oxides and Related Compounds / Magnetische Und Andere Eigenschaften Von Oxiden Und Verwandten Verbindungen B

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