NMR Spectroscopy of Polymers in Solution and in the Solid State brings together a variety of papers on both solution and solid state nuclear magnetic resonance (NMR) in one convenient volume. It includes 31 chapters which are divided into the following sections: overview, solid state NMR of polymers, solution NMR of synthetic polymers, solution NMR of biopolymers, combined NMR-separation techniques, and dynamics of polymers in solution. Practicing NMR spectroscopists, students, and other newcomers to the field will benefit from the book's dual coverage.

Preface

xi

Overview

Advances in the NMR Spectroscopy of Polymers: An Overview

3

(19)

H.N. Cheng

Alan D. English

Solid-State NMR of Polymers

Solution and Solid-State NMR Characterization of Ethylene Oxide-Propylene Oxide Composites for Ultra-Low Dielectric Constant Applications

22

(10)

Peter A. Mirau

Shu Yang

High-Temperature Solid-State NMR of Cross-Linked, Insoluble, and Unswellable Polymers

32

(11)

Khalid Thakur

NMR Studies of the Dynamics of Homo- and Block-Copolymer Poly(ε-caprolactone) Chains in Their Inclusion Compounds with α- and γ-CDs

43

(15)

J. Lu

P. A. Mirau

S. Nojima

A. E. Tonelli

Structural Aspects of Low-Molecular-Weight Azocellulose Polymers: A Solid-State 13C NMR Study

58

(13)

Suizhou Yang

Monsey M. Jacob

Lian Li

Ashok L. Cholli

Jayant Kumar

Structure of Bombyx mori Silk Fibroin before Spinning in Silkworm

71

(12)

Tetsuo Asakura

Jun Ashida

Tsutomu Yamane

Estimation of Physical Properties of Archeological Silk with NMR Relaxation Time and Fluctuation-Dissipation Theorem

83

(11)

Riichiro Chujo

Kyoko Fukutani

Yoshiko Magoshi

Solution NMR of Synthetic Polymers: Multidimensional NMR Techniques

Polymer Characterization by 3D Solution NMR

94

(29)

Peter L. Rinaldi

Triple Resonance 1H/13C/19F Multidimensional Solution NMR of Fluoropolymers: Experimental Aspects

123

(14)

Olivier Assemat

Peter L. Rinaldi

1H/13C/29Si Triple Resonance 3D NMR Study of Poly(dimethylsiloxane) MD3MH

137

(10)

Minghui Chai

Peter L. Rinaldi

Sanlin Hu

Multidimensional NMR Studies on Polyurethane-Based Dendritic Wedges

147

(19)

Minghui Chai

Peter L. Rinaldi

Uraiwan Puapaiboon

Richard T. Taylor

Compositional and Configurational Assignments of Acrylonitrile Copolymers by 2D NMR Spectroscopy

166

(8)

A. S. Brar

Structure Determination of Poly(vinyl alcohol) by 2D NMR Spectroscopy

174

(5)

A. S. Brar

R. Kumar

A. Yadav

M. Kaur

2D NMR of Polymers: Comparison of Some of the Standard Pulse Sequences

179

(13)

Richard A. Newmark

John L. Battiste

Michael N. Koivula

Solution NMR of Synthetic Polymers: Polymer Solution Studies

Recent Advances in the NMR Description of Polypropylene

192

(16)

V. Busico

L. Mannina

A. L. Segre

V. Van Axel Castelli

Effect of Internal Donors in Propylene Polymerization Analyzed with NMR and the Internet

208

(8)

Kenichi Shimozawa

Masayoshi Saito

Riichiro Chujo

Branching Polyester Oligomers and Fractals

216

(12)

Gavin P. Andrews

Allan H. Fawcett

Majid I. M. Hania

An NMR Study on the Bulk Cationic Copolymerization of Trioxane with 1,3-Dioxepane

228

(14)

Min-Hui Cui

Yuli Zhang

Mark Werner

Nan-Loh Yang

Steven P. Fenelli

John A. Grates

1H and 13C Solution NMR of Polyimides Based on 4,4'-Diaminotriphenylmethane: Conformational Analysis Using NOE and Molecular Modeling

242

(16)

Antonio Martinez-Richa

Ricardo Vera-Graziano

Dmitri Likhatchev

In-Situ NMR Spectroscopy to Understand the Mechanism of Enzymatic Polymerization of Engineering Polymeric Materials: Poly(phenols)

258

(14)

Sangrama K. Sahoo

Wei Liu

Lynne Samuelson

Jayant Kumar

Ashok L. Cholli

Solution NMR of Biopolymers

Origins of Flexibility in Complex Polysaccharides

272

(17)

C. Allen Bush

Keratan Sulfates: Structural Investigations Using NMR Spectroscopy

289

(9)

Thomas N. Huckerby

Gavin M. Brown

Robert M. Lauder

Ian A. Nieduszynski

Gelling Mechanisms of Glucomannan Polysaccharides and Their Interactions with Proteins

298

(8)

I. C. Baianu

E. M. Ozu

Synthesis, Physical, and NMR Characteristics of Di- and Tri-Substituted Cellulose Ethers

306

(19)

Navzer (Nozar) D. Sachinvala

David L. Winsor

Walter P. Niemczura

Karol Maskos

Tyrone L. Vigo

Noelie R. Bertoniere

2D NMR Analysis of Ethylcellulose

325

(13)

Qiuwei Xu

Mark Brickhouse

Huiming Wang

Combined NMR and Separation Techniques

On-Line HPLC-NMR of Polymers

338

(6)

Wolf Hiller

Harald Pasch

Complex Polymer Mixture Analysis by On-Line LC(GPC)-NMR

344

(14)

Jian Wu

Kebede Beshah

Copolymer Characterization by SEC-NMR and SEC-MALDI

358

(24)

Maurizio S. Montaudo

Coupled SEC-NMR Analysis of Alginates

382

(16)

Thomas G. Neiss

H. N. Cheng

Dynamics of Polymers in Solution

Local Segmental Dynamics of Polyacrylates in Concentrated Chloroform Solutions

398

(11)

Frank D. Blum

Raj B. Durairaj

NMR Spectroscopic Study of Ion-Conducting 15N-Labeled Polyphosphazenes

409

(16)

Thomas A. Luther

Mason K. Harrup

Frederick F. Stewart

Indexes

Author Index

423

(2)

Subject Index

425

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Nmr Spectroscopy of Polymers in Solution and in the Solid State

9780841238084

0841238081

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