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9780854046621

Aromatic Chemistry

by ; ; ;
  • ISBN13:

    9780854046621

  • ISBN10:

    0854046623

  • Format: Paperback
  • Copyright: 2002-10-25
  • Publisher: Royal Society of Chemistry

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Summary

This book provides an up-to-date and comprehensive account of aromatic chemistry. A series of chapters describes the synthesis and reactions of the major functional derivatives of benzene and the more common polycyclic systems. The concept of aromaticity and the mechanism of aromatic substitution are discussed, as is the use of metals in the synthesis of aromatic compounds. Throughout, emphasis is placed on mechanisms. Worked problems and questions are provided to aid understanding. In addition to providing material required by an undergraduate studying chemistry, Aromatic Chemistry is also ideal for industrial chemists seeking to update their knowledge of this important aspect of chemistry. Ideal for the needs of undergraduate chemistry students, Tutorial Chemistry Texts is a major new series consisting of short, single topic or modular texts concentrating on the fundamental areas of chemistry taught in undergraduate science courses. Each book provides a concise account of the basic principles underlying a given subject, embodying an independent-learning philosophy and including worked examples.

Table of Contents

Aromaticityp. 1
Structure of Benzenep. 2
Stability of the Benzene Ringp. 2
The Huckel Rulep. 5
Nomenclaturep. 11
Aromatic Substitutionp. 15
Electrophilic Aromatic Substitution (S[subscript E]Ar)p. 16
Reactivity and Orientation in Electrophilic Aromatic Substitutionp. 20
The Hammett Equationp. 31
Nucleophilic Aromatic Substitutionp. 33
ipso Substitutionp. 35
Alkylbenzenes and Arylbenzenesp. 38
Source of Alkylbenzenesp. 38
Introduction of Alkyl Groupsp. 39
Reactions of Alkylbenzenesp. 42
Aryl Derivatives of Benzenep. 44
Phenolsp. 47
Industrial Synthetic Methodsp. 47
Laboratory Synthesesp. 48
The Acidity of Phenolsp. 50
Reactions of the Hydroxy Groupp. 51
Reactions of the Ringp. 53
Dihydroxybenzenesp. 55
Aromatic Acidsp. 58
Introduction of Acidic Groupsp. 58
Reactions of Aromatic Acidsp. 60
Acidity of Aromatic Acidsp. 63
Compounds with More Than One Acidic Groupp. 64
Side-chain Acidsp. 65
Aromatic Aldehydes, Ketones and Alcoholsp. 67
Aromatic Alcoholsp. 67
Aromatic Aldehydesp. 68
Aromatic Ketonesp. 76
Nitro Compoundsp. 79
Introduction of the Nitro Groupp. 79
Charge Transfer Complexesp. 83
Reactions of Nitro Compoundsp. 83
Nitrosobenzene and Phenylhydroxylaminep. 85
Aromatic Amines and Diazonium Saltsp. 88
Introduction of the Amino Groupp. 89
Reactions of Aromatic Aminesp. 91
Related Compoundsp. 93
Basicity of Aminesp. 94
Diazonium Saltsp. 95
Aromatic Halogen Compoundsp. 104
Synthesis of Aryl Halidesp. 105
Reactions of Aryl Halidesp. 108
Aromatic Halogen Compounds Substituted in the Side Chainp. 111
Organometallic Reactionsp. 114
Grignard and Organolithium Reagentsp. 114
Electrophilic Metallationp. 118
Transition Metal Mediated Processesp. 119
Aryl Coupling Reactionsp. 121
Arene-Chromium Tricarbonyl Complexesp. 125
Oxidation and Reduction of Aromatic Compoundsp. 129
Reduction of the Benzene Ringp. 129
Oxidation of the Benzene Ringp. 131
Polycyclic Aromatic Hydrocarbonsp. 135
Chemistry of Naphthalenep. 135
Chemistry of Anthracenep. 141
Chemistry of Phenanthrenep. 143
Further Readingp. 146
Answers to Problemsp. 148
Subject Indexp. 166
Table of Contents provided by Blackwell. All Rights Reserved.

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