Organometallic chemistry is an area which touches on, and plays an active role in, all of the traditional divisions of chemistry: inorganic, organic, physical and theoretical. This timely book provides overviews of recent original developments in these areas, including: the synthesis of main group, transition metal and lanthanide organometallics; applications to homogeneous catalysis; structural and theoretical studies; and enantioselective processes. As these topics are currently part of a stream of exciting research with potentially important industrial applications, this title presents informed accounts of state-of-the-art research which will be of great interest to readers. Written by some of the foremost groups in the field and handsomely illustrated throughout, each chapter also provides an extensive bibliography. By introducing areas that are likely to play a prominent role in organometallic chemistry in the near future, Perspectives in Organometallic Chemistry provides an authoritative source of ideas, particularly for all those engaged in research.

Group 15 element imido and phosphido cages; Coordination chemistry and synthetic applications

1

(16)

E.L. Doyle

A.D. Hopkins

G.T. Lawson

M. McPartlin

A.D. Woods

D.S. Wright

Neutral clusters EnRn of the monovalent elements gallium and indium. Recent results in synthesis and reactivity

16

(12)

W. Uhl

New titanium imido chemistry with polydentate N-donor ligands

28

(19)

P. Mountford

Organometallic complexes with 1,2-dichalcogenolate-o-carboranes

47

(15)

Guo-Xin Jin

Synthesis and reactivities of multinuclear sulfur-bridged metal complexes ranging from dinuclear to hexanuclear cores

62

(12)

M. Hidai

α,ω-Bis[(triphenylphosphine)gold(I)] hydrocarbons

74

(12)

K.A. Porter

A. Schier

H. Schmidbaur

Researches on non-classical organolanthanide chemistry

86

(14)

P.B. Hitchcock

A.G. Hulkes

A.V. Khvostov

M.F. Lappert

A.V. Protchenko

Hyper-structured alkynylruthenium complexes: Effect of dimensional evolution on NLO properties

100

(11)

M.G. Humphrey

M.P. Cifuentes

M. Samoc

T. Isoshima

A. Persoons

Cycloaddition of alkynes mediated by [RuCp(L)]+ (L = CO, NCH, PH3) and RuCpCl complexes -- Metallacyclopentatrienes as key intermediates -- A DFT study

111

(9)

M.J. Calhorda

K. Kirchner

L.F. Veiros

Selective C-C coupling reactions of Me2N-CC-NMe2 at iron(0) centers

120

(16)

A.C. Filippou

T. Rosenauer

G. Schnakenburg

Routes to fluorinated organic derivatives by nickel mediated C-F activation of heteroaromatics

136

(16)

T. Braun

R.N. Perutz

Novel η5 -- η6 rearrangement of bis(fluorenyl)lanthanide complexes by the addition of AIR3

152

(15)

H. Yasuda

Results and perspectives of high oxidation state organomolybdenum chemistry in water

167

(16)

E. Collange

F. Demirhan

J. Gun

O. Lev

A. Modestov

R. Poli

P. Richard

D. Saurenz

Modulation of electronic behaviour of metal carbonyl clusters

183

(13)

D. Collini

C. Femoni

M.C. Iapalucci

G. Longoni

P. Zanello

Interionic and intermolecular solution structure of transition metal complexes by NMR

196

(12)

A. Macchioni

Synthetic and mechanistic pathways in platinum(II) chemistry

208

(14)

R. Romeo

L. Monsu Scolaro

New perspectives for olefin complexes: Synthesis and characterisation of stable rhodium(0) and iridium(0) complexes

222

(18)

J. Harmer

G. Frison

M. Rudolph

H. Schonberg

S. Deblon

P. Maire

S. Boulmaaz

F. Breher

C. Bohler

H. Ruegger

A. Schweiger

H. Grutzmacher

Substitution and addition reactions catalyzed by transition metal complexes

240

(13)

I.P. Beletskaya

Late transition metal (Co, Rh, Ir)--siloxide complexes -- Synthesis, structure and application to catalysis

253

(12)

B. Marciniec

I. Kownacki

M. Kubicki

P. Krzyzanowski

E. Walczuk

P. Blazejewska-Chadyniak

Cheap chiral ligands for asymmetric transition metal catalyzed reactions

265

(10)

M.T. Reetz

Chiral metal complexes in asymmetric catalysis

275

(10)

C. Moberg

O. Belda

K. Hallman

R. Stranne

M. Svensson

J.L. Vasse

T. Wondimagegn

R. Zalubovskis

In search of asymmetric propargylic substitution reactions mediated by optically active indenyl-ruthenium(II) allenylidene complexes

285

(12)

V. Cadierno

S. Conejero

M.P. Gamasa

J. Gimeno

Recent developments on hydride iridium triisopropylphosphine complexes: [IrH2(NCCH3)3(PiPr3)]BF4 as hydrogenation catalyst

297

(9)

L.A. Oro

E. Sola

J. Navarro

Pd complex-catalyzed ring-opening polymerisation of 2-aryl-1-methylene-cyclopropanes

306

(11)

S. Kim

D. Takeuchi

K. Osakada

Subject Index

317

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Perspectives in Organometallic Chemistry

9780854048762

0854048766

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