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9780444823847

Structure, Fluctuation, and Relaxation in Solutions: Proceedings of the Yamada Conference Xxxxii, Nagoya, Japan, 11-15 December 1994

by ; ;
  • ISBN13:

    9780444823847

  • ISBN10:

    0444823840

  • Format: Hardcover
  • Copyright: 1996-01-01
  • Publisher: Elsevier Science Ltd
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List Price: $324.25
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Table of Contents

Preface
Organizing Committee and List of Participants
Welcome Address
Yamada Science Foundation and the Scope of Yamada Conference
Executive Members of Foundation
Papers not included in this special issue
Perspective of solution chemistry of Japan. The historical background and recent trendsp. 1
Molecular theory of solvation processes in dipolar and non-dipolar solventsp. 7
An interaction-site representation of the dynamic structure factor of liquid and the solvation dynamicsp. 15
The interplay of dielectric and mechanical relaxation in solvation dynamicsp. 23
Fluctuating charge force fields for aqueous solutionsp. 31
Solvation dynamics of dye molecules in polar solvents studied by time resolved hole burning spectroscopyp. 41
Ultrafast measurements of the dynamics of solvation in polar and non-dipolar solventsp. 49
Solvent and nuclear dynamic effects on intermolecular electron transferp. 59
Theory on rates of solution reactions influenced by slow fluctuations in viscous solvents, and its experimental confirmationp. 65
Dynamics of Brownian motion under a potential and theory on the rate of chemical reactionsp. 75
Structural characteristics of hydrogen-bonded networks in water and ice systemsp. 85
Structure and dynamics of supercooled and glassy aqueous ionic solutionsp. 91
The structure and dynamics of aqueous solutions containing complex moleculesp. 99
Liquid-liquid phase separations and critical behavior of electrolyte solutions driven by long-range and short-range interactionsp. 107
Slow relaxation in pure and binary frozen-in systemsp. 115
Slow dynamics in supercooled fluidsp. 123
Density functional theory of solution dynamicsp. 131
Dissociation and solvation in water and aqueous solutionsp. 139
Effect of solvent, temperature, and pressure on hydrogen bonding and reorientation of water moleculesp. 149
Collective vibrational dynamics of simple liquidsp. 157
Mechanisms of dephasing in femtosecond time-resolved coherent Raman scattering from molecules in liquidsp. 169
Ion solvation and ion association studied by infrared and microwave methodsp. 177
Dynamical aspects of water by low-frequency Raman scatteringp. 187
Ultrasonic relaxation study of fast exchange processes in mixed micelle systems of alcohol-decyltrimethylammonium bromide-waterp. 195
Organometallic free radicals in solutionp. 205
The structure of metal complexes of small models of glycoproteins in aqueous solutionp. 213
Kinetic evidence for short-lived intermediates in metalloporphyrin formationp. 221
Structure and dynamics of solvated ions: new tendencies of researchp. 229
The role of solvent in inorganic reaction mechanisms, as elucidated by high pressure studiesp. 237
EXAFS of bromide ion in solvents and at air/solution interfacep. 245
Redox properties of oxo-bridged di- and tri-nuclear complexes of heavy transition elements: stability of mixed-valence statep. 253
Study of the reduction of Co(NH[subscript 3][subscript 4](pzCO[subscript 2])[superscript 2+] by Fe(CN)[subscript 6][superscript 4-] in binary aqueous mixtures: an interpretation of solvent effects based on spectroscopic datap. 261
Ion pair of tetraalkylammonium picratesp. 265
Ion-pairing effects on the [superscript 59]Co electric field gradients in the NMR relaxations of tripositive cobalt(III) complex ionsp. 269
Concentration dependence of [superscript 59]Co relaxation rates of tris(acetylacetonatao)-cobalt(III) in some organic solventsp. 273
Mechanistic study of oxidation reactions of hydroquinone, catechol, and L-ascorbic acid by dicyanobis(1,10-phenanthroline)iron(III) in dimethyl sulfoxidep. 277
Molecular orientation in fluids near solid-liquid interface as studied by the density functional methodp. 281
The stability and dynamics of clathrate hydratesp. 285
Deviation of the TST rate constant through the nonlinear couplingsp. 289
Spatial correlations in reaction-diffusion systems in nonequilibrium conditionsp. 293
Nonlinear effects of solvation dynamicsp. 297
Solvation dynamics studied by ultrafast transient hole burningp. 301
Hydrogen-bonded structure in aqueous sulfuric acid solutionsp. 305
Raman spectroscopic study of rotational and vibrational relaxation of CF[subscript 3]H in the supercritical sitep. 309
Anomalous conformational behavior of short poly(oxyethylene) chains in water: an FT-IR spectroscopic studyp. 313
Time-resolved resonance Raman study of the recombination dynamics photodissociated carbon monoxide to sperm whale myoglobin and its mutantsp. 317
Solvent viscosity dependence of bimolecular reaction rate constant of the excited 9-cyanoanthracene quenched by 1.3-cyclohexadienep. 321
Extremely slow reorientation dynamics of molecular tracers in glassy polymersp. 325
Dynamics near a liquid surface: mechanisms of evaporation and condensationp. 329
The effect of ionic atmosphere on the tracer diffusion of micellesp. 333
Effect of addition of surfactant on the micelle-monomer exchange processp. 337
Dissipative structure in aqueous polymer solutionsp. 341
Non-linear effects in the free energy profile of electron transfer reaction: an integral equation approachp. 345
Induction time of precipitation of calcium carbonatep. 349
Photophysical properties of viologen-linked N-alkylporphyrins and their zinc(II) complexes in solutionsp. 353
Conductometric study of hydrophobic properties of tris (1,10-phenanthroline) and tris(2,2'-bipyridine) complexesp. 357
Structure of the monohalogenocadmium(II) complexes in N,N-dimethylformamidep. 361
Effect of pressure on the viscosity of aqueous cesium chloride solution at [25 degrees] Cp. 365
Melting behaviour in hexagonal CeCl[subscript 3] and monoclinic ErCl[subscript 2] crystalsp. 369
Polarization effect on the static and dynamic properties of molten lithium iodidep. 373
Evaluation of thermodynamic quantities of fluid mixtures by the PY equationp. 377
Solvation free energy of protein reproduced by the combination of the extended scaled particle theory and the Poisson-Boltzmann equationp. 381
Transport properties of a spherical molecule in solvent with position-dependent viscosityp. 385
Liquid dynamics studied by higher order non-linear optical spectroscopyp. 389
Temperature dependence of singlet excitation energy migration in liquid benzene as revealed by picosecond laser photolysisp. 393
Solvent effect on ultra-fast electron transfer in mixed-valence biferrocene monocationp. 397
Translational diffusion of transient radicals studied by the transient grating methodp. 401
Intra and intermolecular energy transfer in thermal dissociation in the gas and liquid N[subscript 2]O[subscript 4]p. 405
Photoelectron emission spectroscopy applied to bromide ion in solventsp. 409
Direct comparison between femtosecond optical Kerr effect and high-resolution light scattering measurementsp. 413
Vibrational cooling process in solution probed by picosecond time-resolved Raman spectroscopy. Analysis of the cooling kineticsp. 417
Rotational relaxation of rod like molecules: diphenylacetylene in various solventsp. 421
Ground state recovery of phenol blue in fluids near the gas-liquid critical densityp. 425
Dynamics of two-component liquids near the glass transitionp. 429
Relaxation characteristics of intracellular (Na[superscript +] as measured by double quantum filtered (DQf) NMRp. 433
Author Indexp. 437
Subject Indexp. 441
Table of Contents provided by Blackwell. All Rights Reserved.

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