9781402008955

It is possible to "stretch" a liquid and, when suitably prepared, liquids are capable of sustaining substantial levels of tension, often for significant periods of time. These negative pressure states are metastable but can last for days - long enough for substantial experimental investigation. This volume is a review of recent and current research into the behaviour of liquids under negative pressure. Part I deals with the thermodynamics of stretched liquids. Part II discusses the physical and chemical behaviour of liquids under negative pressure. Part III contains papers on the effect of negative pressure on the solidification of a liquid. Part IV is devoted to stretched helium and Part V discusses cavitation in various stretched liquids. Part VI deals with the effect of foreign substances on cavitation.

Introduction

ix

Photograph of the participants

xii

Participants

xiii

Part I: Stability, metastability and instability

Limits of stability for liquids under tension

1

(12)

R.J. Speedy

Limiting superheat of aqueous solutions at negative pressures

13

(10)

V.E. Vinogradov

P.A. Pavlov

Classical thermodynamics of states with negative absolute temperature or with negative absolute pressure

23

(10)

K. Martinas

A.R. Imre

Limiting tensions for liquids and glasses from laboratory and MD studies

33

(14)

Q. Zheng

J. Green

J. Kieffer

P. H. Poole

J. Shao

G. H. Wolf

C. A. Angell

Investigation of the thermodynamic properties of a polarizable water model in a wide range of pressures around the temperature of maximum density

47

(12)

P. Jedlovszky

R. Vallauri

Part II: Physical chemistry of liquids under negative pressure

Water at positive and negative pressures

59

(10)

H. E. Stanley

M. C. Barbosa

S. Mossa

P. A. Netz

F. Sciortino

F. W. Starr

M. Yamada

The thermophysical properties of liquids on the melting line at negative pressures

69

(12)

M. Faizullin

V.P. Skripov

Liquid-liquid phase equilibria in binary mixtures under negative pressure

81

(14)

A. R. Imre

Measuring the properties of liquids and liquid mixtures at absolute negative pressures

95

(14)

L.P.N. Rebelo

Z. P. Visak

J. Szydlowski

H. I. M. Veiga

R. Gomes de Azevedo

P. F. Pires

M. Nunes da Ponte

Limiting tensile strength of capillary-condensed liquids

109

(8)

W.D. Machin

On the tricritical point of the isotropic-nematic transition in a rod-like mesogen hidden in the negative pressure region

117

(10)

S. J. Rzoska

A. Drozd-Rzoska

Part III: Negative pressure and solidification

Negative pressure development during crystallization of polymers

127

(10)

A. Galeski

E. Piorkowska

Cavitation during isothermal crystallization of isotactic polypropylene and poly(methylene oxide)

137

(8)

E. Piorkowska

R. Nowacki

Part IV: Helium under negative pressure

The limits of metastability of liquid helium

145

(16)

S. Balibar

F. Caupin

Cavitation in 3He-4He liquid mixtures

161

(14)

M. Barranco

M. Guilleumas

M. Pi

D.M. Jezek

J. Navarro

A Quantum Monte Carlo study of the negative pressure regime in quantum liquids

175

(12)

J. Boronat

J. Casulleras

Nucleation of bubbles on electrons in liquid helium

187

(14)

H.J. Maris

D. Konstantinov

Quantum statistics of metastable liquid helium

201

(14)

F. Caupin

S. Balibar

Part V: Cavitation during static and dynamic tensions

Acoustic cavitation thresholds of ocean water

215

(16)

V.A. Akulichev

Cavitation in liquids by classical nucleation theory and molecular dynamics simulations

231

(12)

C. Xiao

D.M. Heyes

M. E. Parker

J. G. Powles

A study of cavitation phenomena using an atomic force microscope

243

(12)

M.S. Barrow

W.R. Bowen

N. Hilal

A. Al-Hussany

P.R. Williams

R.L. Williams

C. Wright

Cavitation thresholds, free surface and cavity cluster dynamics in liquids at shock wave reflection

255

(16)

A. Besov

V. Kedrinskii

J. De Vries

M. Kloosterman

Relaxation effects and disintegration problems of cavitating liquids at pulse loading

271

(14)

V.K. Kedrinskii

Measurements of the cavitation threshold of liquids under dynamic stressing by pulses of tension

285

(16)

P.R. Williams

R.L. Williams

Negative pressure tail of a reflected pressure pulse: A lattice-Boltzmann study

301

(6)

G. Hazi

A.R. Imre

Ultrasonic cavitation in freon at room temperature

307

(8)

F. Caupin

V. Fourmond

Part VI: Heterogeneous nucleation

Dependence on kinds of impurity gases in metals of negative pressures in water/metal Berhelot tube systems

315

(12)

Y. Ohde

Y. Tanzawa

Heterogeneous nucleation, influence of heterophase fluctuations on the cavitation strenght, and the supercooling of liquids with phase inclusions

327

V. A. Bulanov

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Liquids Under Negative Pressure

1402008953

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