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9780486495194

Treatise on Irreversible and Statistical Thermodynamics An Introduction to Nonclassical Thermodynamics

by ; ;
  • ISBN13:

    9780486495194

  • ISBN10:

    0486495191

  • Format: Hardcover
  • Copyright: 2002-05-01
  • Publisher: Dover Publications
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Summary

"Thermophysics poses one of the most exciting questions in theoretical physics: how can one reconcile the irreversibility of natural processes with the reversible mechanics governing the elementary constituents of thermal systems?" Professors Yourgrau, van der Merwe and Raw prefaced their treatise with this remark more than 30 years ago; while progress in thermophysics has been, to say the least, dynamic, the remark and the excitement hold true today. For this hardcover Dover edition, the authors (including Wolfgang Yourgrau before his death) extensively revised the treatise. The terms are the same: thermophysics "examines the connection of temperature and entropy with the nonthermal properties of matter and radiation." Thermodynamics strictly refers to "the phenomenological part of thermophysics," generally nonequilibrious; systems in thermomechanical equilibrium belong to thermostatics. Thermophysics conveniently divides into phenomenological (microscopic properties) and statistical (atomic). Classical thermophysics, finally, "excludes the whole of statistical mechanics, while in the phenomenological domain it includes only thermostatics." Contents include: Thermodynamics of Irreversible Processes; General Principles of Statistical Thermodynamics; Assemblies of Noninteracting Structureless Particles; Statistical Theory and More Complex Physical Systems. Each chapter has a bibliography; problems related to specific chapters are offered at the end of the work (no solutions). The reappearance of this treatise in a handsomely bound format will be especially welcomed by advanced students of physics; professors and specialized researchers will want this lucid monograph in their personal libraries for reference and review. Unabridged, corrected Dover republication of the edition published by The Macmillan Co., New York, 1966. Preface, appendix, problems, index, glossary of symbols and physical constants.

Table of Contents

Glossary of Symbols and Physical Constants xi
Thermodynamics of Irreversible Processes
1(54)
Some Concepts of First-Order Thermodynamics
4(6)
Entropy Balance and Entropy Production
10(8)
Forces, Fluxes, and Phenomenological Equations
18(5)
The Onsager Reciprocity Theorem
23(20)
Fluctuation Theory
Microscopic Reversibility
Regression of Fluctuations
Applications of Onsager's Theorem to Thermoelectric Phenomena
43(5)
Stationary States and Biological Systems
48(7)
General Principles of Statistical Thermodynamics
55(60)
The Statistics of μ-Space and γ-Space
57(3)
Liouville's Theorem
60(3)
The Ergodic Problem
63(3)
Phase Averages and the Canonical Distribution
66(2)
The Invalidation of the Classical Concepts
68(4)
Some Further Quantum-Mechanical Aspects
72(4)
The Gibbs Ensemble Method in Quantum Mechanics
76(6)
H-Theorem and Quantum-Mechanical Microcanonical Ensemble
82(7)
Classical H-Theorem, Entropy, and Thermodynamic Probability
89(8)
Quantum-Mechanical Canonical Ensemble
97(10)
Quantum-Mechanical Grand Canonical Ensemble
107(8)
Assemblies of Noninteracting Structureless Particles
115(57)
The Quantum-Mechanical Ideal Gas
118(3)
Dilute Bose-Einstein and Fermi-Dirac Gases
121(4)
Highly Degenerate Fermi-Dirac Gas
125(3)
Thermodynamic Functions of a Fermi-Dirac Gas
128(6)
Application of Fermi-Dirac Statistics to Electrons in Metals
134(4)
Arbitrarily Degenerate Bose-Einstein Ideal Gas
138(6)
Properties of a Bose-Einstein Gas as Functions of T, V, N
144(5)
Behavior of a Bose-Einstein Gas near the Condensation Temperature
149(6)
Statistics of a Photon Gas
155(6)
Blackbody Radiation and the Laws of Planck and Stefan
161(6)
Historical Postscript to Planck's Radiation Law
167(5)
Statistical Theory and More Complex Physical Systems
172(63)
Low-Density Ideal Molecular Gases
172(6)
Thermodynamic Properties of Monatomic Ideal Gases
178(7)
Separation of Degrees of Freedom in a Diatomic Molecule
185(10)
Thermodynamic Properties of Diatomic Ideal Gases
195(8)
Normal Vibrations of Monatomic Crystalline Solids
203(6)
Heat-Capacity Theories of Einstein and Debye
209(8)
Lattice Theory of Born and von Karman and Extensions
217(8)
Epilogue: Some Features of Interacting Particle Systems
225(10)
Appendix: The Gibbs Entropy Paradox 235(7)
Problems 242(19)
Index 261

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