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9783527346912

Mössbauer Spectroscopy Applications in Chemistry and Materials Science

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  • ISBN13:

    9783527346912

  • ISBN10:

    3527346910

  • Edition: 1st
  • Format: Hardcover
  • Copyright: 2023-08-07
  • Publisher: Wiley-VCH

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Summary

Mössbauer Spectroscopy

Unique and comprehensive overview of versatile applications of Mössbauer spectroscopy in chemistry and material sciences

Mössbauer Spectroscopy provides a comprehensive overview of relevant applications of this physical analysis method in chemistry and material sciences.

The book shows the versatility of Mössbauer spectroscopy in finding useful information on electronic structure, structural insights, and solid-state effects of chemical systems. A wide range of chemical applications and applied concepts are covered as well as numerous examples, selected from recent literature.

To aid in reader comprehension and accessibility, contents are well-structured and divided in different sections covering energy, catalysis, coordination chemistry, spin crossover, sensing, photomagnetism.

Edited by prominent scientists in the field and authored by a group of international experts, Mössbauer Spectroscopy covers sample topics such as:

  • Li-ion batteries, catalysts, fuel cells, Fe based silicides and iron phosphates containing minerals
  • Gold clusters and gold mixed valence complexes
  • Molecule based magnets, photoswitchable spin crossover coordination polymers and molecular sensors for meat freshness control

With comprehensive coverage of the developments in the technique, Mössbauer Spectroscopy is a beneficial resource for researchers, professionals, and academics in chemistry related fields, such as material science, sustainable environment, and molecular electronics. It can be used by newcomers as well as for educational purposes at the master and PhD levels.

Author Biography

Yann Garcia studied chemistry and physics at the University of Bordeaux (France), where he also completed his PhD degree with the late Prof. Olivier Kahn. He was a postdoctoral fellow at University of Mainz (Germany) with Prof. Philipp Gütlich. He joined the UCLouvain (Belgium) in 2001 where he is currently a professor of analytical chemistry. His research interests span spin crossover materials, photomagnetic molecular switches, hybrid materials and chemical applications of Mössbauer spectroscopy.

Junhu Wang studied radiochemistry at Lanzhou University (China). He was awarded Master's and PhD degrees (jointly trained with Japan Atomic Energy Research Institute) at Toho University (Japan) in 1998 and 2002, respectively. He is full professor & group leader at Dalian Institute of Chemical Physics (DICP) and Chinese Academy of Sciences (CAS). His main research fields are Mössbauer spectroscopic applications and nanometer-sized catalytic materials.

Tao Zhang received his PhD in physical chemistry from DICP, Chinese Academy of Sciences, in 1989 under the supervision of Prof. Liwu Lin. After postdoctroal research with Prof. Frank Berry at Birmingham University,he founded his own group at Dalian Institute of Chemical Physics in 1995, where he also became full professor. He was an invited professor at University of Poitiers (France) in the period of 2006-2007 and has been a guest professor at University of Namur (Belgium) since 2011. He was the director of DICP in the period of 2007-2017. He was officially selected as Academician by the Chinese Academy of Sciences in 2013. In 2017, he was promoted as a vice president of Chinese academy of sciences. Over the past decades, Prof. Zhang has successfully designed a great number of nano and subnano metallic catalysts for applications in energy conversion.

Table of Contents

SECTION 1: MOLECULAR ELECTRONICS
Prussian Blue and related Iron Cyanide Complexes: The invaluable input of Mössbauer spectroscopy
Size effect of intercalated cation on the charge transfer phase transition and ferromagnetism for iron mixed-valence systems
57Fe and 119Sn-Mössbauer probes for multifunctional cyano-bridged compounds Mössbauer spectroscopy
Mössbauer Spectroscopy studies of FeII Spin Crossover Complexes with a N2O4 Coordination Sphere
Study on the electronic state of gold mixed-valence complexes by 197Au Mössbauer spectroscopy
The input of Mössbauer spectroscopy for the study of selected Fe(II) spin crossover materials
Metal atom dynamics of Fe and Sn Organometallics
Mössbauer spectroscopy of selected molecular magnets

SECTION 2: ENERGY
Relevance of Mössbauer Spectroscopy to study new materials for Li-ion batteries and reforming catalysis
Mössbauer spectroscopy of catalysts
Quasi in situ 57Fe Mössbauer spectroscopic study for PROX over IrFe catalyst

Mössbauer spectroscopic investigation of Prussian blue analogues and their derivatives applied for environmental catalysis and electrochemistry

Mössbauer spectroscopic investigation of Fe-based silicides

Fe-N-C catalysts prepared by the use of structure foaming agents / non-carboneous templates


SECTION 3: LIFE SCIENCES AND SUSTAINABLE DEVELOPMENT

Mössbauer studies in biological chemical compounds
Mössbauer spectroscopy of proteins
Redox reactions in gleysols and role of bacteria
Mössbauer spectroscopy of Sn fluorides

SECTION 4: COMPUTATIONS OF MÖSSBAUER PARAMETERS

Calculating Mössbauer spectroscopy parameters using the Local Pair Natural Orbital Coupled-Cluster method
Theoretical prediction of Mössbauer spectroscopy parameters using ab initio calculations
How ab-initio computations can help to understand Mössbauer spectroscopy of batteries?

SECTION 5: CHEMISTRY OF NANOMATERIALS
Fe oxide nanomaterials: the key role of Mössbauer spectroscopy
The input of Mössbauer spectroscopy for the study of Fe Nanofibers

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